METHOD FOR MAKING NANOSTRUCTURE TRANSISTORS WITH FLUSH SOURCE/DRAIN DOPANT BLOCKING STRUCTURES INCLUDING A SUPERLATTICE
20250056824 ยท 2025-02-13
Inventors
Cpc classification
H10D64/017
ELECTRICITY
H01L21/76897
ELECTRICITY
H10D62/8161
ELECTRICITY
H10D62/832
ELECTRICITY
H10D30/43
ELECTRICITY
H10D30/6713
ELECTRICITY
H10D62/8162
ELECTRICITY
H10D62/8181
ELECTRICITY
H10D30/6735
ELECTRICITY
H10D62/815
ELECTRICITY
H10D62/371
ELECTRICITY
H10D30/014
ELECTRICITY
H10D30/6757
ELECTRICITY
H10D62/822
ELECTRICITY
H10D64/256
ELECTRICITY
H10D62/10
ELECTRICITY
International classification
H01L29/66
ELECTRICITY
H01L29/15
ELECTRICITY
H01L29/417
ELECTRICITY
H01L29/775
ELECTRICITY
H01L29/786
ELECTRICITY
H01L29/06
ELECTRICITY
H01L29/08
ELECTRICITY
H01L29/161
ELECTRICITY
Abstract
A method for making a semiconductor device may include forming spaced apart gate stacks on a substrate defining respective trenches therebetween. Each gate stack may include alternating layers of first and second semiconductor materials, with the layers of the second semiconductor material defining nanostructures. The method may further include forming respective source/drain regions within the trenches, forming respective insulating regions adjacent lateral ends of the layers of the first semiconductor material, and forming respective dopant blocking superlattices adjacent lateral ends of the nanostructures and flush with adjacent surfaces of the insulating regions. Each dopant blocking superlattice may include stacked groups of layers, with each group of layers including a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.
Claims
1-20. (canceled)
21. A method for making a semiconductor device comprising: forming a plurality of spaced apart gate stacks on a substrate defining respective trenches therebetween, each gate stack comprising a plurality of layers of first and second different semiconductor materials; forming respective source/drain regions within the trenches; forming respective insulating regions adjacent lateral ends of the layers of the first semiconductor material; and forming respective dopant blocking superlattices adjacent lateral ends of the layers of the second semiconductor material and flush with adjacent surfaces of the insulating regions, each dopant blocking superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.
22. The method of claim 21 further comprising forming a respective semiconductor buffer layer between each lateral end of the layers of the second semiconductor material and the adjacent dopant blocking superlattice.
23. The method of claim 21 comprising forming a respective lateral bottom dopant blocking superlattice between the substrate and the source/drain regions, each lateral bottom dopant blocking superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.
24. The method of claim 21 wherein the first semiconductor material comprises silicon germanium.
25. The method of claim 21 wherein the second semiconductor material comprises silicon.
26. The method of claim 21 wherein the source/drain regions comprise phosphorus doped silicon (Si:P).
27. The method of claim 21 further comprising forming respective conductive contact liners in the trenches adjacent the insulating regions and dopant blocking superlattices.
28. The method of claim 27 further comprising forming a respective metal plug adjacent each conductive contact liner.
29. The method of claim 21 wherein the base semiconductor monolayers comprise silicon.
30. The method of claim 21 wherein the non-semiconductor monolayers comprise oxygen.
31. A method for making a semiconductor device comprising: forming a plurality of spaced apart gate stacks on a substrate defining respective trenches therebetween, each gate stack comprising a plurality of layers of first and second different semiconductor materials; forming respective source/drain regions within the trenches; forming respective insulating regions adjacent lateral ends of the layers of the first semiconductor material; forming respective dopant blocking superlattices adjacent lateral ends of the layers of the second semiconductor material and flush with adjacent surfaces of the insulating regions, each dopant blocking superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions; forming a respective semiconductor buffer layer between each lateral end of the layers of the second semiconductor material and the adjacent dopant blocking superlattice; and forming a respective lateral bottom dopant blocking superlattice between the substrate and the source/drain regions, each lateral bottom dopant blocking superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.
