MICROELECTRONIC ASSEMBLIES FORMED USING METAL SILICIDE, AND METHODS OF FABRICATION
20170018517 ยท 2017-01-19
Assignee
Inventors
Cpc classification
H01L2224/804
ELECTRICITY
H01L2224/73204
ELECTRICITY
H01L2224/0401
ELECTRICITY
H01L25/0652
ELECTRICITY
H01L2224/9202
ELECTRICITY
H01L2224/80896
ELECTRICITY
H01L2224/08237
ELECTRICITY
H01L2224/80486
ELECTRICITY
H01L2224/97
ELECTRICITY
H01L24/82
ELECTRICITY
H01L2224/80896
ELECTRICITY
H01L24/80
ELECTRICITY
H01L2224/80001
ELECTRICITY
H01L24/89
ELECTRICITY
H01L21/486
ELECTRICITY
H01L2224/80895
ELECTRICITY
H01L2224/97
ELECTRICITY
H01L23/5226
ELECTRICITY
H01L2224/82
ELECTRICITY
H01L2224/82
ELECTRICITY
H01L2224/80001
ELECTRICITY
H01L2224/80487
ELECTRICITY
H01L23/49827
ELECTRICITY
International classification
H01L23/498
ELECTRICITY
Abstract
Two microelectronic components (110, 120), e.g. a die and an interposer, are bonded to each other. One of the components' contact pads (110C) include metal, and the other component has silicon (410) which reacts with the metal to form metal silicide (504). Then a hole (510) is made through one of the components to reach the metal silicide and possibly even the unreacted metal (110C) of the other component. The hole is filled with a conductor (130), possibly metal, to provide a conductive via that can be electrically coupled to contact pads (120C.B) attachable to other circuit elements or microelectronic components, e.g. to a printed circuit board.
Claims
1-20. (canceled)
21. A fabrication method comprising: providing a first structure comprising circuitry comprising one or more contact pads each of which comprises metal, the first structure comprising first dielectric surrounding each contact pad; providing a substrate comprising a first side comprising one or more silicon regions each of which is surrounded by second dielectric; attaching the first structure to the substrate so that the first dielectric physically contacts the second dielectric and so that at least a portion of the metal of each contact pad reacts with at least a portion of the silicon of a corresponding silicon region to form metal silicide.
22. The method of claim 21, comprising bonding the first dielectric with the second dielectric.
23. The method of claim 22 wherein each of the first dielectric and the second dielectric is silicon dioxide.
24. The method of claim 22, wherein the bonding overlaps in time with a silicidation operation in which at least said portion of the metal of each contact pad reacts with at least said portion of the silicon of the corresponding silicon region to form said metal silicide.
25. The method of claim 21 wherein in said attaching, a first surface of each contact pad meets a first surface of at least one corresponding silicon region of the substrate to form said metal silicide; and immediately prior to said attaching, the first surface of each contact pad is level with at least one surface of the first dielectric.
26. The method of claim 21 wherein in said attaching, a first surface of each contact pad meets a first surface at least one corresponding silicon region of the substrate; and immediately prior to said attaching, the first surface of each silicon region is level with at least one surface of the second dielectric.
27. The method of claim 21 wherein immediately prior to said attaching, at least one said contact pad protrudes out of the first dielectric.
28. The method of claim 21 wherein immediately prior to said attaching, the first substrate comprises a circuit element and a conductive path connected to the circuit element; and in said attaching, the conductive path becomes connected to said metal silicide, connecting the metal silicide to the circuit element.
29. The method of claim 28 wherein the circuit element is a transistor.
30. The method of claim 21 further comprising, after said attaching: forming one or more holes in a second side of the substrate, the second side being opposite to the first side, each hole reaching the metal silicide formed by reacting at least a portion of the metal of the corresponding contact pad; and forming a conductive via in each hole, the conductive via reaching at least one of the metal of the corresponding contact pad and the corresponding metal silicide.
31. A microelectronic component comprising: a substrate comprising one or more silicon regions at a top side of the substrate; and a first structure comprising circuitry comprising one or more contact pads at a bottom side of the first structure, wherein each said contact pad comprises metal and overlies at least one corresponding silicon region at the top side of the substrate; wherein for each said contact pad, the microelectronic component comprises: a metal silicide region underlying and physically contacting the contact pad and overlying and physically contacting the corresponding silicon region, wherein the metal silicide is a compound of silicon and the same metal as present in the contact pad; and a dielectric region surrounding and physically contacting the contact pad, the metal silicide region, and the silicon region.
