SEMICONDUCTOR DEVICES AND METHODS OF FABRICATING THE SAME
20170271479 ยท 2017-09-21
Inventors
- Jinbum Kim (Seoul, KR)
- Jaeyoung Park (Yongin-si, KR)
- DONGHUN LEE (DAEGU, KR)
- Jeongho Yoo (Seongnam-si, KR)
- JIEON YOON (HAWSEONG-SI, KR)
- Kwan Heum Lee (Suwon-si, KR)
- Choeun Lee (Pocheon-si, KR)
- Bonyoung Koo (Suwon-si, KR)
Cpc classification
H10D64/512
ELECTRICITY
H01L21/3003
ELECTRICITY
H10D62/021
ELECTRICITY
H10D62/81
ELECTRICITY
H10D64/01
ELECTRICITY
H10D62/822
ELECTRICITY
H10D64/017
ELECTRICITY
H10D64/256
ELECTRICITY
International classification
H01L29/66
ELECTRICITY
H01L21/30
ELECTRICITY
H01L29/165
ELECTRICITY
H01L29/40
ELECTRICITY
H01L29/08
ELECTRICITY
H01L29/423
ELECTRICITY
H01L29/417
ELECTRICITY
H01L29/04
ELECTRICITY
Abstract
A method of fabricating a semiconductor device is provided as follows. A source/drain pattern is formed on a substrate. The source/drain pattern contains silicon atoms and germanium atoms. At least one germanium atom is removed from the germanium atoms of the source/drain pattern.
Claims
1. A semiconductor device, comprising: active patterns disposed on a substrate, wherein each of the active patterns, extending in a first direction, has a first region and a recessed region; a device isolation pattern provided on the substrate to cover lower sidewalls of the active patterns; a gate pattern disposed on the first region of the active pattern, wherein the gate pattern extends in a second direction different from the first direction; a source/drain pattern disposed on the recessed regions of the active patterns; and a capping pattern covering the source/drain pattern, wherein the capping pattern has a substantially uniform thickness, wherein the source/drain pattern comprises: first portions provided on the recess regions of the active patterns; and a second portion provided on the device isolation pattern and interposed between the first portions.
2. The semiconductor device of claim 1, wherein the capping pattern comprises a first portion, a second portion connected to the first portion and a third portion connected to the first and second portions, and the first, second and third portions have substantially a same thickness.
3. The semiconductor device of claim 2, wherein the first portions of source/drain pattern contact the first and second portions of the capping pattern and has a {111} crystal plane, and the second portion of the source/drain pattern contacts the third portion of the capping pattern and has a {100} crystal plane and a {110} crystal plane.
4. The semiconductor device of claim 2, wherein the source/drain pattern and the capping pattern comprise a plurality of germanium atoms, and the capping pattern has less germanium atoms than the source/drain pattern.
5. A semiconductor device, comprising: an active pattern disposed on a substrate and extended in a first direction; a gate pattern disposed on a first region of the active pattern and extended in a second direction different from the first direction; a source/drain pattern disposed on a second region of the active pattern, wherein the second region of the active pattern is adjacent to the gate pattern and the source/drain pattern has a first concentration of germanium atoms; a first capping pattern covering the source/drain pattern, wherein the first capping pattern has a second concentration of germanium atoms smaller than the first concentration and the capping pattern has a substantially uniform thickness; and a contact plug penetrating the first capping pattern to be in contact with the source/drain pattern.
6. The semiconductor device of claim 5, wherein a difference between the second concentration and the first concentration is about 3 atomic percent or more.
7. The semiconductor device of claim 5, wherein the second region of the active pattern is recessed, and the source/drain pattern is disposed in the recessed second region.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0032] These and other features of the inventive concept will become more apparent by describing in detail example embodiments thereof with reference to the accompanying drawings of which:
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
[0043] Although corresponding plan views and/or perspective views of some cross-sectional view(s) may not be shown, the cross-sectional view(s) of device structures illustrated herein provide support for a plurality of device structures that extend along two different directions as would be illustrated in a plan view, and/or in three different directions as would be illustrated in a perspective view. The two different directions may or may not be orthogonal to each other. The three different directions may include a third direction that may be orthogonal to the two different directions. The plurality of device structures may be integrated in a same electronic device. For example, when a device structure (e.g., a memory cell structure or a transistor structure) is illustrated in a cross-sectional view, an electronic device may include a plurality of the device structures (e.g., memory cell structures or transistor structures), as would be illustrated by a plan view of the electronic device. The plurality of device structures may be arranged in an array and/or in a two-dimensional pattern.
DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS
[0044] Example embodiments of the inventive concept will be described below in detail with reference to the accompanying drawings. However, the inventive concept may be embodied in different forms and should not be construed as limited to the embodiments set forth herein. In the drawings, the thickness of layers and regions may be exaggerated for clarity. It will also be understood that when an element is referred to as being on another element or substrate, it may be directly on the other element or substrate, or intervening layers may also be present. It will also be understood that when an element is referred to as being coupled to or connected to another element, it may be directly coupled to or connected to the other element, or intervening elements may also be present. Like reference numerals may refer to the like elements throughout the specification and drawings.
[0045]
[0046] Referring to
[0047] A device isolation pattern 110 may be formed on the substrate 100 to cover at least a portion of both sidewalls of the active pattern AF. The device isolation pattern 110 may be formed to expose an upper portion of the active pattern AF. The device isolation pattern 110 may be formed using a shallow trench isolation (STI) method. The device isolation pattern 110 may be formed of or include a high density plasma oxide layer, a spin on glass (SOG) layer, and/or a chemical vapor deposition (CVD) oxide layer.
[0048] A sacrificial gate pattern 200 may be formed on the substrate 100. The sacrificial gate pattern 200 may cross the active pattern AF and extend along a second direction D2. Here, the second direction D2 may be parallel to the bottom surface of the substrate 100 and cross the first direction D1. The sacrificial gate pattern 200 may be formed to cover the channel region CHR of the active pattern AF and expose the source/drain regions SDR. The sacrificial gate pattern 200 may be formed of or include polysilicon.
[0049] Spacer patterns 210 may be formed on the substrate 100 to cover both sidewalls of the sacrificial gate pattern 200. The spacer patterns 210 may include a plurality of stacked layers. The formation of the spacer patterns 210 may include forming a spacer layer (not shown) on the substrate 100 to conformally cover the sacrificial gate pattern 200 and performing an etching process to etch at least a portion of the spacer layer. The spacer patterns 210 may be formed of or include an insulating material (e.g., silicon nitride, silicon carbide, silicon carbonitride, and silicon oxynitride). In an example embodiment, the spacer patterns 210 may be formed of or include at least one of low-k dielectric materials.
[0050] Referring to
[0051] Referring to
[0052] The source/drain pattern 300 may be formed to have a germanium content of about 5 atomic percent or higher. The source/drain pattern 300 may include a first layer 301 and a second layer 302 on the first layer 301. The substrate 100 may be a silicon wafer. The first layer 301 may be formed to have a germanium content lower than that of the second layer 302. For example, the first layer 301 may be formed to have a germanium content of 30 atomic percent or lower, and the second layer 302 may be formed to have a germanium content of 30 atomic percent or higher. The first layer 301 may be interposed between the substrate 100 and the second layer 302 to relieve a mechanical stress, which is caused by a difference in lattice constant between the substrate 100 and the second layer 302.
[0053] The source/drain pattern 300 may have upper and lower inclined surfaces 300a and 300b. The upper and lower inclined surfaces 300a and 300b may be the crystal plane of {111}. For example, the upper and lower inclined surfaces 300a and 300b may be reciprocally inclined with respect to the bottom surface of the substrate 100 to meet each other. The source/drain pattern 300 may be formed to contain p-type dopants (e.g., B and/or Al).
[0054] Referring to
[0055] Hereinafter, the formation of the capping pattern CP will be described in more detail with reference to Table 1, in conjunction with
TABLE-US-00001 TABLE 1 First Example Second Example Formation of Formation of Formation of Formation of S/D pattern capping pattern S/D pattern capping pattern 1.sup.st chamber 1.sup.st chamber 1.sup.st chamber 2.sup.nd chamber Supplied Si-containing gas, Hydrogen gas Si-containing gas, Hydrogen gas Gas Ge-containing gas Ge-containing gas Process 1.sup.st temperature T1 2.sup.nd temperature 1.sup.st temperature T1 3.sup.rd temperature Temperature T2, (T2 T1) T3, (T3 T1)
[0056] In the first example, the capping pattern CP may be formed by a hydrogen thermal treatment process. For example, the supply of the silicon-containing or germanium-containing gas may be interrupted, and a hydrogen gas may be supplied into the first chamber. The temperature of the first chamber may be controlled in such a way that the substrate 100 has a second temperature (e.g., ranging from about 400 C. to about 700 C.). The second temperature may be substantially equal to or higher than the first temperature. At the second temperature T2, the hydrogen gas may react with germanium atoms of the source/drain pattern 300 so that the germanium atoms may be removed. In an example embodiment, the device isolation pattern 110 and the sacrificial gate pattern 200 may have a surface that is free of germanium, and this may make it possible for the hydrogen gas to be selectively reacted with the source/drain pattern 300. Accordingly, the capping pattern CP may be locally, or selectively formed on the source/drain pattern 300.
