Field-effect transistor
09698235 ยท 2017-07-04
Assignee
Inventors
Cpc classification
H10D62/832
ELECTRICITY
H10D64/691
ELECTRICITY
H10D30/6211
ELECTRICITY
H01L21/02266
ELECTRICITY
H10D30/6741
ELECTRICITY
H10D30/675
ELECTRICITY
H10D30/6757
ELECTRICITY
H01L21/02197
ELECTRICITY
International classification
H01L21/02
ELECTRICITY
H01L29/786
ELECTRICITY
H01L29/49
ELECTRICITY
H01L29/08
ELECTRICITY
Abstract
The present invention provides a field-effect transistor having an accumulation-layer-operation type field-effect transistor that includes a semiconductor layer in which a source region, a channel region, and a drain region that have either an N-type or P-type conductivity in common are formed, and a gate electrode disposed adjacent to the channel region via a gate insulating film, wherein the gate insulating film is made of a dielectric having a change gradient of a relative dielectric constant in which the relative dielectric constant changes to decrease according to the magnitude of a gate voltage applied to the gate electrode.
Claims
1. A field-effect transistor of an accumulation-layer-operation type, comprising: a semiconductor layer in which a source region, a channel region, and a drain region that have either an N-type or P-type conductivity in common are formed; and a gate electrode disposed adjacent to the channel region via a gate insulating film, wherein the gate insulating film is made of a dielectric having a change gradient of a relative dielectric constant in which the relative dielectric constant changes to decrease according to a magnitude of a gate voltage applied to the gate electrode; and wherein the dielectric has the change gradient of the relative dielectric constant in which when the gate voltage is modulated by 0.5 V, the relative dielectric constant becomes lower than or equal to a 0.5-times of the relative dielectric constant before modulation.
2. The field-effect transistor according to claim 1, wherein when an origin is defined as an electric field intensity of 0 where the electric field intensity is an intensity of an electric field applied to the dielectric, the dielectric has a local maximum value of the relative dielectric constant in a range of the electric field intensity that does not overlap the origin.
3. The field-effect transistor according to claim 1, wherein the dielectric is constituted by any one of: a superlattice structure formed by laminating layers of a metal oxide having a perovskite-type crystalline structure, a metal oxide having a fluorite-type crystalline structure, and a metal oxide having the perovskite-type crystalline structure of a different kind; a superlattice structure formed by laminating layers of metal oxides having the fluorite-type crystalline structure of different kinds; and a superlattice structure formed by laminating layers of a metal oxide having the perovskite-type crystalline structure and a metal oxide having the fluorite-type crystalline structure.
4. The field-effect transistor according to claim 1, wherein the semiconductor layer has a thickness of from 6 nm through 10 nm.
5. The field-effect transistor according to claim 1, wherein the channel region has an impurity concentration of from 410.sup.18/cm.sup.3 through 710.sup.18 cm.sup.3.
6. The field-effect transistor according to claim 1, further comprising: an interfacial layer disposed between the channel region and the gate insulating film.
7. The field-effect transistor according to claim 1, wherein the semiconductor layer is made of a material which is any one of silicon, germanium, tin, a mixed crystal of silicon and germanium, a mixed crystal of germanium and tin, and a group III-V compound.
8. The field-effect transistor according to claim 1, wherein the field-effect transistor has a transistor structure of any one of a bulk type, a SOI type, a fin type, and a nanowire-type.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
DESCRIPTION OF EMBODIMENTS
(16) A field-effect transistor of the present invention will be described with reference to mainly
(17) The support substrate 1 is not particularly limited, and an arbitrary support substrate may be selected according to the purpose. For example, the support substrate in a known SOI (Silicon on Insulator) substrate may be used.
(18) The insulating layer 2 is disposed over the support substrate 1. The insulating layer 2 is not particularly limited, and an arbitrary insulating layer may be selected according to the purpose. For example, the embedded oxide film in the SOI substrate may be used.
