Decorative welding rod for surface coverings

Abstract

The present invention relates to a decorative welding rod, and to a method to produce a decorative welding rod, comprising a gelified plastisol-based composition comprising a PVC resin in a benzoate plasticizer, and unfused and coloured PVC-based particles.

Claims

1. A decorative welding rod to join elements of a decorative surface covering comprising unfused and coloured PVC-based particles having a first size and colour, said welding rod comprising a continuous matrix formed by a gelified plastisol-based composition comprising a PVC resin in a benzoate plasticizer, said continuous matrix having embedded therein unfused PVC-based particles having a second size and colour visually matching the first size and colour of the PVC-based particles used in the decorative surface covering.

2. The decorative welding rod according to claim 1, wherein the plastisol-based composition further comprises a phthalate plasticizer and/or a phosphate plasticizer.

3. The decorative welding rod according to claim 1, wherein the benzoate plasticizer represents between 2.5 % wt and 34 % wt of the total weight of the composition.

4. The decorative welding rod according to claim 2, wherein the ratio between the benzoate plasticizer and the other phthalate and/or phosphate plasticizer is between 5 and 100.

5. The decorative welding rod according to claim 1, wherein the plastisol-based composition comprises an additive, said additive being a stabilizer, a deairing agent, a viscosity depressant, a pigment, or a mixture thereof.

6. The decorative welding rod according to claim 1, wherein the PVC-based particles represent up to 50 % wt of the total weight of the plastisol-based composition.

7. The decorative welding rod according to claim 1. wherein said unfused PVC-based particles represent between 12 % wt and 28 % wt with respect to said PVC resin contained in said continuous matrix.

8. The decorative welding rod according to claim 1, wherein the welding rod has a round cross-section.

9. A decorative welding rod to join elements of a decorative surface covering comprising unfused and coloured PVC-based particles having a first size and colour, said welding rod comprising a continuous matrix formed by a gelified plastisol-based composition comprising a PVC resin in a benzoate plasticizer, said continuous matrix having embedded therein unfused PVC-based particles having a second size and colour identical to the first size and colour of the unfused PVC-based particles used in the elements of the decorative surface.

10. A decorative welding rod to join elements of a decorative surface covering comprising unfused and coloured PVC-based particles, said welding rod comprising a continuous matrix formed by a gelified plastisol-based composition of a PVC resin in at least one plasticizer, said continuous matrix having suspended therein unfused and coloured PVC-based particles in an amount of between 12 % wt to 28 % wt with respect to said PVC resin of said gelified plastisol-based composition, wherein said at least one plasticizer comprises a benzoate plasticizer representing between 17 % wt and 34 % wt, of the total composition.

Description

SHORT DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 represents a welding rod according to the prior art joining three-dimensional floor-covering elements.

(2) FIG. 2 represents a welding rod according to the prior art joining jasped floor-covering elements.

(3) FIG. 3 represents a welding rod according to the prior art joining floor-covering elements comprising a multicoloured-chips image.

(4) FIG. 4 represents the welding rod according to the invention joining three-dimensional floor-covering elements.

(5) FIG. 5 represents the welding rod according to the invention joining jasped floor-covering elements.

(6) FIG. 6 represents the welding rod according to the invention joining floor-covering elements comprising a multicoloured-chips image.

(7) FIG. 7 is a schematic representation of an equipment for producing a welding rod according to the invention.

DETAILED DESCRIPTION OF THE INVENTION

(8) A welding rod for surface coverings has to conciliate not only aesthetical requirements, but also many mechanical requirements (flexibility, adhesion, . . . ) that are different from those of floor-covering elements.

(9) The present invention relates to a decorative welding rod 5, and to a method for producing such a decorative welding rod joining floor-covering elements, particularly PVC-based covering elements, more particularly PVC-based covering elements 2 comprising multicoloured chips or granules image, or PVC-based covering elements 1 or 3 comprising a three-dimensional effect.

(10) Contrary to welding rods according to the prior art 4, the decorative welding rod 5 according to the invention present the advantage of having the required properties of a welding rod, but also of being visually integrated to three-dimensional or granules image floor covering.

(11) The decorative welding rod 5 according to the invention comprises a gelified plastisol-based composition comprising a PVC resin suspended in a plasticizer, and substantially comprising the same PVC-based particles than those used in the decorative surface elements to join, i.e. PVC-based particles identical or equivalent to those used in the decorative surface elements to join.

(12) The advantage of using a plastisol-based composition is that, in addition to enabling the welding rod to have good adhesion to any PVC-based surface coverings, it enables to get a welding rod 5 that can identically or similarly reproduce the aspect of a large number of multicoloured pattern coverings (FIGS. 4 to 6), by adapting the size and colour of the unfused and coloured PVC-based particles of the rod to those of the covering elements, and optionally by incorporating a pigment. The emulated coverings may be homogenous or multiple layer coverings, and comprise coloured chips, or granules, or have a coloured pattern printed.