[0057] In an example embodiment, the capping pattern CP may be formed by a hydrogen plasma treatment process, which is performed at a lower temperature than that for the source/drain pattern 300. For example, the substrate 100 may be provided in a second chamber. The second chamber may be a plasma chamber. The temperature of the second chamber may be controlled in such a way that the substrate 100 has a third temperature lower than the first temperature. For example, the third temperature may range from about 300 C. to about 500 C. (for example, at about 400 C.). The hydrogen gas may be supplied into the second chamber, while the silicon-containing gas and the germanium-containing gas may not be supplied. Accordingly, since the silicon-containing gas and the germanium-containing gas are not supplied in the process of forming the capping pattern CP, the formation of by-products due to the silicon-containing gas and the germanium-containing gas may be prevented from being formed on the device isolation pattern 110 and/or the sacrificial gate pattern 200. Plasma may be generated in the second chamber to produce hydrogen radical, hydrogen anion, and/or hydrogen cation from the hydrogen gas. At a third temperature lower than the first temperature, germanium atoms positioned at the surface region of the source/drain pattern may react with the hydrogen radical, the hydrogen anion, and/or the hydrogen cation. Since the capping pattern CP is formed at the third temperature lower than the first temperature, it may be avoided that the formation of the capping pattern CP affect the reliability of the semiconductor device 1.
[0058] Referring to
[0059] The gate pattern 510 may be formed on the gate insulating pattern 500 and in the opening 250. The gate pattern 510 may extend in the second direction D2 to cross the active pattern AF. The gate pattern 510 may be formed on the channel region CHR of the active pattern AF. The gate pattern 510 may include a plurality of layers. The gate pattern 510 may be formed of or include at least one of conductive materials including conductive metal nitrides, transition metals (e.g., titanium, tantalum, and so forth), and metals. The formation of the gate pattern 510 may include forming a conductive layer (not shown) to fill the opening 250 and performing a thermal treatment process (e.g., an annealing process) on the conductive layer. The thermal treatment process for forming the gate pattern 510 may lead to agglomeration of germanium atoms contained in the source/drain pattern 300. The agglomeration of germanium atoms may result in an electric short between the source/drain pattern 300 and the gate pattern 510, in operation of the semiconductor device 1. In an example embodiment, since the capping pattern CP is formed to cover the source/drain pattern 300, the germanium atoms contained in the source/drain pattern 300 may be avoided from being agglomerated in the thermal treatment process. As described above, the thermal treatment process may be performed to form the gate pattern 510, but the present inventive concept is not limited thereto. For example, the thermal treatment process may refer to a thermal treatment process, which may be performed after the formation of the capping pattern CP. According to an example embodiment of the present inventive concept, the semiconductor device 1 can be fabricated to have improved reliability.
[0060] Referring to
[0061] Referring to
[0062] The source/drain pattern 300 may be formed at a side of the sacrificial gate pattern 200. The source/drain pattern 300 may be formed of or include silicon-germanium (SiGe). The source/drain pattern 300 may be formed by an epitaxial growth process using the recessed regions 150 of the active patterns AF as a seed layer, as described with reference to
[0063] As shown in
[0064] The capping pattern CP may be formed on the source/drain pattern 300 by an epitaxial growth process. For example, the capping pattern CP may be formed on the source/drain pattern 300 by supplying silicon-containing gas into the first chamber. The capping pattern CP may have a silicon content higher than that of the source/drain pattern 300.
[0065] The capping pattern CP may have a growth rate depending on a crystal orientation. For example, the capping pattern CP may have a slow growth speed in a crystal orientation of <111> and thus it may have a relatively thin thickness on the inclined surfaces 310a and 310b of the first portions 310. In other words, the growth rate of the capping pattern CP may be higher on crystal orientations of <100> or <110> than on the crystal orientation of <111>. Accordingly, the capping pattern CP may be thicker on the upper surface 320u of the second portion 320 than on the first portions 310. Furthermore, the second portion 320 may have surfaces with various crystal directions, and thus, the capping pattern CP on the second portion 320 may not be uniform. The capping pattern CP may not be formed on a lower surface 3201 of the second portion 320. In other example embodiments, the capping pattern CP on the lower surface 3201 of the second portion 320 may be thinner than the capping pattern CP on the upper surface 320u of the second portion 320.