(19) A semiconductor layer 9 in which the source region 3, the drain region 4, and the channel region 5 are formed is disposed over insulating layer 2. The semiconductor layer 9 is not particularly limited, and an arbitrary semiconductor layer may be selected according to the purpose. For example, the semiconductor layer in the SOI substrate may be used. That is, it is possible to constitute the support substrate 1, the insulating layer 2, and the semiconductor layer 9 by using the SOI substrate.
(20) Although the SOI substrate is raised as an example, a semiconductor material for forming the semiconductor layer 9 is not particularly limited, and a semiconductor material other than silicon may be selected where appropriate. For example, germanium, tin, a mixed crystal of silicon and germanium, a mixed crystal of germanium and tin, and a group III-V compound such as In.sub.xGa.sub.1-xAs (where x is greater than or equal to 0.53) and GaSb may be used.
(21) A thickness of the semiconductor layer 9 is not particularly limited, but is preferably from 6 nm through 10 nm from a viewpoint of obtaining a steep current change rate of lower than 60 mV/decade in the subthreshold region at room temperature.
(22) The source region 3 and the drain region 4 are formed by ion implantation of an impurity substance into the semiconductor layer 9. The impurity substance is not particularly limited so long as the impurity substance is a material that generates carriers. Examples of the impurity substance when the source region 3 and the drain region 4 are formed to have an N-type conductivity include P and As. Examples of the impurity substance when the source region 3 and the drain region 4 are formed to have a P-type conductivity include B. A method for ion implantation is not particularly limited, and may be carried out according to a known ion implantation method. For example, the method may be carried out by performing ion implantation into the semiconductor layer 9 with a known ion implantation apparatus using a material gas such as a boron difluoride (BF.sub.2) gas, a phosphine (PH.sub.3) gas, and an arsine (AsH.sub.3) gas or a solid of a material such as solid P and solid As as an ion source.
(23) The source region 3 and the drain region 4 formed to have the same conductivity type. A concentration of the impurity substance in the source region 3 and the drain region 4 is not particularly limited, but is preferably from 110.sup.19/cm.sup.3 through 110.sup.21/cm.sup.3 in order to suppress a parasitic resistance.
(24) The channel region 5 is disposed between the source region 3 and the drain region 4 and formed to have the same conductivity type as the source region 3 and the drain region 4 to form an accumulation-operation-type transistor.
(25) The channel region 5 is not particularly limited, and may be formed according to the same method as the method for forming the source region 3 and the drain region 4. However, the impurity concentration in the channel region 5 is preferably from 410.sup.18/cm.sup.3 through 710.sup.18/cm.sup.3 from a viewpoint of obtaining a steep current change rate of lower than 60 mV/decade in the subthreshold region at room temperature.
(26) As described above, the source region 3, the channel region 5, and the drain region 4 that have either an N-type or P-type conductivity in common are formed in the semiconductor layer 9, which enables an accumulation-layer-type transistor operation. That is, when a predetermined gate voltage is set to the gate electrode 8, a field effect generated due to an electric potential difference between the gate electrode 8 and the channel region 5 causes the channel region 5 to be depleted to block a drain current between the source region 3 and the drain region 4 (OFF state). When a different gate voltage is applied to the gate electrode 8, the depletion of the channel region 5 shrinks to promote an accumulation layer in which the same carriers as those in the source region 3 and the drain region 4 are accumulated to be formed in the channel region 5, which causes a drain current to flow between the source region 3 and the drain region 4 through the accumulation layer (ON state).
(27) Incidentally, transistors of the accumulation-operation type are typically normally-on types in which a current flows even when no gate voltage is applied. However, transistors preferable for use in low-power-consuming integrated circuits are normally-off types. Hence, the field-effect transistor 10 is an accumulation-operation-type transistor of a normally-off type.