(13) Furthermore, the plastisol-based compositions have the advantage of being implemented in a straight-forward process, a process suitable for producing welding rod reproducing the marble aspect, or the depth aspect, of any floor-covering elements.

(14) The plastisol-based composition is a suspension, or emulsion, of particles of one, or several, homopolymeric or copolymeric PVC resin, suspended in at least one plasticizer, the plasticizer being a phthalate plasticizer, a benzoate plasticizer, a phosphate plasticizer, or a mixture thereof.

(15) Preferably, the plastisol-based composition comprises a benzoate plasticizer. Preferably, the benzoate plasticizer is either a monobenzoate or a dibenzoate plasticizer, or a mixture thereof. In a preferred embodiment, the monobenzoate is isononylbenzoate or 2-ethylhexylbenzote. In another embodiment, the plasticizer is a dibenzoate plasticizer, preferably a mixture of diethylene glycol dibenzoate and dipropylene glycol dibenzoate.

(16) By providing a thick paste consistency to the plastisol-based composition, the benzoate plasticizer has the advantage of enabling an easier gelation of the composition in a film, for example in a 4mm-thick film, compared to the gelation using classic plasticizers. Furthermore, the benzoate plasticizer has the advantage of giving good stain resistance to the welding rod.

(17) Preferably, the plastisol-based composition comprises a mixture of a benzoate plasticizer and a phthalate plasticizer and/or a phosphate plasticizer. Preferably, the phthalate plasticizer is selected from the group consisting of benzyl butyl phthalate (BBP), di(2-ethylhexyl)phthalate (DEHP), di-isobutyl phthalate (DIBP), Diisodecyl (DIDP), di-isoheptyl phthalate (DIHP), di(isononyl) cyclohexane-1,2-dicarboxylate (DINCH), di-isononyl phthalate (DINP), or a mixture thereof. Preferably, the phosphate plasticizer is selected from the group consisting of cresyl diphenyl phosphate (CDP), di-phenyl 2-ethylhexyl phosphate (EDP), isodecyl diphenyl phosphate (IDP), or a mixture thereof.

(18) The preferred plasticizer mixture is a mixture of diethylene glycol dibenzoate and dipropylene glycol dibenzoate, di-isononyl phthalate (DINP), and cresyl diphenyl phosphate (CDP).

(19) Preferably, the at least one plasticizer represents between 17% wt and 35% wt of the total weight of the composition. Preferably, the benzoate plasticizer represents up to 35% wt of the total weight of the composition, the phthalate plasticizer up to 35% wt of the total weight of the composition, and the phosphate plasticizer up to 15% wt of the total weight of the composition. Preferably, in a plasticizer mixture, the ratio between the benzoate plasticizer and the other plasticizer (phthalate and/or phosphate plasticizer) is between 0.10 and 0.6.

(20) The plastisol-based composition may further comprise an additive which may be a stabilizer, a deairing agent, a viscosity depressant, a pigment or a mixture thereof.

(21) Preferably, the additive represents between 1% wt and 5% wt of the total weight of the composition.

(22) The plastisol-based composition may be transparent or translucent so that the welding rod emulates a three-dimensional covering (FIG. 4), or may comprise one or several pigments, identical or corresponding to the pigment of the covering elements, so that the welding rod emulates the marble aspect of the covering (FIG. 6).

(23) The multicoloured PVC-based particles in the plastisol-based composition have a size and colour, or colours, identical or corresponding to those of the particles into the floor-covering elements to join. The PVC-based particles may have any suitable shape to participate to the visual integration of the welding rod to the floor covering. In a preferred embodiment, the PVC-based particles have a shape so that, when the welding rod is cut off after welding, they have the appearance of chips or spangles. More preferably, the PVC-based particles are substantially round or spherical.

(24) Preferably, the multicoloured PVC-based particles have a size up to 5 mm, more preferably between 1.2 and 2.8 mm.

(25) Preferably, the multicoloured PVC-based particles represent between 12% wt to 28% wt in respect to 100 parts of PVC resin in the plastisol-based composition.

(26) The PVC-based particles may further comprise a filler, a stabilizer, an antioxidant, a matting agent, a pigment, or a mixture thereof.

(27) Examples of welding rod compositions are given in table 1. The unit Phr means proportion by weight, with respect to 100 parts of the polymer (PVC).

(28) TABLE-US-00001 1 2 3 4 5 6 7 8 9 (Phr) (Phr) (Phr) (Phr) (Phr) (Phr) (Phr) (Phr) (Phr) PVC 100 100 100 100 100 100 100 100 100 Benzoate 24.5 12 28 24.5 24.5 5 47 57 0 plasticizer Phthalate 26.5 17.5 30 26.5 26.5 45 0 0 49.84 plasticizer Phosphate 7 7 0 7 7 0 10 0 0 plasticizer Stabilizer 5.5 5.5 5.5 5.5 5.5 4.5 4.5 5.5 4.5 Deairing 0.1 0.1 0.1 0.1 0.1 0 0 0.1 0 agent Viscosity 1 1 1 1 1 7.5 7.5 0 7.5 depressant PVC granules 30 15 45 45 45 21.675 21.675 15 21.675 Pigment 0 3 0 0 3.5 0 0 3.5 0

(29) As an example, the PVC polymer is B7021 or P1430 from Vestolit, or a mixture of 75% PB1704H from Arkema and 25% of Vinnolit C66W from Vinnolit, or a mixture of 69.5% of Pevikon P1412 from Ineos or E70TT from Vinnolit GmbH and 30.5% of Vinnolit C66W or C65V from Vinnolit GmbH or 266SC/F from Solvin.