[0066] Referring to
[0067] Referring to
[0068]
[0069] Referring to
[0070] The source/drain pattern 300 may be formed at a side of the sacrificial gate pattern 200. The source/drain pattern 300 may be formed of or include silicon-germanium (SiGe). The source/drain pattern 300 may be formed by an epitaxial growth process using the recessed regions 150 of the active patterns AF as a seed layer, as described with reference to
[0071] The source/drain pattern 300 may include a first portion 310 and a second portion 320. For example, the first portion 310 may include the inclined surfaces 310a and 310b that are a crystal plane of {111}. The first portions 310 may meet each other to form the second portion 320 between the first portions 310. The upper surface 320u of the second portion 320 may have a crystal plane (e.g., of {100} and {110}) that is different from that of the first portions 310.
[0072] Referring to
[0073] In example embodiments, the capping pattern CP may be formed in the source/drain pattern 300. Accordingly, germanium atoms contained in the source/drain pattern 300 may be prevented from being agglomerated, and thus, the semiconductor device 3 may have increased reliability.
[0074] Referring to
[0075]
[0076] Referring to
[0077] The controller 1110 may include at least one of a microprocessor, a digital signal processor, a microcontroller, or another logic device, which is configured to have a similar function to them. The I/O unit 1120 may include a keypad, a keyboard, or a display unit. The memory device 1130 may store data and/or commands. The memory device 1130 may include a nonvolatile memory device (e.g., a FLASH memory device, a phase-change memory device, a magnetic memory device, and so forth). Furthermore, the memory device 1130 may further include a volatile memory device. For example, the memory device 1130 may include a static random access memory (SRAM) device with the semiconductor device according to example embodiments of the present inventive concept. It may be possible to omit the memory device 1130, depending on the purpose of the electronic system 1100 or a type of an electronic product, for which the electronic system 1100 is used. The interface unit 1140 may transmit electrical data to a communication network or may receive electrical data from a communication network. The interface unit 1140 may operate in a wireless or wired manner. For example, the interface unit 1140 may include an antenna for the wireless communication or a transceiver for the wired and/or wireless communication. A semiconductor device according to an example embodiment of the present inventive concept may be provided as a part of the controller 1110 or the I/O unit 1120. Although not shown in the drawings, the electronic system 1100 may further include a fast DRAM device and/or a fast SRAM device that acts as a cache memory for improving an operation of the controller 1110.
[0078]
[0079] Referring to
[0080] The processor 1211 may include one or more processor cores C1-Cn. The one or more processor cores C1-Cn may be configured to process data and signals. The processor cores C1-Cn may be configured to include the semiconductor device according to example embodiments of the present inventive concept.
[0081] The electronic device 1200 may be configured to perform its own functions using the processed data and signals. For example, the processor 1211 may be an application processor.
[0082] The embedded memory 1213 may exchange a first data DAT1 with the processor 1211. The first data DAT1 may be data processed, or to be processed, by the one or more processor cores C1-Cn. The embedded memory 1213 may manage the first data DAT1. For example, the embedded memory 1213 may be used for a buffering operation on first data DAT1. In other words, the embedded memory 1213 may be operated as a buffer memory or a working memory for the processor 1211.
[0083] In example embodiments, the electronic device 1200 may be used to realize a wearable electronic device. In general, the wearable electronic device may be configured to perform an operation of calculating a small amount of data, rather than calculating a large amount of data. In this sense, in the case where the electronic device 1200 is used for a wearable electronic device, the embedded memory 1213 may be configured to have a relatively small buffer capacity.
[0084] The embedded memory 1213 may be a static random access memory (SRAM) device. The SRAM device may have a faster operating speed than that of a dynamic random access memory (DRAM) device. Accordingly, in the case where the SRAM is embedded in the semiconductor chip 1210, it is possible for the electronic device 1200 to have a small size and a fast operating speed. Furthermore, in the case where the SRAM is embedded in the semiconductor chip 1210, it is possible to reduce an active power of the electronic device 1200. For example, the SRAM may include the semiconductor device according to example embodiments of the present inventive concept.