32. The microelectronic component of claim 31 wherein: for each contact pad, the first structure comprises a first dielectric region surrounding and physically contacting the contact pad; for each silicon region, the substrate comprises a second dielectric region surrounding and physically contacting the silicon region; and each said dielectric region comprises at least one said first dielectric region and at least one said second dielectric region.
33. The microelectronic component of claim 32 wherein for at least one said contact pad, the dielectric region is silicon dioxide.
34. The microelectronic component of claim 31 wherein the first substrate comprises a circuit element and a conductive path interconnecting the circuit element and the metal silicide.
35. The microelectronic component of claim 34 wherein the circuit element is a transistor.
36. The microelectronic component of claim 31 wherein the one or more silicon regions are a plurality of silicon regions which are electrically insulated from each other.
37. The microelectronic component of claim 31 further comprising, for at least one said contact pad, a metal via electrically coupled to at least one said contact pad and extending down through the corresponding silicon region.
38. The microelectronic component of claim 37 wherein the metal via is connected to a contact pad on a bottom of the substrate.
39. The microelectronic component of claim 37 wherein the metal via is located in a hole extending down through the corresponding silicon region.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0015]
[0016]
[0017]
[0018]
DESCRIPTION OF SOME EMBODIMENTS
[0019] The embodiments described in this section illustrate but do not limit the invention. The invention is defined by the appended claims.
[0020] In this disclosure, the term conductive means electrically conductivity unless stated otherwise. Similarly, insulator means electrical insulation unless stated otherwise. The term dielectric means any electrical insulator, not necessarily with a high dielectric constant.
[0021]
[0022] The die or module 110 can be fabricated using conventional processes, or a conventionally-fabricated die or module can be further processed to provide the desired metal of sufficient thickness at the top of contact pads 110C. For example,
[0023] Of note, metal 320 may initially cover passivation 210, but can be removed from over passivation 210 by chemical mechanical polishing (CMP) or a suitable etch or some other process. These examples are not limiting.
[0024]
[0025] In exemplary embodiments, the structure of
[0026] As shown in
[0027] Optionally (
[0028] As shown in
[0029] Then (
TABLE-US-00001 TABLE 1 Silicidation Parameters Sintering Heating Silicide Silicide Metal Silicide T time thickness resistivity 110C 504 ( C.) (minutes) (nm) (cm) Nickel NiSi 400-600 30 sec. to 10 nm 14-20 10 min. Cobalt Co.sub.2Si 300-500 30 sec. to 10 nm 70 10 min. Cobalt CoSi 400-600 30 sec. to 10 nm 100-150 10 min. Platinum PtSi 250-400 30 sec. to 10 nm 28-35 10 min.
[0030] Other metals and process parameters are possible, including those in well-known silicidation processes. Multiple die or MCMs can be attached to the interposer by silicidation simultaneously or at different times, e.g. one by one. The structures 110 can be any microelectronic components, possibly a whole wafer, such as a monolithic wafer or a reconstituted wafer, i.e. a wafer reconstituted from individual die held together by an adhesive such as an organic encapsulant; see e.g. U.S. Pat. No. 7,901,989 issued Mar. 8, 2011 to Haba et al. and incorporated herein by reference. (Of note, the die fabrication steps described above in connection with
[0031] As seen in
[0032] If desired (
[0033] For simplicity, the handle wafer 506 and the encapsulant 508 are not shown in subsequent drawings.
[0034] If desired, support 420 may be thinned at this stagesupport 420 may have been initially thick to provide greater mechanical strength and heat dissipation at the previous fabrication stages. In some embodiments, support 420 is entirely removed to expose the dielectric 430 on the bottom. In some embodiments, dielectric 430 is also thinned or entirely removed. This thinning or removal of the support or the dielectric is not represented in
[0035] Then (
[0036] In some embodiments, a separate hole 510 is made through each silicon island 410.
[0037] In the embodiment shown, at each contact pad 110C, the hole 510 is laterally surrounded by corresponding silicide 504 and silicon region 410, as illustrated in insert A (showing the top view). However, the holes can be laterally shifted relative to the regions 504 and 510 and can have any shape, as illustrated in insert B (top view). Also, a hole 510 can be wide enough to consume all of the corresponding silicide 504 and silicon 410. The wide holes are discussed in more detail below.