(28) It is possible to make the field-effect transistor 10 operate as a normally-off type, by adjusting a metal material (work function) of the gate electrode 8 and a thickness of the channel region 5 (semiconductor layer 9) according to a known example to thereby set a threshold voltage defining ON-OFF operations to a predetermined value. That is, based on the setting of the threshold voltage, the field-effect transistor 10 switches off when the channel region 5 is depleted to offset an electric field that is generated due to an electric potential difference between the gate electrode 8 and the channel region 5 even when no gate voltage is applied, and switches on when the depletion shrinks upon application of a gate voltage in a positive direction to weaken the electric field.
(29) The gate insulating film 7 is disposed over the channel region 5 and made of a dielectric having a change gradient of a relative dielectric constant in which the relative dielectric constant changes to decrease according to the magnitude of the gate voltage applied to the gate electrode 8. A characteristic of the dielectric will be described with reference to
(30) Typically, dielectrics include dielectrics that have a characteristic exemplified by a sign A in
(31) The field-effect transistor 10 using the nonlinearly responding dielectric having the relative dielectric constant that changes according to the magnitude of the gate voltage is operated based on a setting of the gate voltage within a range in which the change gradient of the relative dielectric constant in which the relative dielectric constant changes to decrease is used wholly or partially.
(32) In regard to
(33) It is preferable that when an origin is set at an applied electric field intensity of 0, the nonlinearly responding dielectric have a local maximum value of the relative dielectric constant in a range of the electric field intensity that does not overlap the origin. This characteristic of the nonlinearly responding dielectric will be described with reference to
(34) As plotted in
(35) In the accumulation-operation-type field-effect transistor 10, the nonlinearly responding dielectric may be under an electric field having a high intensity due to a field effect attributed to the aforementioned electric potential difference even in an OFF state in which no gate voltage is applied to the gate electrode 8. Hence, it is preferable to use the nonlinearly responding dielectric having a local maximum value of the relative dielectric constant in a range of the electric field intensity that does not overlap the origin.
(36) From a viewpoint of obtaining a steep current change rate of lower than 60 mV/decade in the subthreshold region at room temperature, it is preferable that the change gradient of the relative dielectric constant be steep in the field-effect transistor 10 utilizing the change gradient of the relative dielectric constant. Specifically, it is preferable that the nonlinearly responding dielectric have a change gradient of the relative dielectric constant in which when the gate voltage is modulated to a value higher by 0.5 V on an absolute value basis, the relative dielectric constant becomes lower than or equal to a 0.5-times multiple of the relative dielectric constant before modulation.
(37) The nonlinearly responding dielectric is not particularly limited, and it is preferable that the nonlinearly responding dielectric be constituted by any one of: a superlattice structure formed by laminating layers of a metal oxide having a perovskite-type crystalline structure, a metal oxide having a fluorite-type crystalline structure, and a metal oxide having the perovskite-type crystalline structure of a different kind; a superlattice structure formed by laminating layers of metal oxides having the fluorite-type crystalline structure of different kinds; and a superlattice structure formed by laminating layers of a metal oxide having the perovskite-type crystalline structure and a metal oxide having the fluorite-type crystalline structure, which are examples of dielectrics having the characteristic described above.
(38) Examples of the metal oxide having the perovskite-type crystalline structure include CaTiO.sub.3, SrTiO.sub.3, BaTiO.sub.3, CaZrO.sub.3, SrZrO.sub.3, BaZrO.sub.3, CaHfO.sub.3, SrHfO.sub.3, BaHfO.sub.3, PbTiO.sub.3, (Ba, Sr)TiO.sub.3, Pb(Zr, Ti)O.sub.3, SrBi.sub.2Ta.sub.2O.sub.9, SrBi.sub.2Nb.sub.2O.sub.9, and Sr.sub.2Bi.sub.4Ti.sub.5O.sub.18.
(39) Examples of the metal oxide having the fluorite-type crystalline structure include ZrO.sub.2, ZrO.sub.2 in which Y is added in an amount of from 9 mol % through 13 mol %, HfO.sub.2, HfO.sub.2 in which Y is added in an amount of from 9 mol % through 13 mol %, HfO.sub.2 in which La is added in an amount of from 9 mol % through 13 mol %, and (Zr, Hf)O.sub.2.
