Transistor having blocks of source and drain silicides near the channel
11631739 · 2023-04-18
Assignee
Inventors
- Fabrice Nemouchi (Grenoble, FR)
- Antonio Lacerda Santos Neto (Grenoble, FR)
- Francois Lefloch (Grenoble, FR)
Cpc classification
H01L21/823418
ELECTRICITY
H10N60/128
ELECTRICITY
H01L21/28097
ELECTRICITY
International classification
H01L29/08
ELECTRICITY
H01L21/28
ELECTRICITY
H01L21/324
ELECTRICITY
H01L21/8234
ELECTRICITY
Abstract
A method for producing a transistor includes producing on a substrate provided with a semiconductor surface layer in which an active area can be formed, a gate block arranged on the active area. Lateral protection areas are formed against lateral faces of the gate block. Source and drain regions based on a metal material-semiconductor material compound are formed on either side of the gate and in the continuation of a portion located facing the gate block. Insulating spacers are formed on either side of the gate resting on the regions based on a metal material-semiconductor material compound.
Claims
1. A method for producing a transistor comprising the steps of: producing, on a substrate provided with a semiconductor surface layer wherein an active area is capable of being formed, a gate block arranged on the active area, forming lateral protection areas against lateral faces of the gate block, depositing at least one layer of metal material so as to cover the gate block, the lateral protection areas and the active area and carrying out at least one thermal annealing so as to form, in the active area, regions based on metal material-semiconductor material compound on either side of the gate block and in a continuation of a portion of the semiconductor surface layer located facing the gate block, the portion being capable of forming a transistor channel, the thermal annealing being provided, in terms of duration, such that an interface between one or more of the regions based on a metal material-semiconductor material compound and the semiconductor portion is located vertically to the lateral protection areas or beneath and facing the lateral protection areas, the regions based on a metal material-semiconductor material compound being capable of respectively forming transistor source and drain regions, then forming insulating spacers on either side of the gate block and resting on the regions based on a metal material-semiconductor material compound.
2. The method according to claim 1, wherein the insulating spacers are produced against and in contact with the lateral protection areas.
3. The method according to claim 1, wherein the substrate is of a semiconductor-on-insulator type and is provided with an insulating layer on which the semiconductor surface layer rests, the thermal annealing is provided, in terms of duration, such that the metal material-semiconductor material compound is formed on either side of the lateral protection areas over an entire thickness of the active area, whereby the regions based on the metal material-semiconductor material compound are thus in contact with the insulating layer of the substrate.
4. The method according to claim 1, wherein the lateral protection areas have a low thickness, which is less than 5 nm, and preferably lies in the range 1 to 2 nm.
5. The method according to claim 4, wherein the lateral protection areas have a uniform thickness on the lateral faces of the gate block.
6. The method according to claim 1, wherein the lateral protection areas are foil led by conformal deposition of a protection layer on the gate block then by anisotropic removal of the protection layer.
7. The method according to claim 6, wherein the protection layer is in particular made of silicon nitride, and whereby the anisotropic removal of the protection layer comprises steps of: implanting, one of helium and hydrogen, a part of the protection layer located on a top face of the gate block and parts which extend on either side of the gate block parallel to the active area, the implantation preferably being carried out using at least one vertical beam which extends parallel to a normal to a main plane of the substrate, and selectively the etching the implanted parts of the protection layer.
8. The method according to claim 1, wherein the gate includes at least one semiconductor tip and wherein, prior to the formation of the lateral protection areas, a hard mask is formed on a top face of the tip of the gate block, the hard mask being preserved during the deposition of the layer of metal material in order to cover the gate block, the lateral protection areas and the active area, the method comprising, after the formation of insulating spacers: forming at least one masking layer around the gate block and so as to reveal the hard mask, removing the hard mask so as to reveal the top face of the gate block, depositing at least one metal or metal alloy layer on the top face of the gate block, and carrying out at least one annealing so as to form an area based on a metal-semiconductor compound on the top face of the gate block.
9. The method according to claim 8, wherein the masking layer is formed by at least one stressing layer produced on the insulating spacers.
10. The method according to claim 1, wherein the metal material is formed of Pt, Nb, Co, V or of a rare earth.
11. The method according to claim 1, wherein the regions based on the metal material-semiconductor material compound are capable of adopting superconducting properties.
12. The method according to claim 1, wherein: the substrate is of a semiconductor-on-insulator type and is provided with an insulating layer on which the semiconductor surface layer rests, and the thermal annealing comprises forming the metal material-semiconductor material compound on either side of the lateral protection areas through the semiconductor surface layer in contact with the lateral protection areas and with the insulating layer of the substrate.
13. The method according to claim 1, comprising forming the lateral protection areas in contact with the lateral faces of the gate block.
14. A transistor structure comprising: an active area formed in a semiconductor surface layer of a substrate, a gate block arranged on the active area, lateral protection areas disposed against lateral faces of the gate block, regions based on a metal material-semiconductor material compound disposed on either side of the gate block and in a continuation of a portion of the active area which is located facing the gate block, the portion being capable of forming a transistor channel, and the regions based on a metal material-semiconductor material compound respectively forming transistor source and drain regions, and insulating spacers disposed on either side of the gate block and in contact with the regions based on a metal material-semiconductor material compound, wherein an interface between one or more of the regions based on a metal material-semiconductor material compound and the portion is located vertically to the lateral protection areas or beneath and facing the lateral protection areas.
15. The transistor structure according to claim 14, wherein the insulating spacers are disposed in contact with the lateral protection areas.