[0038] Dielectric 520 (
[0039] Conductor 130 (
[0040] Conductor 130 can be any suitable material. For example, metal can be used that has low resistivity and forms a low resistivity metallurgical junction with the surface of contact pads 110C; if the contact pads' metal is copper or nickel, then conductor 130 can be copper. Known deposition techniques can be used for conductor 130, including CVD, electroless plating, electroplating, or a combination of these and possibly other techniques. If excess metal 130 is formed on the bottom of substrate 404 (i.e. of support 420), such metal can be removed by CMP, etching, and/or other techniques or combination of techniques. Alternatively, some of the metal 130 on the bottom can be patterned to provide some or all of RDL lines 140L (
[0041] Subsequent fabrication can be conventional. For example, in some embodiments, no RDL is formed on the bottom, but the bottom ends of conductive vias 130 provide the interposer's bottom contact pads (like 120C.B in
[0042] Many variations are possible. For example, support 420 and/or silicon regions 410 may include circuitry with transistors, capacitors, inductors, or other elements, and this circuitry can be connected to die 110 or interposer contact pads 120C.B. One example is shown in
[0043] As seen from the above, in the embodiments of
[0044] Then (
[0045] Another possible isolation technique is PN junction isolation. More particularly, in
[0046] A still another possibility, not relying on layer 430, is to remove the portion of substrate 404 below the regions 410. This can be done by substrate thinning similar to the process described above in connection with
[0047] Then fabrication proceeds as described above up to the stage of
[0048] Then (
[0049] Subsequent fabrication can be as described above (formation of holes 510 and vias 130 through islands 410, etc.).
[0050] A still another possibility avoiding formation of layer 430 is to remove the unreacted silicon 410. For example, in some embodiments, fabrication proceeds to obtain the structure of
[0051] The invention is not limited to the embodiments described above, and in particular to any dimensions or processes, except as defined by the claims. For example, in substrate 404 of
[0052] Silicon regions 410 can be pure silicon or may contain impurities. They consist essentially of silicon in the sense that they can react with metal to form metal silicide to provide a suitable bond. Metal silicide regions 504 also do not have to be pure metal silicide but they provide a suitable bond as needed. For example, in some embodiments, silicon regions 410 are at least 90% by atomic weight silicon before silicidation, and metal silicide regions 504 are at least 90% by atomic weight metal silicide.
[0053] Likewise, metal regions such as contact pads 110C or conductive vias 130 may contain non-metal impurities but they consist essentially of metal to provide the corresponding electrical conductivity. For example, in some embodiments, the impurities change the electrical conductivity by at most 10%, and/or the impurities are at most 10% by weight.
[0054] Thus, the terms silicon regions, metal silicide regions, and metal regions mean consisting essentially of silicon, metal silicide, or metal respectively as defined above.
[0055] The vias 130 are shown as vertical, i.e. with vertical sidewalls, but they may have sloped sidewalls or sidewalls having any shape. In some embodiments, each via 130 has a vertical portion (e.g. a center portion) extending along the entire via.
[0056] Some embodiments are defined by the following clauses:
[0057] Clause 1 defines a fabrication method comprising:
[0058] providing a first structure (e.g. die or wafer 110) comprising circuitry comprising one or more contact pads (e.g. 110C) each of which comprises metal;
[0059] providing a substrate (e.g. 404) comprising a first side comprising one or more silicon regions (e.g. 410), the substrate also comprising a second side opposite to the first side;
[0060] attaching the first structure to the substrate so that at least a portion of the metal of each contact pad reacts with at least a portion of the silicon of a corresponding silicon region to form metal silicide;
[0061] forming one or more holes (e.g. 510) in the second side of the substrate, each hole reaching the metal silicide formed by reacting at least a portion of the metal of the corresponding contact pad; and
[0062] forming a conductive via (e.g. 130) in each hole, the conductive via reaching the metal of the corresponding contact pad and/or reaching the corresponding metal silicide, the conductive via extending to the substrate's surface at the second side of the substrate.
[0063] Clause 2 defines the method of clause 1 wherein each hole, and the corresponding conductive via, pass at least part way through the metal silicide.
