Method of manufacturing nickel silicide in bipolar complementary-metal-oxide-semiconductor (BiCMOS)
12199090 ยท 2025-01-14
Assignee
Inventors
- Mantavya Sinha (Irvine, CA, US)
- Edward Preisler (San Clemente, CA, US)
- David J. Howard (Irvine, CA, US)
Cpc classification
H01L21/324
ELECTRICITY
H10D84/0109
ELECTRICITY
International classification
H01L27/06
ELECTRICITY
H01L21/324
ELECTRICITY
Abstract
A bipolar complementary-metal-oxide-semiconductor (BiCMOS) device includes a MOS transistor including CMOS nickel silicided regions in a CMOS region, and a bipolar transistor in a bipolar region. The bipolar transistor includes a nickel silicided emitter, a collector, and a base including an intrinsic base, a link base, and a nickel silicided extrinsic base. The intrinsic base is situated between the nickel silicided emitter and the collector. A dielectric spacer separates the link base from the nickel silicided emitter. The nickel silicided extrinsic base provides an electrical connection to the link base and the intrinsic base. A nickel silicided collector sinker provides an electrical connection to the collector. The CMOS nickel silicided regions, nickel silicided emitter, nickel silicided extrinsic base, and nickel silicided collector sinker can include an additive of molybdenum (Mo) and/or platinum (Pt). A low temperature rapid thermal anneal can be performed so as to prevent deactivation of dopants.
Claims
1. A method comprising: providing a bipolar complementary-metal-oxide-semiconductor (BiCMOS) device comprising: a MOS transistor in a CMOS region; a bipolar transistor in a bipolar region, said bipolar transistor comprising: an emitter, a collector, and a base comprising an intrinsic base, a link base, and an extrinsic base; said intrinsic base being situated between said emitter and said collector; a dielectric spacer separating said link base from said emitter; said extrinsic base providing an electrical connection to said link base and said intrinsic base; a collector sinker providing an electrical connection to said collector; said emitter comprising an exposed top surface and an exposed outer sidewall that form a substantially right-angle corner; forming a nickel layer over said MOS transistor and said bipolar transistor, said nickel layer directly contacting said exposed top surface and said exposed outer sidewall of said emitter; performing a first rapid thermal anneal to form CMOS nickel silicided regions, a nickel silicided emitter, a nickel silicided extrinsic base, and a nickel silicided collector sinker; removing unreacted nickel of said nickel layer; performing a second rapid thermal anneal prior to forming a contact to said bipolar transistor, wherein said second rapid thermal anneal is a low temperature rapid thermal anneal; and forming an emitter contact directly contacting an outer sidewall of said nickel silicided emitter.
2. The method of claim 1, wherein said nickel silicided extrinsic base is conformal.
3. The method of claim 1, wherein said nickel silicided extrinsic base is raised.
4. The method of claim 1, wherein said second rapid thermal anneal transforms at least one of said CMOS nickel silicided regions, said nickel silicided emitter, said nickel silicided extrinsic base, or said nickel silicided collector sinker into an a less nickel-rich form.
5. A method comprising: providing a bipolar complementary-metal-oxide-semiconductor (BiCMOS) device comprising: a MOS transistor in a CMOS region; a bipolar transistor in a bipolar region, said bipolar transistor comprising: an emitter, a collector, and a base comprising an intrinsic base, a link base, and an extrinsic base; said intrinsic base being situated between said emitter and said collector; a dielectric spacer separating said link base from said emitter; said extrinsic base providing an electrical connection to said link base and said intrinsic base; a collector sinker providing an electrical connection to said collector; said emitter comprising an exposed top surface and an exposed outer sidewall that form a substantially right-angle corner; forming a nickel layer over said MOS transistor and said bipolar transistor, said nickel layer directly contacting said exposed top surface and said exposed outer sidewall of said emitter, said nickel layer including additives of molybdenum (Mo) and/or platinum (Pt); performing a first rapid thermal anneal to form CMOS nickel silicided regions, a nickel silicided emitter, a nickel silicided extrinsic base, and a nickel silicided collector sinker, said CMOS nickel silicided regions, nickel silicided emitter, nickel silicided extrinsic base, and nickel silicided collector sinker including said additives; removing unreacted nickel of said nickel layer; performing a second rapid thermal anneal prior to forming a contact to said bipolar transistor, wherein said second rapid thermal anneal is a low temperature rapid thermal anneal; and forming an emitter contact directly contacting an outer sidewall of said nickel silicided emitter.
