Method for postdoping a semiconductor wafer
09559020 ยท 2017-01-31
Assignee
Inventors
- Reinhard Ploss (Unterhaching, DE)
- Helmut Oefner (Zorneding, DE)
- Hans-Joachim Schulze (Taufkirchen, DE)
Cpc classification
H01L22/20
ELECTRICITY
H01L21/261
ELECTRICITY
H10D12/481
ELECTRICITY
H01L22/14
ELECTRICITY
H01L22/12
ELECTRICITY
H10D30/0297
ELECTRICITY
International classification
H01L29/12
ELECTRICITY
H01L21/261
ELECTRICITY
H01L21/324
ELECTRICITY
Abstract
A method for treating a semiconductor wafer having a basic doping is disclosed. The method includes determining a doping concentration of the basic doping, and adapting the basic doping of the semiconductor wafer by postdoping. The postdoping includes at least one of the following methods: a proton implantation and a subsequent thermal process for producing hydrogen induced donors. In this case, at least one of the following parameters is dependent on the determined doping concentration of the basic doping: an implantation dose of the proton implantation, and a temperature of the thermal process.
Claims
1. A method for treating a semiconductor wafer having a basic doping, comprising: determining a doping concentration of the basic doping; and adapting the basic doping of the semiconductor wafer by postdoping the semiconductor wafer comprising a proton implantation and a subsequent thermal process for producing hydrogen induced donors, wherein at least one of the following parameters is dependent on the determined doping concentration of the basic doping: an implantation dose of the proton implantation, and a temperature of the thermal process.
2. The method as claimed in claim 1, wherein the temperature during the thermal process is between 400 C. and 570 C. or between 450 C. and 550 C.
3. The method as claimed in claim 2, wherein the duration of the thermal process is between one hour and ten hours or between three hours and six hours.
4. The method as claimed in claim 1, wherein the semiconductor wafer has a first side associated with a subsequent fabrication of a completed semiconductor device thereon, and wherein the proton implantation is carried out via the first side.
5. The method as claimed in claim 4, wherein the proton implantation comprises at least two proton implantation acts in which protons are implanted with different implantation energies.
6. The method as claimed in claim 1, wherein the semiconductor wafer has a first side associated with a subsequent fabrication of a completed semiconductor device thereon, and a second side opposite the first side, and wherein the proton implantation is carried out via the second side.
7. The method as claimed in claim 1, wherein determining the doping concentration of the basic doping of the semiconductor wafer comprises a measurement of a resistivity of the semiconductor wafer.
8. The method as claimed in claim 7, wherein the semiconductor wafer is a semiconductor wafer obtained by dividing a cylindrical single crystal, and wherein the resistivity is measured after the single crystal has been divided.
9. The method as claimed in claim 7, wherein the semiconductor wafer is a semiconductor wafer obtained by dividing a cylindrical single crystal, and wherein the resistivity is measured before the single crystal is divided.
10. The method as claimed in claim 1, wherein the basic doping is an n-type basic doping.
11. The method as claimed in claim 10, wherein the basic doping is formed by phosphorus atoms.
12. The method as claimed in claim 1, wherein the basic doping is a p-type basic doping.
13. The method as claimed in claim 1, wherein the doping concentration of the basic doping is higher than 1E13 cm.sup.3.
14. The method as claimed in claim 13, wherein the doping concentration of the basic doping is higher than 1E12 cm.sup.3.
15. The method as claimed in claim 1, wherein a doping concentration of the basic doping before the adaptation is between 20% to 60% of a doping concentration after the adaptation.
16. The method as claimed in claim 1, wherein protons are implanted during the proton implantation via a first side of the semiconductor wafer into an end-of-range region of the semiconductor wafer, and wherein the thermal process is chosen such that a doping concentration added by the adaptation is approximately homogeneous in at least between 60% to at least 80% of a volume of the semiconductor wafer in a region between the end-of-range region and the first side.
17. The method as claimed in claim 16, wherein a ratio between a maximum doping concentration and a minimum doping concentration in the at least approximately homogeneously doped volume is less than 1.2.
18. The method as claimed in claim 1, wherein protons are implanted during the proton implantation via a first side of the semiconductor wafer into an end-of-range region, and wherein a portion of the semiconductor wafer is removed at least as far as the end-of-range region proceeding from a second side situated opposite the first side.