(30) As an example, the benzoate plasticizer is Santicizer 9500 from Ferro, Benzoflex 181, or Benzoflex 284, or Benzoflex 2088 from Velsicol Chemical Corporation.

(31) As an example, the phthalate plasticizer is Jayflex 77 from Exxon Mobile or Vestinol 9 from Oxeno Olefinchemie GmbH.

(32) As an example, the phosphate plasticizer is Santicizer1439 from Ferro, Disflamol DPO or Disflamol DPK from Lanxess, or Santicizer 148 from Ferro.

(33) As an example, the stabilizer is Lankromark LZC649 from Akcros, Lastab DP34 from Lagor, or Lankromark LZB6137 from Akcros.

(34) As an example, the deairing agent is Byk3105, or Byk3160 or Byk3155 from Byk.

(35) As an example, the viscosity depressant is DP110 from E-chem, Byk5050 or Byk21151 from Byk.

(36) As an example, the pigment is any suitable only limited to aesthetic considerations. Preferably, it is Heliogen Blue K6911D from BASF, Cromophtal Red BRN from Ciba, or Bayferrox 318 from Lanxess.

(37) The PVC-based particles are either multicolour particles or particles from different colours; their amount, size and colour, are chosen to match the design of the floor-covering elements to be welded. For example, the PVC-based particles are made of four different colours for a non-directional floor covering having large particles in clear wear layer design effect (Tarkett Century Croma) (FIG. 4), or made of two different colours for a floor covering having small particles in pigmented wear layer design effect (Tarkett Safetred Universal flooring) (FIG. 6), or made of six different colours for a floor covering having a 3D design effect in clear wear layer (Tarkett Safetred Dimension flooring), or made of multicolour particles for a floor covering having a stone-marble effect (Tarkett Optima flooring) (FIG. 5).

(38) The multicoloured PVC-based particles are produced by any suitable process. Preferably, they are produced by grounding a coloured PVC-based film calendered beforehand or a PVC-based cord-extruded beforehand. Preferably, the PVC-based sheet, or the cord, has a single colour to give single colour particles. However, the PVC-based sheet, or the cord, may have different colours, for example with a marbling effect, to give multicoloured particles.

(39) The method to produce decorative welding rod according to the invention comprises a step of depositing a welding rod composition, comprising a plastisol-based composition comprising coloured PVC-based particles, onto a band-shape carrier 12, or belt, preferably without using any other support or substrate, a step of gelling the composition, preferably between 140 to 240 C., more preferably at around 200 C., the gelling step being preferably performed immediately after the deposition of said composition, and a step of embossing the decorative sheet 13 thus obtained in order to form a plurality of welding rod 15.

(40) Preferably, the components of the welding rod composition are blended in a suitable mixer under vacuum to prevent from air entrapment in the welding rod before being deposited on a band-shape carrier 12.

(41) Preferably, the decorative sheet 13 thus produced has a thickness corresponding to the final diameter of the desired welding rod. Preferably, the decorative sheet 13 has a thickness of around 4 mm. Preferably, the welding rod 5 has a diameter of around 4 mm.

(42) The method according to the invention is suitable for different decorative welding rod as it uses the same plastisol-based composition, only the presence of a pigment and/or the type of PVC-based particles changes.

(43) The device 6 to implement the method for producing the welding rod 5 presents the advantage of being a compact device having roughly the size of an extruder.

(44) In a preferred embodiment, the device 6 comprises a paste-feeding pipe 7 for the deposition of the welding rod composition, a knife coater 8 to spread the composition onto, and across, the band-shape carrier 12, and to set the film to the desired thickness, and cheek plates 9 to prevent the welding rod compositing from spreading outside band-shape carrier 12.

(45) The band-shape carrier 12 has the shape of a belt and does not comprise grooves. It is made of any suitable heat-resistant material, made for example of textile, or preferably made of metal, preferably made of stainless steel. Preferably, the band-shape carrier 12 is coated with teflon. Preferably the band-shape carrier 12 may be heated.

(46) The gelling of the welding rod composition may be done with any suitable device. It may be performed for example by two infrared heating devices, or preferably using two iron plate heating devices 10 and 11, arranged on both sides of the band-shape carrier 12, and in close contact with said band-shape carrier 12.

(47) The device 6 further comprises an embossing device 14 comprising two engraved cylinders, for example made of steel, embossing the decorative sheet 13 to form a plurality of decorative welding rods 15 which can be cut to get single the decorative welding rods.