6. The method of claim 5, wherein said nickel silicided extrinsic base is conformal.
7. The method of claim 5, wherein said nickel silicided extrinsic base is raised.
8. The method of claim 5, wherein said additives include both Mo and Pt.
9. The method of claim 5, further comprising removing an unreacted portion of said additives concurrently with said removing said unreacted nickel.
10. The method of claim 5, wherein said second rapid thermal anneal transforms at least one of said CMOS nickel silicided regions, said nickel silicided emitter, said nickel silicided extrinsic base, or said nickel silicided collector sinker into an a less nickel-rich form.
11. A method comprising: providing a bipolar complementary-metal-oxide-semiconductor (BiCMOS) device comprising: a MOS transistor in a CMOS region; a bipolar transistor in a bipolar region, said bipolar transistor comprising: an emitter, a collector, and a base comprising an intrinsic base, a link base, and an extrinsic base; said intrinsic base being situated between said emitter and said collector; a dielectric spacer separating said link base from said emitter; said extrinsic base providing an electrical connection to said link base and said intrinsic base; a collector sinker providing an electrical connection to said collector; said emitter comprising an exposed top surface and an exposed outer sidewall that form a substantially right-angle corner; forming a nickel layer over said MOS transistor and said bipolar transistor, said nickel layer directly contacting said exposed top surface and said exposed outer sidewall of said emitter, said nickel layer including additives of molybdenum (Mo) and/or platinum (Pt); performing a first rapid thermal anneal to form CMOS nickel silicided regions, a nickel silicided emitter, a nickel silicided extrinsic base, and a nickel silicided collector sinker; removing unreacted nickel of said nickel layer using a first cleaning action; removing an unreacted portion of said additives using a second cleaning action; performing a second rapid thermal anneal prior to forming a contact to said bipolar transistor, wherein said second rapid thermal anneal is a low temperature rapid thermal anneal; and forming an emitter contact directly contacting an outer sidewall of said nickel silicided emitter.
12. The method of claim 11, wherein said nickel silicided extrinsic base is conformal.
13. The method of claim 11, wherein said nickel silicided extrinsic base is raised.
14. The method of claim 11, wherein said additives include both Mo and Pt.
15. The method of claim 11, wherein said second rapid thermal anneal transforms at least one of said CMOS nickel silicided regions, said nickel silicided emitter, said nickel silicided extrinsic base, or said nickel silicided collector sinker into an a less nickel-rich form.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(8) The following description contains specific information pertaining to implementations in the present disclosure. The drawings in the present application and their accompanying detailed description are directed to merely exemplary implementations. Unless noted otherwise, like or corresponding elements among the figures may be indicated by like or corresponding reference numerals. Moreover, the drawings and illustrations in the present application are generally not to scale, and are not intended to correspond to actual relative dimensions.
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(10) Actions 102 through 110 shown in flowchart 100 of
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(12) In various implementations substrate 212 can comprise bulk silicon (for example, high-resistivity silicon), germanium, or a group III-V material. For example, substrate 212 can be a typical monocrystalline bulk silicon. In other implementations, substrate 212 can be a pre-fabricated semiconductor-on-insulator (SOI) substrate. In the SOT implementation, a bonded and etch back SOT (BESOI) process, a separation by implantation of oxygen (SIMOX) process, or a smart cut process can be used for fabricating the SOI substrate as known in the art.
(13) Bipolar transistor 222 is situated in bipolar region 218. MOS transistor 224 is situated in CMOS region 220. Additional bipolar devices and additional CMOS devices (not shown in
(14) MOS transistor 224 includes transistor body 258, source/drain regions 260, lightly-doped source/drain regions 262, gate oxide 264, gate 266, and dielectric spacers 268. Transistor body 258 is situated in substrate 212. Transistor body 258 has a first conductivity type. For example, transistor body 258 can be implanted with boron or another appropriate P type dopant, such that transistor body 258 has P type conductivity.