32. The method of claim 31 wherein the first semiconductor material comprises silicon germanium, and the second semiconductor material comprises silicon.
33. The method of claim 31 wherein the source/drain regions comprise phosphorus doped silicon (Si:P).
34. The method of claim 31 further comprising forming respective conductive contact liners in the trenches adjacent the insulating regions and dopant blocking superlattices.
35. The method of claim 34 further comprising forming a respective metal plug adjacent each conductive contact liner.
36. A method for making a semiconductor device comprising: forming a plurality of spaced apart gate stacks on a substrate defining respective trenches therebetween, each gate stack comprising a plurality of layers of first and second different semiconductor materials; forming respective source/drain regions within the trenches; forming respective insulating regions adjacent lateral ends of the layers of the first semiconductor material; and forming respective dopant blocking superlattices adjacent lateral ends of the layers of the second semiconductor material and flush with adjacent surfaces of the insulating regions, each dopant blocking superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.
37. The method of claim 36 further comprising forming a respective semiconductor buffer layer between each lateral end of the layers of the second semiconductor material and the adjacent dopant blocking superlattice.
38. The method of claim 36 comprising forming a respective lateral bottom dopant blocking superlattice between the substrate and the source/drain regions, each lateral bottom dopant blocking superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.
39. The method of claim 36 wherein the first semiconductor material comprises silicon germanium, and the second semiconductor material comprises silicon.
40. The method of claim 36 further comprising forming respective conductive contact liners in the trenches adjacent the insulating regions and dopant blocking superlattices.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0016]
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DETAILED DESCRIPTION
[0026] Example embodiments will now be described more fully hereinafter with reference to the accompanying drawings, in which the example embodiments are shown. The embodiments may, however, be implemented in many different forms and should not be construed as limited to the specific examples set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete. Like numbers refer to like elements throughout.
[0027] Generally speaking, the present disclosure relates to semiconductor devices having an enhanced semiconductor superlattice therein to provide performance enhancement characteristics. The enhanced semiconductor superlattice may also be referred to as an MST layer or MST technology in this disclosure.
[0028] More particularly, the MST technology relates to advanced semiconductor materials such as the superlattice 25 described further below. In prior work, Applicant theorized that certain superlattices as described herein reduce the effective mass of charge carriers and that this thereby leads to higher charge carrier mobility. See, e.g., U.S. Pat. No. 6,897,472, which is hereby incorporate herein in its entirety by reference.
[0029] Further development by Applicant has established that the presence of MST layers may advantageously improve the mobility of free carriers in semiconductor materials, e.g., at interfaces between silicon and insulators like SiO.sub.2 or HfO.sub.2. Applicant theorizes, without wishing to be bound thereto, that this may occur due to various mechanisms. One mechanism is by reducing the concentration of charged impurities proximate to the interface, by reducing the diffusion of these impurities, and/or by trapping the impurities so they do not reach the interface proximity. Charged impurities cause Coulomb scattering, which reduces mobility. Another mechanism is by improving the quality of the interface. For example, oxygen emitted from an MST film may provide oxygen to a SiSiO.sub.2 interface, reducing the presence of sub-stoichiometric SiO.sub.x. Alternately, the trapping of interstitials by MST layers may reduce the concentration of interstitial silicon proximate to the SiSiO.sub.2 interface, reducing the tendency to form sub-stoichiometric SiO.sub.x. Sub-stoichiometric SiO.sub.x at the SiSiO.sub.2 interface is known to exhibit inferior insulating properties relative to stoichiometric SiO.sub.2. Reducing the amount of sub-stoichiometric Sio.sub.x at the interface may more effectively confine free carriers (electrons or holes) in the silicon, and thus improve the mobility of these carriers due to electric fields applied parallel to the interface, as is standard practice in field-effect-transistor (FET) structures. Scattering due to the direct influence of the interface is called surface-roughness scattering, which may advantageously be reduced by the proximity of MST layers followed by anneals or during thermal oxidation.
[0030] In addition to the enhanced mobility characteristics of MST structures, they may also be formed or used in such a manner that they provide piezoelectric, pyroelectric, and/or ferroelectric properties that are advantageous for use in a variety of different types of devices, as will be discussed further below.