19. The method as claimed in claim 18, wherein the first side of the semiconductor wafer is associated with a subsequent fabrication of a completed semiconductor device thereon.
20. The method as claimed in claim 1, wherein a device to be manufactured on the semiconductor wafer comprises a device requiring a high dielectric strength, and wherein the resultant adapted basic doping in the semiconductor wafer results in a region that comprises a drift region of a MOSFET type device or a base region for a diode or thyristor device.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Example embodiments are explained in greater detail below with reference to drawings. These drawings serve to explain the principle, and so the drawings illustrate only those features which are necessary for understanding the principle. The drawings are not true to scale. In the drawings, unless indicated otherwise, identical reference signs designate identical features having the same meaning.
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DETAILED DESCRIPTION
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(17) The resistivity is directly dependent on the doping concentration, the resistivity decreasing if the doping concentration increases. In the example illustrated, it shall be assumed that the semiconductor rod consists of silicon and that it has a basic doping of the n-type produced by n-doping phosphorus atoms as dopant atoms. For the above-indicated values of the resistivity at the two ends, the dopant concentration at said one end is for example approximately 3E12 cm.sup.3, and at the opposite end for example approximately 2E13 cm.sup.3. In a manner corresponding to the electrical resistivity, therefore, the doping concentration over the entire length of the semiconductor rod also varies by more than a factor of 6. Furthermore, from semiconductor rod to semiconductor rod the maximum doping concentration (the minimum resistivity) and accordingly the minimum doping concentration (the maximum resistivity) also vary on account of conventional process fluctuations during the production of the doped semiconductor rods.
(18) From the semiconductor rod illustrated schematically in
(19) Since semiconductor rods produced according to the MCZ method, and hence the semiconductor wafers produced therefrom, can have a diameter of 12 inches or more, with the use of such semiconductor wafers it is possible to simultaneously produce a higher number of semiconductor components than would be the case, for example, if smaller semiconductor rods produced according to the FZ (float-zone) method were used. Therefore, it is desirable to be able to use semiconductor rods produced according to the MCZ method (or generally semiconductor rods whose doping fluctuates greatly in the longitudinal direction) for the production of semiconductor components having a high dielectric strength.
(20) A description is given below of various methods which ultimately make it possible to use such semiconductor wafers for the production of semiconductor components having a high dielectric strength. These methods require firstly determining a doping concentration of the basic doping of the individual semiconductor wafers. This process of determining the doping concentration of the basic doping can be carried out, for example, by measuring the resistivity of the individual semiconductor wafers. Optical methods for determining the doping concentration, such as, for example, the surface photovoltage method or the -PCD (Microwave Photoconductive Decay) method, are also possible.
(21) The electrical resistivity can be measured for example by means of a four-tip measurement on the semiconductor wafer.
(22) As already mentioned, the electrical resistivity is directly related to the doping concentration of the basic doping, such that the doping concentration of the basic doping can be determined on the basis of the electrical resistivity. For silicon having an n-type basic doping on the basis of phosphorus atoms, the doping concentration of the basic doping can be determined depending on the electrical resistivity for example with the aid of the diagram in Sze: Semiconductor Devices, Physics and Technology, 2.sup.nd edition, 2002, Wiley-Verlag, ISBN 0-471-33372-7, page 55, FIG. 7.
(23) As has already been mentioned above, the doping in the semiconductor rod 1 in a radial direction is approximately homogeneous, such that the doping concentration of the basic doping in the semiconductor wafer 100 is approximately homogeneous, on condition that the thickness of the semiconductor wafer 100 is small in comparison with the length l of the semiconductor rod 1. Given a length l of the semiconductor rod 1 of several 100 millimeters, such as, for example, 1000 millimeters or more, and a customary thickness of the semiconductor wafer 100 of less than 1 mm, this condition is met. The above-explained measurement of the surface resistivity, with the aim of determining the doping concentration of the basic doping, can be carried out at a plurality of locations of the front side and/or rear side 101, 102 of the semiconductor wafer 100, wherein the results thereby obtained for the surface resistivity orderived therefromthe doping concentration of the basic doping can be averaged. The result obtained by this averaging is then the determined doping concentration of the basic doping of the semiconductor wafer 100.