(15) Source/drain regions 260 are situated in transistor body 258. Lightly-doped source/drain regions 262 are also situated in transistor body 258. Source/drain regions 260, as well as lightly-doped source/drain regions 262, have a second conductivity type opposite to the first conductivity type. Continuing the above example, where transistor body 258 has P type conductivity, source/drain regions 260, as well as lightly-doped source/drain regions 262, can be implanted with phosphorus or another appropriate N type dopant. As known in the art, lightly-doped source/drain regions 262 can be regions having lower dopant concentration than source/drain regions 260. Source/drain regions 260 and lightly-doped source/drain regions 262 together function as sources/drains of MOS transistor 224.
(16) Gate oxide 264 is situated over transistor body 258. Gate oxide 264 can comprise, for example, silicon dioxide (SiO.sub.2) or another dielectric. Gate 266 is situated over gate oxide 264. Gate 266 can comprise polycrystalline silicon (polysilicon) or a conductive metal. Dielectric spacers 268 are situated on sides of gate 266. Dielectric spacers 268 can comprise, for example, silicon nitride (SiN). In the present implementation, lightly-doped source/drain regions 262 are aligned with gate 266, while source/drain regions 260 are aligned with dielectric spacers 268.
(17) Bipolar transistor 222 includes emitter 226, base 242, intrinsic collector 232 and extrinsic collector 234, isolation structures 240, dielectric segments 252, and dielectric spacers 254 and 256. Emitter 226 is situated over base 242. Emitter 226 can comprise polysilicon. In one implementation, where bipolar transistor 222 is an NPN transistor, emitter 226 can be implanted with phosphorus or another appropriate N type dopant.
(18) Emitter 226 includes top surface 228 and sidewalls 230. On an upper part of emitter 226, sidewalls 230 are exposed. On a lower part of emitter 226, sidewalls 230 are surrounded by dielectric spacers 256. In the present implementation, emitter 226 is substantially T shaped. In various implementations, emitter 226 may have any other shape. Dielectric spacers 256 separate link bases 246 from emitter 226. Dielectric spacers 256 on sidewalls 230 of emitter 226 can comprise, for example, SiO.sub.2, SiN, or a bilayer of SiO.sub.2 and SiN.
(19) Intrinsic collector 232 and extrinsic collector 234 are situated in bipolar region 218. Intrinsic collector 232 and extrinsic collector 234 have the same conductivity type as emitter 226. Intrinsic collector 232 is relatively heavily doped compared to extrinsic collector 234. Continuing the above example, where bipolar transistor 222 is an NPN transistor, extrinsic collector 234 can be implanted with an N type dopant, while intrinsic collector 232 can be heavily implanted with an N+ type dopant.
(20) Sub-collector 236 is situated in substrate 212 below intrinsic collector 232, extrinsic collector 234, and collector sinkers 238. Sub-collector 236 and collector sinkers 238 can be heavily doped regions having the same conductivity type as intrinsic collector 232. Continuing the above example, where bipolar transistor 222 is an NPN transistor, sub-collector 236 and collector sinkers 238 can be heavily implanted with an N+ type dopant. Sub-collector 236 and collector sinkers 238 provide a low resistance electrical pathway from intrinsic collector 232 through sub-collector 236 and collector sinkers 238 to the top surface of substrate 212. Thus, collector sinkers 238 provide external electrical connections to the collector of bipolar transistor 222.
(21) Isolation structures 240 are situated in extrinsic collector 234 near collector sinkers 238. Isolation structures 240 can be, for example, local oxidation of silicon (LOCOS) or shallow trench isolation (STI) oxide, formed in a manner known in the art. Dielectric segments 252 are situated on isolation structures 240. The presence of dielectric segments 252 on isolation structures 240 increases the separation between extrinsic bases 248 of base 242 and extrinsic collector 234. The increased separation translates to a lower capacitance value between extrinsic bases 248 and extrinsic collector 234. In one implementation, dielectric segments 252 can comprise SiO.sub.2. In various implementations, dielectric segments 252 can be low-k dielectric materials having a dielectric constant lower than SiO.sub.2, such as porous silica, fluorinated amorphous carbon, fluoro-polymer, parylene, polyarylene ether, silsesquioxane, fluorinated silicon dioxide, and diamond-like carbon.