[0031] Referring now to
[0032] Each group of layers 45a-45n of the superlattice 25 illustratively includes a plurality of stacked base semiconductor monolayers 46 defining a respective base semiconductor portion 46a-46n and a non-semiconductor monolayer(s) 50 thereon. The non-semiconductor monolayers 50 are indicated by stippling in
[0033] The non-semiconductor monolayer 50 illustratively includes one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions. By constrained within a crystal lattice of adjacent base semiconductor portions it is meant that at least some semiconductor atoms from opposing base semiconductor portions 46a-46n are chemically bound together through the non-semiconductor monolayer 50 therebetween, as seen in
[0034] In other embodiments, more than one such non-semiconductor monolayer may be possible. It should be noted that reference herein to a non-semiconductor or semiconductor monolayer means that the material used for the monolayer would be a non-semiconductor or semiconductor if formed in bulk. That is, a single monolayer of a material, such as silicon, may not necessarily exhibit the same properties that it would if formed in bulk or in a relatively thick layer, as will be appreciated by those skilled in the art.
[0035] Applicant theorizes without wishing to be bound thereto that non-semiconductor monolayers 50 and adjacent base semiconductor portions 46a-46n cause the superlattice 25 to have a lower appropriate conductivity effective mass for the charge carriers in the parallel layer direction than would otherwise be present. Considered another way, this parallel direction is orthogonal to the stacking direction. The band modifying layers 50 may also cause the superlattice 25 to have a common energy band structure, while also advantageously functioning as an insulator between layers or regions vertically above and below the superlattice.
[0036] Moreover, this superlattice structure may also advantageously act as a barrier to dopant and/or material diffusion between layers vertically above and below the superlattice 25. These properties may thus advantageously allow the superlattice 25 to provide an interface for high-K dielectrics which not only reduces diffusion of the high-K material into the channel region, but which may also advantageously reduce unwanted scattering effects and improve device mobility, as will be appreciated by those skilled in the art.
[0037] It is also theorized that semiconductor devices including the superlattice 25 may enjoy a higher charge carrier mobility based upon the lower conductivity effective mass than would otherwise be present. In some embodiments, and as a result of the band engineering achieved by the present embodiments, the superlattice 25 may further have a substantially direct energy bandgap that may be particularly advantageous for opto-electronic devices, for example.
[0038] The superlattice 25 also illustratively includes a cap layer 52 on an upper layer group 45n. The cap layer 52 may comprise a plurality of base semiconductor monolayers 46. The cap layer 52 may have between 2 to 100 monolayers of the base semiconductor, and, more preferably between 10 to 50 monolayers.
[0039] Each base semiconductor portion 46a-46n may comprise a base semiconductor selected from the group consisting of Group IV semiconductors, Group III-V semiconductors, and Group II-VI semiconductors. Of course, the term Group IV semiconductors also includes Group IV-IV semiconductors, as will be appreciated by those skilled in the art. More particularly, the base semiconductor may comprise at least one of silicon and germanium, for example.
[0040] Each non-semiconductor monolayer 50 may comprise a non-semiconductor selected from the group consisting of oxygen, nitrogen, fluorine, carbon and carbon-oxygen, for example. The non-semiconductor is also desirably thermally stable through deposition of a next layer to thereby facilitate manufacturing. In other embodiments, the non-semiconductor may be another inorganic or organic element or compound that is compatible with the given semiconductor processing as will be appreciated by those skilled in the art. More particularly, the base semiconductor may comprise at least one of silicon and germanium, for example.
[0041] It should be noted that the term monolayer is meant to include a single atomic layer and also a single molecular layer. It is also noted that the non-semiconductor monolayer 50 provided by a single monolayer is also meant to include a monolayer wherein not all of the possible sites are occupied (i.e., there is less than full or 100% coverage). For example, with particular reference to the atomic diagram of
[0042] In other embodiments and/or with different materials this one-half occupation would not necessarily be the case as will be appreciated by those skilled in the art. Indeed it can be seen even in this schematic diagram, that individual atoms of oxygen in a given monolayer are not precisely aligned along a flat plane as will also be appreciated by those of skill in the art of atomic deposition. By way of example, a preferred occupation range is from about one-eighth to one-half of the possible oxygen sites being full, although other numbers may be used in certain embodiments.