(24) Instead of measuring the resistivity of the semiconductor wafer 100 after the latter has been cut off from the semiconductor rod 1, there is also the possibility of measuring the resistivity of a semiconductor wafer or of a plurality of semiconductor wafers even before they are cut off from the semiconductor rod 1. Such a procedure is illustrated schematically in
(25) In the measuring method, provision is made for determining the resistivity of the semiconductor rod 1 at least one position of the semiconductor rod 1 in the longitudinal direction x, wherein the electrical resistivity determined at this position is the electrical resistivity of the semiconductor wafer that is later cut off from this position of the semiconductor rod 1.
(26) The measurement of the electrical resistivity of the semiconductor rod 1 at one position or at a plurality of positions of the semiconductor rod 1 in the longitudinal direction x thereof can be carried out by means of a four-tip measurement, for example. Referring to
(27) The method additionally provides for postdoping the semiconductor wafer taking account of the previously determined doping concentration of the basic doping such that the semiconductor wafer 100 has a defined basic doping, i.e. a defined doping concentration of the basic doping. The method provides, in particular, for performing an additional n-type doping of the semiconductor wafer 100. In the case where an n-type basic doping of the semiconductor wafer 100 is present, this additional n-type doping can serve to obtain a higher n-type doping of the semiconductor wafer. In the case where a p-type basic doping of the semiconductor wafer 100 is present, this additional n-type doping can serve to reduce a net p-type doping of the semiconductor wafer.
(28) One possible method for postdoping the semiconductor wafer 100 is illustrated schematically in
N.sub.TOT=N.sub.G+N.sub.H(1),
wherein N.sub.TOT is the total doping concentration, N.sub.G denotes the doping concentration of the basic doping, and N.sub.H denotes the doping concentration added by the postdoping.
(29) Since the basic doping N.sub.G can differ greatly for individual semiconductor wafers 100 in the manner explained, it is necessary for the doping concentration N.sub.H added by the postdoping to be adapted to the basic doping N.sub.G already present, in order to achieve a defined total doping of the semiconductor wafer 100.
(30) In the method explained above with reference to
(31) The implantation method can be carried out in such a way that protons are implanted into the semiconductor wafer 100 only with one implantation energy via one of the front and rear sides 101, 102 (this side is subsequently designated as the implantation side). A maximum of the proton concentration then initially lies at a position in a vertical direction of the semiconductor wafer 100 which is determined by the implantation energy. This position is usually designated as the end-of-range or end-of-range region of the implantation. The vertical direction of the semiconductor wafer 100 is a direction perpendicular to the front and rear sides 101, 102. During the subsequent thermal process, the protons then diffuse in the direction of the side via which the protons were implanted, and hydrogen induced donors arise from crystal defects produced by the proton irradiation in the crystal lattice of the semiconductor wafer 100 and the protons. To what extent the protons diffuse in the direction of the implantation side and how homogeneous a doping is between the end-of-range and the implantation side depends, inter alia, on the duration of the thermal process and the position of the end-of-range proceeding from the implantation side. In principle, it holds true that the doping becomes more homogeneous as the duration of the thermal process increases, i.e. as the duration of the redistribution of the protons increases.
(32) One example provides for carrying out the thermal process until the volume between the implantation side and the end-of-range has an at least approximately homogeneous doping. This should be understood to mean that at least 60% or even at least 80% of a volume of the semiconductor wafer 100 between the implantation side and the end-of-range of the implantation has an at least approximately homogeneous doping. In this connection, an at least approximately homogeneous doping is a doping for which a ratio between a maximum doping concentration and a minimum doping concentration in a volume region under consideration is less than 3, less than 2, less than 1.5 or even less than 1.2.
(33) A further method provides for carrying out a plurality of implantations via at least one of the front and rear sides 101, 102 and for varying the implantation energy in the process.
(34) In a region between the end-of-range of the implantation and the opposite side of the semiconductor wafer 100 relative to the implantation side, no crystal defects are produced by the proton implantation, such that no hydrogen induced donors are formed there (despite a possible diffusion of the protons into this region). One example of the method provides for implanting protons into the semiconductor wafer 100 both via the front side 101 and via the rear side 102, wherein the implantation energies can be chosen in particular such that the end-of-range of the implantation via one of the front and rear sides lies closer to the other of the front and rear sides than the end-of-range of the implantation via said other of the front and rear sides. In this case, crystal defects are present in all regions of the semiconductor wafer, such that an approximately homogeneous doping can be achieved over the entire wafer 100.