(40) Examples of the superlattice structure include a laminated structure of SrTiO.sub.3 and BaTiO.sub.3, a laminated structure of SrZrO.sub.3 and BaZrO.sub.3, a laminated structure of SrHfO.sub.3 and BaHfO.sub.3, a laminated structure of ZrO.sub.2 and HfO.sub.2, a laminates structure of SrHfO.sub.3 and HfO.sub.2, and a laminated structure of SrZrO.sub.3 and ZrO.sub.2.
(41) Various reports have been raised as examples of the nonlinearly responding dielectric. The nonlinearly responding dielectric may be formed according to such known examples. As specific examples of the known examples, a reported example of SrTiO.sub.3 having the perovskite-type crystalline structure (Referential Document 1) and a reported example of the superlattice structure (Referential Document 2) are plotted d in
(42) A thickness of the gate insulating film 7 made of the nonlinearly responding dielectric is not particularly limited. However, from a viewpoint of obtaining a steep current change rate of lower than 60 mV/decade in the subthreshold region at room temperature, it is preferable that an effective oxide film thickness (EOT; Equivalent Oxide Thickness) of the gate insulating film 7 have a change rate (EOT.sub.max/EOT.sub.min) of greater than or equal to 2 when the gate voltage is modulated by 0.5 V. EOT.sub.max represents EOT after the gate voltage is modulated, and EOT.sub.min represents EOT before the gate voltage is modulated.
(43) Referential Document 1: S. Komatsu et al., Jpn. J. Appl. Phys. vol. 37 (1998) p. 5651.
(44) Referential Document 2: J. Kim et al., Appl. Phys. Lett. vol. 80 (2002) p. 3581.
(45) The gate electrode 8 is disposed over the gate insulating film 7. A material for forming the gate electrode 8 is not particularly limited, and examples of the material include Al, Au, Pt, W, TaN, TiN, and silicide. A method for forming the gate electrode 8 is not particularly limited, and examples of the method include a sputtering method and a CVD (Chemical Vapor Deposition) method. A thickness of the gate electrode 8 is not particularly limited and may be from about 10 nm through 50 nm.
(46) The interfacial layer 6 is disposed between the channel region 5 and the gate insulating film 7. The interfacial layer 6 has a function for suppressing interdiffusion of the constituent atoms of the gate insulating film 7 and the channel region 5 between each other, and is disposed as needed depending on the construction of the gate insulating film 7 and the channel region 5.
(47) A material for forming the interfacial layer 6 is not particularly limited, and examples of the material include HfO.sub.2, ZrO.sub.2, Al.sub.2O.sub.3, SiN, and InP. A method for forming the interfacial layer 6 is not particularly limited, and examples of the method include a sputtering method and a CVD method.
(48) In disposing the interfacial layer 6, it is more preferable if a thickness of the interfacial layer 6 is smaller and preferably smaller than or equal to, for example, 5 nm. In disposing the interfacial layer 6, the EOT of the gate insulating film 7 is set to include an EOT of the interfacial layer 6.
(49) An operation of the accumulation-operation-type field-effect transistor 10 having the configuration described above will be described.
(50) First, the gate voltage of the gate electrode 8 is set to 0 or a small value. At the time, the gate insulating film 7 is under an electric field having a high intensity due to an electric potential difference between the gate electrode 8 and the channel region 5 and in a state of having a high relative dielectric constant according to the characteristic of the nonlinearly responding dielectric plotted in
(51) Next, a gate voltage higher than that in the OFF state is applied to the gate electrode 8. At the time, as the gate voltage increases, the electric field intensity at the gate insulating film 7 weakens to cause a decreasing change of the relative dielectric constant according to the characteristic of the nonlinearly responding dielectric. In response to this decreasing change, carriers are gradually accumulated in the depleted region in the channel region 5 to form an accumulation layer, which causes a drain current to flow between the source region 3 and the drain region 4 through the accumulation layer in the channel region 5 (ON state).