[0085] The cache memory 1215 may be mounted on the semiconductor chip 1210, along with the one or more processor cores C1-Cn. The cache memory 1215 may be configured to store cache data DATc that will be used or directly accessed by the one or more processor cores C1-Cn. The cache memory 1215 may be configured to have a relatively small capacity and a very fast operating speed. In example embodiments, the cache memory 1215 may include an SRAM device including the semiconductor device according to example embodiments of the present inventive concept. In the case where the cache memory 1215 is used, it is possible to reduce an access frequency or an access time to the embedded memory 1213 performed by the processor 1211. In other words, the use of the cache memory 1215 may allow the electronic device 1200 to have a fast operating speed.
[0086] To provide better understanding of an example embodiment of the present inventive concept, the cache memory 1215 is illustrated in
[0087] The processor 1211, the embedded memory 1213, and the cache memory 1215 may be configured to exchange or transmit data, based on at least one of various interface protocols. For example, the processor 1211, the embedded memory 1213, and the cache memory 1215 may be configured to exchange or transmit data, based on at least one of Universal Serial Bus (USB), Small Computer System Interface (SCSI), Peripheral Component Interconnect (PCI) Express, Advanced Technology Attachment (ATA), Parallel ATA (PATA), Serial ATA (SATA), Serial Attached SCSI (SAS), Integrated Drive Electronics (IDE), or Universal Flash Storage (UFS).
[0088]
[0089] Referring to
[0090] A first source/drain of the first pull-up transistor TU1 and a first source/drain of the first pull-down transistor TD1 may be connected to a first node N1. A second source/drain of the first pull-up transistor TU1 may be connected to a power line Vcc, and a second source/drain of the first pull-down transistor TD1 may be connected to a ground line Vss. A gate of the first pull-up transistor TU1 and a gate of the first pull-down transistor TD1 may be electrically connected to each other. Accordingly, the first pull-up transistor TU1 and the first pull-down transistor TD1 may constitute a first inverter. The mutually-connected gates of the first pull-up transistor TU1 and the first pull-down transistor TD1 may serve as an input terminal of the first inverter, and the first node N1 may serve as an output terminal of the first inverter.
[0091] A first source/drain of the second pull-up transistor TU2 and a first source/drain of the second pull-down transistor TD2 may be connected to the second node N2. A second source/drain of the second pull-up transistor TU2 may be connected to the power line Vcc, and a second source/drain of the second pull-down transistor TD2 may be connected to the ground line Vss. A gate of the second pull-up transistor TU2 and a gate of the second pull-down transistor TD2 may be electrically connected to each other. Accordingly, the second pull-up transistor TU2 and the second pull-down transistor TD2 may constitute a second inverter. The mutually-connected gates of the second pull-up transistor TU2 and the second pull-down transistor TD2 may serve as an input terminal of the second inverter, the second node N2 may serve as an output terminal of the second inverter.
[0092] The first and second inverters may be coupled with each other to form a latch structure. For example, the gates of the first pull-up transistor TU1 and the first pull-down transistor TD1 may be electrically connected to the second node N2, and the gates of the second pull-up and second pull-down transistors TU2 and TD2 may be electrically connected to the first node N1. The first source/drain of the first access transistor TA1 may be connected to the first node N1, and the second source/drain of the first access transistor TA1 may be connected to a first bit line BL1. The first source/drain of the second access transistor TA2 may be connected to the second node N2, and the second source/drain of the second access transistor TA2 may be connected to a second bit line BL2. The gates of the first and second access transistors TA1 and TA2 may be electrically coupled to a word line WL. The SRAM cell according to an example embodiment of the present inventive concept may have the afore-described structure, but an example embodiment of the present inventive concept is not limited thereto.
[0093]
[0094] According to an example embodiment of the present inventive concept, a capping pattern may be formed on a source/drain pattern, and thus, it is possible to protect the source/drain pattern against a damage which may occur in a process of fabricating a semiconductor device. Furthermore, it is possible to prevent or suppress a short circuit from being formed between the source/drain pattern and the gate pattern. The capping pattern may be formed through a process of removing germanium atoms from a surface of the source/drain pattern, and thus, it is possible to prevent by-products from being formed in a process of forming the capping pattern. Since the capping pattern can be formed to a conformal thickness, it can be removed by an etching process for forming a contact hole. Accordingly, it is possible to improve an electric resistance property between the contact plug and the source/drain pattern. According to an example embodiment of the present inventive concept, the semiconductor device can have improved reliability.
[0095] While the present inventive concept has been shown and described with reference to example embodiments thereof, it will be apparent to those of ordinary skill in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the inventive concept as defined by the following claims.