(35) Another example provides for carrying out implantation only via one side and for removing (thinning) the semiconductor wafer 100, proceeding from the side via which implantation was not effected, as far as the end-of-range or even including the end-of-range. After the removal, the approximately homogeneously doped region remains between the earlier end-of-range and the implantation side. The removal comprises, for example, at least one of an etching method, a grinding method and a polishing method.
(36) Two examples of a postdoping of the semiconductor wafer 100 using a proton implantation and a subsequent thermal process are explained below. For explanation purposes, it shall be assumed that a total basic doping (target doping concentration) of the semiconductor wafer of 3.6E13 cm.sup.3 is intended to be achieved over a depth of at least 120 m. This basic doping corresponds to a resistivity of 120 ohm-cm. The examples explained below specify in each case the determined basic doping of a semiconductor wafer 100 and the process parameters for the postdoping (proton dose, implantation energy and duration and temperature of the thermal process) which was carried out in order to achieve an at least approximately homogeneous doping with the target doping concentration in the semiconductor wafer 100 between the end-of-range of the implantation and the implantation side.
1st Example
(37) Determined basic doping: 3.08E13 cm.sup.3 (140 ohm-cm) Implantation energy: 4 MeV Implantation dose: 1E14 cm.sup.2 Duration of the thermal process: 10 hours Temperature of the thermal process: 505 C.
2nd Example
(38) Determined basic doping: 2.16E13 cm.sup.3 (200 ohm-cm) Implantation energy: 4 MeV Implantation dose: 1.5E14 cm.sup.2 Duration of the thermal process: 8 hours Temperature of the thermal process: 500 C.
(39) The above-explained postdoping of the semiconductor wafer 100 can be performed on the unprocessed semiconductor wafer 100, that is to say when the semiconductor wafer 100 has only the basic doping with which the semiconductor rod 1 was produced. In this case, however, there is the risk that further process steps carried out for producing components having a high dielectric strength will reduce the doping concentration of the hydrogen induced donors in an undesired manner. In one example embodiment of the method, therefore, provision is made for performing the postdoping of the semiconductor wafer 100 only when some process steps for producing a semiconductor component having a high dielectric strength have already been carried out. This is explained by way of example below with reference to
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(43) The drain region 14 and the source and body regions 13, 12 can be produced in a conventional manner by implantation and/or diffusion processes. The drift region 11 is a region having the basic doping of the semiconductor wafer 100, which before the postdoping is given only by the doping of the semiconductor rod 1. In the example illustrated, the gate electrodes 21 are trench electrodes, that is to say electrodes arranged in trenches of the semiconductor wafer 100. Such gate electrodes 21 can be produced in a conventional manner by producing trenches, producing a gate dielectric 22 on sidewalls and on the bottom of the trenches and by producing gate electrodes 21 on the gate dielectric layer 22. It goes without saying that other gate topologies, such as a planar gate electrode, for example, can also be provided.
(44) During the postdoping, in the manner explained, protons are implanted into the semiconductor wafer 100 via at least one of the front and rear sides 101, 102 and then the thermal process for producing the hydrogen induced donors is carried out. In one example, the proton implantation is carried out via the front side 101 in such a way that the maximum of the proton concentration directly after the implantation, i.e. the end-of-range, is near the drain zone 14 or in the drain zone. In this case, during the thermal process the protons diffuse in the direction of the front side 101 and bring about an approximately homogeneous postdoping of the drift zone 11. During this process, the body zone 12, the source zone 13 and the drain zone 14 can also be postdoped. However, the doping concentrations of these semiconductor zones are usually greater than the desired doping concentration of the postdoping by a multiple, such that the postdoping does not significantly influence the doping concentrations of these semiconductor zones 12, 13, 14. In this regard, the doping concentration of the drain zone 14 and of the source zone 13 lies above 10.sup.19 cm.sup.3, for example, and the doping concentration of the body zone 12 lies above 10.sup.16 cm.sup.3, for example, while the desired doping concentration of the postdoping lies in the range of between 10.sup.13 cm.sup.3 and 10.sup.14 cm.sup.3, for example.