[0043] Silicon and oxygen are currently widely used in conventional semiconductor processing, and, hence, manufacturers will be readily able to use these materials as described herein. Atomic or monolayer deposition is also now widely used. Accordingly, semiconductor devices incorporating the superlattice 25 in accordance with the embodiments may be readily adopted and implemented, as will be appreciated by those skilled in the art.
[0044] Referring now additionally to
[0045] In some device embodiments, all of the base semiconductor portions of a superlattice may be a same number of monolayers thick. In other embodiments, at least some of the base semiconductor portions may be a different number of monolayers thick. In still other embodiments, all of the base semiconductor portions may be a different number of monolayers thick.
[0046] Turning to
[0047] In some embodiments, silicon buffers 106a, 106b may optionally be epitaxially grown on the sides of the nanosheets 104 and the substrate 101 within the recess 103, respectively (
[0048] MST film and cap formation may then be performed (FIG. 4C) to define superlattices 125a and cap layers 152a on the buffers 106a, as well as a superlattice 125b and cap layer 152b on the buffer 106b (
[0049] Source/drain regions 107 may then be formed within the recesses 103 using a hard mask 108 (
[0050] Referring additionally to
[0051] It should be noted that in some embodiments the buffers 106a and/or 106b may be omitted, as the additional Si recess etching may provide sufficient surface smoothing without the buffer(s). Furthermore, formation of the cap layer 152b may occur as part of the source/drain region 107 formation (Si:P process), which does not diminish the overall area available for the source/drain region. The cap layer 152 eventually gets doped with P during this process. Additionally, in some embodiments the cap layers 152a and/or 152b may optionally be omitted. More particularly, in an example implementation the MST and Si:P formation may both advantageously occur within the same chamber in-situ, in which case MST layers without a cap layer may still provide desired blocking capabilities. The Si:P 107 may then be etched where exposed through the hard mask 108, and a metal 120 deposited thereover (
[0052] While the superlattices 125a provide similar dopant blocking capabilities (i.e., blocking the phosphorous in the source/drain regions 107 from the nanosheet 104 channel layers) to the superlattices 125a described above, the present approach may provide an additional advantage in that the buffers 106a, superlattices 125a, and cap layers 152a do not protrude into the source/drain regions 107. By way of example, this configuration may occupy significantly less source/drain area, on the order of 11-25% in some embodiments, whereas the above-described approach may create additional resistance due to the loss of available source/drain surface area, which may be undesirable in certain embodiments.
[0053] Turning to
[0054] A potential drawback of this conventional approach is that there is a relatively small amount of contact area between the contact 70 and the source/drain region 67 (i.e., only at the top of the source/drain region), which may result in relatively high contact resistance. Various example embodiments which provide for enhanced contact area, and therefore lower contact resistance, are now described. One such example embodiment is described with reference to
[0055] In some embodiments, silicon buffers 206a, 206b may optionally be epitaxially grown on the sides of the nanosheets 204 and the substrate 201 within the recess 203, respectively (
[0056] Next, spacers 212 are formed on the inside edges of the hard mask 208, allowing the Si:P to be etched such that a Si:P liner remains within the trench 203 (
[0057] Another example embodiment which provides reduced contact resistance is now described with reference to
[0058] Still another example embodiment which provides reduced contact resistance is now described with reference to
[0059] Yet another example embodiment which provides reduced contact resistance is now described with reference to
[0060] Example dimensions which may be used for one of more of the following embodiments include: gate height=63 nm; gate length (Lg)=12 nm; SiGe layer thickness=12.8 nm; and Si nanosheet thickness=5 nm. However, it will be appreciated that other dimensions are possible in different configurations, as will be appreciated by those skilled in the art.
[0061] Many modifications and other embodiments of the invention will come to the mind of one skilled in the art having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is understood that the invention is not to be limited to the specific embodiments disclosed, and that modifications and embodiments are intended to be included within the scope of the appended claims.