(22) Base 242 is situated on intrinsic collector 232, extrinsic collector 234, and dielectric segments 252. Base 242 includes intrinsic base 244, link bases 246, and extrinsic bases 248. Intrinsic base 244 is situated between emitter 226 and intrinsic collector 232. Intrinsic base 244 refers to the region of base 242 underlying the bottom surface of emitter 226, enclosed within dashed lines in
(23) In the present implementation, bipolar transistor 222 is a heterojunction bipolar transistor (HBT). Base 242 can comprise a different material than emitter 226 and/or intrinsic collector 232, thereby creating a heterojunction with emitter 226 and/or intrinsic collector 232. This heterojunction enables bandgap narrowing and makes it possible for bipolar transistor 222 to achieve high gain values. In one implementation, emitter 226 and intrinsic collector 232 comprise silicon, and base 242 comprises silicon-germanium (SiGe).
(24) In the present implementation, base 242 is heavily doped and has a conductivity type opposite to the conductivity type of emitter 226 and intrinsic collector 232. Continuing the above example, where bipolar transistor 222 is an NPN transistor, base 242 can be heavily implanted with a P+ type dopant. Heavy doping of base 242 further enables bandgap narrowing and makes it possible for bipolar transistor 222 to achieve higher gain values.
(25) In the present implementation, base 242 can also be a thin base. Thickness t.sub.B of base 242 can have the minimum possible value permitted for a given fabrication process. Base 242 can be formed by chemical vapor deposition (CVD), physical vapor deposition (PVD), or molecular beam epitaxy (MBE), and can have a minimum possible thickness permitted by the formation technique. In one implementation, the thickness t.sub.B of base 242 can be on the order of one hundred angstroms (100 ) or less. Thin base 242 causes an increased gain for bipolar transistor 222, and additionally enables low intrinsic device delays essential for high speed circuit performance.
(26) Base 242 is conformally formed. In particular, extrinsic bases 248 conform to dielectric segments 252. As such, segments of extrinsic bases 248 over extrinsic collector 234 are situated at a lower height than segments of extrinsic bases 248 over dielectric segments 252. Conformal segments 250 of extrinsic bases 248 transition from the height of extrinsic bases 248 over extrinsic collector 234 to the height extrinsic bases 248 over dielectric segments 252. Notably, there exist gaps in extrinsic bases 248 between conformal segments 250 of extrinsic bases 248 and dielectric spacers 256.
(27) Dielectric spacers 254 are situated on sides of extrinsic bases 248 and sides of dielectric segments 252. Dielectric spacers 254 can comprise, for example, SiN. Dielectric spacers 254 separate extrinsic bases 248 from collector sinkers 238. As described above, dielectric segments 252 lower the capacitance value between extrinsic bases 248 and extrinsic collector 234.
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(29) Nickel layer 270 can be formed, for example, by sputtering. In one implementation, layer 270 comprises only nickel (Ni). In various implementations, nickel layer 270 comprises nickel along with one or more additives of molybdenum (Mo) and/or platinum (Pt). If nickel layer 270 is too thick, it can consume the entire semiconductor thickness t.sub.B of extrinsic bases 248 during a subsequent annealing action, and undesirably short extrinsic base 248 of base 242 to extrinsic collector 234. In one implementation, in order to maintain extrinsic bases 248 as thin extrinsic bases while still preventing shorting, the thickness of nickel layer 270 can have the minimum permitted thickness needed to achieve a complete layer for a given fabrication process. If both nickel layer 270 and base 242 having the minimum permitted thicknesses would still result in shorting, thickness t.sub.B of base 242 can be increased as needed to prevent shorting.
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(31) The first RTA also causes nickel layer 270 to react with emitter 226, collector sinkers 238, and extrinsic bases 248 on bipolar transistor 222 to form metal-rich nickel silicides 276, 278, and 280 respectively. Notably, nickel silicide 276 is situated on top surface 228 and on sidewalls 230 of emitter 226. In the present application, nickel silicide 276 and emitter 226 may be collectively referred to as a nickel silicided emitter. Similarly, nickel silicides 278 and collector sinkers 238 may be collectively referred to as nickel silicided collector sinkers, and nickel silicides 280 and extrinsic bases 248 may be collectively referred to as nickel silicided extrinsic bases. It is noted that dielectric spacers 254 and 256 do not react during the first RTA and are thus not silicided. As such, dielectric spacers 254 are utilized to separate and insulate nickel silicides 278 and 280 from shorting to each other, and dielectric spacers 256 are utilized to separate and insulate nickel silicides 276 and 280 from shorting to each other.