(52) At the time, a steep current change rate during the shift from the OFF state to the ON state of lower than 60 mV/decade can be obtained in the subthreshold region at room temperature.
(53) Further, the operation range of the gate voltage for ON/OFF switching can be defined by low voltages.
(54) A configuration of an inversion-operation-type field-effect transistor obtained by forming a gate insulating film with a ferroelectric having a dielectric constant that changes according to an electric field intensity is known to be used for a memory operation purpose. However, there has been no report that a steep current change rate of lower than 60 mV/decade is obtained when a field-effect transistor intended for use as a switching operation purpose is constituted based on the configuration of this inversion-operation-type field-effect transistor. The reason for this is not necessarily certain. However, as a result of a computational study of the present inventors', the reason is inferred to be that in the case of the inversion layer operation, a saddle point at which the drain current becomes constant and the nonlinearly responding dielectric does not function as the gate insulating film is present in the subthreshold region, which inhibits steepening of the current change rate.
(55) This will be described by taking the characteristics plotted in
(56) As the gate voltage increases from this state (1.0 V, see the curve d in
(57) In this example, a case of a so-called N-type transistor where the gate voltage is changed in the positive direction has been described. However, the field-effect transistor of the present invention can also be applied as a so-called P-type transistor that is operated by changing the gate voltage in the negative direction. That is, also in this case, the relative dielectric constant of the gate insulating film 7 and the electric field intensity change in the same way as when the gate voltage is changed in the positive direction. Therefore, a field-effect transistor utilizing this characteristic can be obtained.
(58) An embodiment of the present invention has been described by raising as an example, the field-effect transistor 10 having the configuration represented by a SOI-type field-effect transistor obtained by disposing the gate insulating film 7 and the gate electrode 8 in this order over the channel region 5 in the semiconductor layer 9. However, the transistor configuration utilizing the characteristic of the nonlinearly responding dielectric of which the gate insulating film 7 is made is not limited to the SOI type. The field-effect transistor of the present invention may be constructed as known transistor configurations such as a bulk type that utilizes a flat surface of a crystalline substrate as a channel, a fin type in which one surface and another surface of a channel region are covered with a gate insulating film and a gate electrode that are formed in a squared-U shape, and a nanowire type in which the circumference of a cylindrical channel region is covered with a gate insulating film and a gate electrode.
(59) A simulation test was conducted for confirming the operation of the field-effect transistor described above. The simulation test was conducted by assuming a field-effect transistor 20 illustrated in
(60) The field-effect transistor 20 includes a SOI substrate obtained by laminating, in an order of reciting, an insulating layer 22 and a semiconductor layer 29 in which a source region 23, a drain region 24, and a channel region 25 are formed over a support substrate 21, a gate insulating film 27 disposed over the channel region 25, and a gate electrode 28 disposed over the gate insulating film 27.
(61) Details of the members will be described. A thickness of a semiconductor layer 29 was 8 nm. An impurity introduced into the source region 23 and the drain region 24 by ion implantation was As, and the impurity concentration was 110.sup.20/cm.sup.3. An impurity introduced into the channel region 25 by ion implantation was As, and the impurity concentration was 510.sup.18/cm.sup.3. A relative dielectric constant of the gate insulating film 27 made of the nonlinearly responding dielectric was variable in a range of from 25 through 5. A work function of the gate electrode 28 was 5.0 eV.
(62) In the simulation test, a drain current when the gate voltage was applied to the gate electrode 28 of the field-effect transistor 20 while a source electrode was maintained at 0 V and a drain electrode was maintained at 0.1 V was calculated. A simulator used for the calculation was HYENEXX ver. 5.5 developed by Selete, Inc.