[0064] Clause 3 defines the method of clause 1 wherein each hole passes through the metal silicide, and the corresponding conductive via reaches an unreacted metal of the corresponding contact pad.
[0065] Clause 4 defines the method of clause 1 wherein:
[0066] providing the first structure comprises providing dielectric (e.g. 450) surrounding each contact pad;
[0067] providing the substrate comprises providing dielectric (e.g. 210) surrounding each silicon region; and
[0068] the method further comprises bonding the dielectric surrounding each contact pad with the dielectric surrounding each silicon region.
[0069] Clause 5 defines the method of clause 4 wherein the bonding overlaps in time with a silicidation operation in which at least said portion of the metal of each contact pad reacts with at least said portion of the silicon of the corresponding silicon region to form said metal silicide.
[0070] Clause 6 defines the method of clause 1 wherein the substrate comprises a non-dielectric region (e.g. below 430) and a dielectric region (e.g. 430) separating the one or more silicon regions from the non-dielectric region.
[0071] Clause 7 defines the method of clause 1 wherein providing the substrate comprises:
[0072] providing a second structure (e.g. support 420 and dielectric 430) comprising a dielectric surface (e.g. top surface of 430); and
[0073] forming the one or more silicon regions on the dielectric surface.
[0074] Clause 8 defines the method of clause 1 wherein providing the substrate comprises:
[0075] providing a silicon substrate (e.g. 404 in
[0076] removing part of the silicon substrate to form one or more protrusions at the first side of the silicon substrate, each protrusion comprising one of the one or more silicon regions.
[0077] Clause 9 defines the method of clause 8 wherein the one or more silicon regions are a plurality of the silicon regions, and the method further comprises implanting a species into the silicon substrate to electrically insulate the silicon regions from each other.
[0078] Clause 10 defines the method of clause 1 wherein providing the substrate comprises:
[0079] providing a silicon substrate; and
[0080] forming dielectric (e.g. 450) at a top of the silicon substrate, the substrate comprising one or more silicon regions each of which has a top surface bordering on the dielectric.
[0081] Clause 11 defines the method of clause 10 wherein the one or more silicon regions are a plurality of silicon regions whose top surfaces are separated from each other by the dielectric.
[0082] Clause 12 defines the method of clause 1 further comprising, after attaching the first structure to the substrate, thinning the substrate from the second side to expose each silicon region at the second side (see
[0083] Clause 13 defines the fabrication method of clause 1 wherein the one or more silicon regions are a plurality of the silicon regions electrically insulated from each other.
[0084] Clause 14 defines a microelectronic component comprising:
[0085] a first structure (e.g. 110) comprising circuitry comprising one or more metal regions (e.g. 110C) at a bottom of the first structure;
[0086] for each metal region, [0087] at least one corresponding silicon region (e.g. 410); [0088] at least one metal silicide region physically contacting the metal region and the corresponding silicon region; [0089] at least one conductive via reaching the corresponding metal region and/or the corresponding metal silicide region from below the silicon region;
[0090] the microelectronic component further comprising, at its bottom side, one or more contact pads for attachment to circuitry, each of the one or more contact pads being electrically coupled to at least one of the one or more conductive vias.
[0091] Clause 15 defines the assembly of clause 14 wherein each conductive via passes through the corresponding metal silicide region and reaches the corresponding metal region.
[0092] Clause 16 defines the assembly of clause 14 or 15 wherein each conductive via passes through the corresponding silicon region.
[0093] Clause 17 defines the assembly of clause 14, 15, or 16 wherein each conductive via is made essentially of metal.
[0094] Clause 18 defines the assembly of clause 14, 15, 16, or 17 wherein the one or more silicon regions are formed on a dielectric layer, and each conductive via passes through the dielectric layer.
[0095] Clause 19 defines the assembly of clause 14, 15, 16, 17, 18, or 19 wherein the one or more silicon regions are a plurality of silicon regions electrically insulated from each other.
[0096] Clause 20 defines the assembly of clause 14, 15, 16, 17, 18, or 19 wherein the one or more silicon regions are electrically insulated from each conductive via.
[0097] Clause 21 defines the assembly of clause 14, 15, 16, 17, 18, 19, or 20 wherein each conductive via comprises a vertical portion extending along the entire conductive via.
[0098] Other embodiments and variations are within the scope of the invention, as defined by the appended claims.