(32) Only small volumes of silicon of extrinsic bases 248 are consumed during formation of nickel silicides 280. For example, nickel layer 270 may consume approximate fifty percent (50%) less silicon of extrinsic bases 248 during formation of nickel silicides 280, compared to a volume of silicon of extrinsic bases 248 consumed by a conventional cobalt layer during formation of conventional cobalt silicides. Because nickel layer 270 utilizes small volumes of silicon of extrinsic bases 248, nickel silicides 280 are thin and do not undesirably short to extrinsic collector 234. Additionally, intrinsic base 244, link bases 246, and extrinsic bases 248 can be formed thin. Furthermore, thin intrinsic base 244 results in an increased gain for bipolar transistor 222.
(33) Because nickel layer 270 utilizes small volumes of silicon of extrinsic bases 248, nickel silicides 280 do not extend significantly into link bases 246 under dielectric spacers 256. As seen in
(34) As described above, in various implementations, nickel layer 270 comprises nickel along with one or more additives of Mo and/or Pt. In such implementations, nickel silicides 272, 274, 276, 278, and 280 will include these additives. These additives further prevent spiking and/or agglomeration in nickel silicides 272, 274, 276, 278, and 280.
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(36) Unreacted nickel can be removed, for example, using a wet etch sulfuric peroxide mix comprising sulfuric acid and hydrogen peroxide. In various implementations, other etch chemistries or other techniques may be utilized to remove unreacted nickel. In various implementations, unreacted additives of Mo and/or Pt may be removed concurrently with the removal of unreacted nickel, or using another cleaning action.
(37) Remaining nickel silicides 272, 274, 276, 278, and 280 enable BiCMOS structure 208 to achieve reduced dimensions. As described above, because nickel layer 270 (shown in
(38) Because nickel silicides 280 are thin, the spacing between lower segments of nickel silicides 280 overlying extrinsic collector 234 and nickel silicide 276 on sidewalls 230 of emitter 226, represented by dimension D2 in
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(40) In contrast, nickel silicides 272, 274, 276, 278, and 280 transform into less nickel-rich forms at a lower temperature. For example, in
(41) The second RTA transforms nickel-rich nickel silicides into less nickel-rich forms having high conductivity and low electromigration. Nickel silicides 272, 274, 276, 278, and 280 create highly conductive electrical connections to source/drain regions 260, gate 266, emitter 226, collector sinkers 238, and extrinsic bases 248. In particular, nickel silicides 276, 278, and 280 reduce the emitter contact resistance, collector contact resistance, and base contact resistance of bipolar transistor 222, enabling improved current gain.
(42) Nickel silicide 276 particularly reduces the emitter contact resistance of bipolar transistor 222. For example, if a subsequently formed emitter contact (not shown) were misaligned, because nickel silicide 276 extends to and is situated on sidewalls 230 of emitter 226, portions of the emitter contact that would otherwise contact low conductivity dielectric spacers 256 may instead contact high conductivity nickel silicide 276. As another example, because nickel silicide 276 wraps around top surface 228 to sidewalls 230, nickel silicide 276 reduces abnormalities and current crowding at corners of the nickel silicided emitter.
(43) BiCMOS structure 210 represents a substantially completed BiCMOS device. However, BiCMOS structure 210 can also include additional elements not shown in
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(45) As shown in
(46) From the above description it is manifest that various techniques can be used for implementing the concepts described in the present application without departing from the scope of those concepts. Moreover, while the concepts have been described with specific reference to certain implementations, a person of ordinary skill in the art would recognize that changes can be made in form and detail without departing from the scope of those concepts. As such, the described implementations are to be considered in all respects as illustrative and not restrictive. It should also be understood that the present application is not limited to the particular implementations described above, but many rearrangements, modifications, and substitutions are possible without departing from the scope of the present disclosure.