(63) The result of the simulation is plotted in
(64) As plotted in
(65) The change of the relative dielectric constant of the gate insulating film 27 relative to the gate voltage, which was used for the calculation of the simulation test, will be described. As indicted by a formula (1) below, there is a relationship that the EOT of the gate insulating film 27 made of the nonlinearly responding dielectric is the minimum when the relative dielectric constant is the maximum, whereas the EOT is the maximum when the relative dielectric constant is the minimum. The change of the EOT of the gate insulating film 27 relative to the gate voltage is plotted in
EOT=.sub.SiO.sub.
(66) In the formula (1) above, T represents a physical film thickness of the gate insulating film 27, represents the dielectric constant of the gate insulating film, and .sub.SiO.sub.
(67) As described above, a drain current rising characteristic that was steeper than the current change rate in the subthreshold region at room temperature of 60 mV/decade, which is the theoretical limit in existing field-effect transistors, was obtained in the simulation test.
(68) Further, the result of a consideration about conditions for obtaining a steep drain current rising characteristic will be described below.
(69) First, a case where the EOT changing characteristic was varied will be described. From a viewpoint of obtaining a steep drain current rise, it is necessary that the relative dielectric constant largely change when the gate voltage is modulated by 0.5 V.
(70) Here, a relative dielectric constant changing condition effective for obtaining a steep drain current rise was considered based on an EOT change rate (EOT.sub.max/EOT.sub.min) of the EOT change plotted in the aforementioned
(71)
(72) As plotted in
(73) Next, a relationship between the thickness of the channel region 25 in the semiconductor layer 29 and the current change rate will be described.
(74)
(75) As plotted in
(76) Next, a relationship between the impurity concentration in the channel region 25 in the semiconductor layer 29 and the current change rate will be described.
(77)
(78) As plotted in
EXAMPLES
(79) A film formation experiment was conducted in which a film of the nonlinearly responding dielectric having the same characteristic as that of the gate insulating film 27 used in the calculation of the simulation test was actually formed. Here, a SrHfO.sub.3 film having a perovskite-type crystalline structure was formed as the film of the nonlinearly responding dielectric.
(80) First, under an Ar gas atmosphere, sputtering targeting SrO.sub.2 and HfO.sub.2 was performed on a Si substrate set in a vacuum chamber of a RF sputter system (MPS-6000-MLT available from Ulvac, Inc.) under control of the plasma power of the targets and a shutter opening/closing time, to form a SrHfO.sub.3 film having an adjusted chemical composition. Next, the Si substrate over which the SrHfO.sub.3 film was formed was subjected to a heating treatment at 1,000 C. for 10 seconds under a nitrogen gas atmosphere, to form a SrHfO.sub.3 film having a perovskite-type crystalline structure.
(81)
(82) Here, the Si substrate over which the single body film of SrHfO.sub.3 having a perovskite-type crystalline structure was formed was measured for a Sr atom depth distribution with a Rutherford backscattering analyzer (HRBS500 available from Kobe Steel, Ltd.). The result of the measurement is plotted in
(83) As plotted in
(84) In view of this fact, a HfO.sub.2 film having a thickness of 3 nm was once formed as an interfacial layer over a Si substrate, and then a SrHfO.sub.3 film having a perovskite-type crystalline structure was formed over the HfO.sub.2 film in the same manner as described above. Here, the HfO.sub.2 film was formed with a RF sputter system (MPS-6000-MLT available from Ulvac, Inc.).
(85) The result of measurement of a Sr atom depth distribution when the interfacial layer was formed measured by the Rutherford backscattering analyzer is plotted in
(86) As plotted in
(87) Hence, when the interfacial layer was formed, it was possible to suppress diffusion of the Sr atoms into the Si substrate.
REFERENCE SIGNS LIST
(88) 1, 21 support substrate 2, 22 insulating layer 3, 23 source region 4, 24 drain region 5, 25 channel region 6 interfacial layer 7, 27 gate insulating film 8, 28 gate electrode 9, 29 semiconductor layer 10, 20 field-effect transistor 31, 32 gate voltage-drain current characteristic of field-effect transistor 33 gate voltage-relative dielectric constant characteristic of field-effect transistor