(45) The MOS transistor component produced on the basis of the semiconductor wafer 100 in accordance with
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(47) A further example embodiment provides for implanting protons via the rear side 102 or protons via the front and rear sides 101, 102. In this case, the metallization 31 is produced after the postdoping has been carried out. The same correspondingly applies to metallizations in the region of the front side 101 which form the later gate terminal and the later source terminal of the component.
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(49) This method provides for thinning the semiconductor wafer after the postdoping proceeding from the rear side 102.
(50) This region between the rear side 102 and the end-of-range region 110 or between the rear side 102 and including the end-of-range region is subsequently removed by the removal of the semiconductor wafer 100 proceeding from the rear side 102. The reference sign 102 in
(51) As an alternative to the method explained with reference to
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(53) As also in the case of the example embodiment explained above with reference to
(54) The doping concentration of the p-type emitter 42 and of the n-type emitters 43 is for example in the range of the doping concentration of the source and drain regions 13, 14 of the component in accordance with
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(57) In the method explained, the total doping concentration of the semiconductor wafer is composed of the original doping concentration resulting from the process for producing the semiconductor wafer 100 or the semiconductor rod 1 and the doping concentration added by the postdoping. One example of the method provides for the original basic doping concentration already to make up at least 20%, at least 40% or at least 60% of the total doping concentration. Correspondingly, the postdoping contributes a maximum of 80%, a maximum of 60% or a maximum of 40% to the total doping concentration after the postdoping has been carried out. The presence of a basic doping of the order of magnitude mentioned above has the result that parasitic effects, such as, for example, the presence of oxygen in the semiconductor wafer, have a less disturbing effect than in a comparative case in which, proceeding from an intrinsic semiconductor wafer, the doping is brought about only by hydrogen induced donors. Moreover, the costs of the postdoping are lower than in a method in which, proceeding from an intrinsic semiconductor wafer, the doping is brought about only by hydrogen induced donors, since the required proton implantation dose is significantly lower than for the case of a pure proton doping.
(58) As an alternative or in addition to a postdoping comprising a proton implantation and a thermal process, a postdoping of the semiconductor wafer 100 can also be effected by means of a neutron irradiation. During the irradiation of a semiconductor wafer 100 consisting of silicon with neutrons, radioactive silicon-31 (31 Si) arises, which decays to n-doping phosphorus with a half-life of approximately 2.6 hours and with emission of beta radiation. In this method, the doping concentration of the postdoping can be set by means of the irradiation dose of the neutrons. For the total doping after carrying out such a postdoping method using a neutron irradiation, the following holds true:
N.sub.TOT=N.sub.G+N.sub.N(2),
wherein N.sub.TOT is the total basic doping after the postdoping has been carried out, N.sub.G is the basic doping before the postdoping and N.sub.N is the postdoping brought about by the neutron implantation.
(59) Referring to
(60) Since neutrons penetrate far into the semiconductor wafer even with a comparatively low implantation energy, there is also the possibility of carrying out the postdoping for a plurality of semiconductor wafers simultaneously, which jointly form a monocrystalline portion of the original semiconductor rod 1.
(61) Since a thermally stable n-type doping results from the neutron implantation, the postdoping using the neutron implantation can already be carried out on the end process semiconductor wafer 100, i.e. before implantation and/or diffusion processes for producing active component regions are actually carried out. Optionally, a specific heat treatment step for activating the phosphorus doping and for annealing the radiation damage can be carried out, wherein the temperatures can be between 800 C. and 1000 C. and the duration is one or more hours, for example. However, it is also possible to use for this purpose temperature steps which are carried out during the production of a semiconductor component for other purposes, such as, for example, for activating or indiffusing implanted dopants.
(62) The method explained above makes it possible to individually adapt the doping concentration of a semiconductor wafer which already has a basic doping.
(63) In the method, there is the possibility, in particular, of setting different total dopings for different semiconductor wafers from a semiconductor rod, depending on the requirement. In this regard, by way of example, semiconductor wafers having a low basic doping can be postdoped such that they have a first total doping concentration, while semiconductor wafers which already have a higher basic doping can be postdoped such that they have a second total doping concentration, higher than the first total doping concentration. The individual wafers from a rod can be grouped, for example, wherein the dopings of the wafers of the different groups are adapted to different total doping concentrations, for example.