16. The transistor structure according to claim 14, wherein the substrate is a semiconductor-on-insulator type substrate and is provided with an insulating layer on which the semiconductor surface layer rests, the regions based on a metal material-semiconductor material compound being arranged on either side of the lateral protection areas over an entire thickness of the active area, whereby the regions based on a metal material-semiconductor material compound are thus in contact with the insulating layer of the substrate.
17. The transistor structure according to claim 14, wherein the transistor is a JoFET type transistor and/or the regions being based on a metal material-semiconductor material compound having superconducting properties.
18. A method for producing a transistor comprising the steps of: producing, on a substrate provided with a semiconductor surface layer forming an active area, a gate block arranged on the active area, forming lateral protection layers against lateral faces of the gate block, depositing at least one layer of metal material so as to cover the gate block, the lateral protection layers and the active area, carrying out at least one thermal annealing so as to form regions based on metal material-semiconductor material compound on either side of the gate block in physical contact with the lateral protection layer and the active area, and forming insulating spacers on either side of the gate block over the lateral protection layers and the regions after the at least one thermal annealing.
19. The method according to claim 18, wherein the thermal annealing comprises forming the regions on either side of the lateral protection layer partially through the semiconductor surface layer.
20. The method according to claim 18, wherein: the substrate is of a semiconductor-on-insulator type and is provided with an insulating layer on which the semiconductor surface layer rests, and the thermal annealing comprises forming the regions through the semiconductor surface layer in contact with the lateral protection areas and with the insulating layer of the substrate.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The present invention will be better understood after reading the following description of example embodiments, given for purposes of illustration only and not intended to limit the scope of the invention, and with reference to the accompanying figures, wherein:
(2)
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(7) Identical, similar or equivalent parts in the different figures bear the same reference numerals in order to ease the passage from one figure to another.
(8) The different parts shown in the figures are not necessarily displayed according to a uniform scale in order to make the figures easier to read.
(9) Moreover, in the description below, the terms that depend on the orientation of the structure, such as “top”, “surface”, “lateral” apply for a structure that is considered to be oriented in the manner illustrated in the figures.
Detailed Description of Specific Embodiments
(10) One example method for producing source and drain areas made of a semiconductor-metal compound and which are near the channel area will now be given with reference to
(11) The transistor produced can be, for example, of the JoFET (Josephson Field Effect Transistor) type, in other words a field-effect transistor for which the coupling between two regions of superconductor materials can be modulated by an electrostatic gate.
(12) In the example shown in
(13) The substrate 1 thus comprises a semiconductor carrier layer 2 coated in an insulating layer 3, for example a buried silicon oxide (BOX), covering the carrier layer 2, itself coated in at least one semiconductor surface layer 4, for example made of silicon.
(14) The thickness e.sub.3 of the insulating layer 3 of the substrate can lie in the range 10 to 50 nm for example, and in particular in the range 20 to 30 nm for FDSOI technology. The thickness e.sub.4 of the semiconductor surface layer 4 can lie in the range 3 to 30 nm for example, and in particular in the range 6 to 10 nm for a JoFET.
(15) In the semiconductor surface layer 4, an active transistor area 4a is defined, in this example by etching so as to remove certain portions of the semiconductor surface layer 4 and reveal certain areas of the carrier layer 2 located around the active area 4a.
(16) Around the active area 4a, insulating areas 14, in particular of the STI (shallow trench isolation) type are typically produced. For this purpose, an insulating layer 12 formed, for example, by a stack of silicon oxide and of silicon nitride, can be deposited in trenches around the active area 4a. Then, filling is carried out using insulating material 13 such as silicon oxide. This filling can be followed by a CMP step removing the excess insulating material 13 then by the removal of the insulating layer 12 on the active area 4a.
(17) The active area 4a intended to receive at least one channel region of the transistor is covered with a gate dielectric 7, for example SiO.sub.2 or HfO.sub.2 and a gate material 9, for example based on polysilicon, wherein a gate dielectric area and a gate block are respectively defined. For a JoFET, a gate of critical dimension dc (dimension measured parallel to the plane [O; x; y] of the orthogonal coordinate system [O; x; y; z] given in
(18) The active area 4a projects from the gate block 9 such that revealed regions of the active area 4a extend on either side of the lateral faces 9c of the gate. The length Ld of this projection can lie in the range 10 nm to 100 nm for example.
(19) In the specific example embodiment shown in
(20) In this example embodiment, after having defined the gate block 9, this hard mask 11 is retained. Protection areas are then formed against lateral faces 9c of the gate block 9.
(21) For this purpose, oxidation of the lateral faces 9c can be carried out and areas of polysilicon oxide, for example, can thus be produced. An oxide thickness that lies in the range 2 nm to 4 nm for example can be obtained on the lateral faces 9c, which typically corresponds to a polysilicon consumption of 1 nm to 2 nm. A step of deoxidising the active area 4a can then be carried out. This deoxidation can be implemented by way of a plasma method, preferably using an anisotropic plasma, such as an Ar plasma. Such deoxidation allows source and drain areas to be revealed while preserving the lateral faces 9c covered with protection oxide. Such a deoxidation step can, according to one specific embodiment, correspond to a cleaning step that is carried out at a later time, typically immediately before a step of depositing a metal layer for silicidation of the source and drain areas.
(22) Alternatively and advantageously, the production of the lateral protection areas comprises the deposition of a thin protection layer 15 so as to cover the gate block 9 (
(23) Etching is then carried out (
(24) These lateral protection areas 15c are typically formed with a thickness that is less than that conventionally provided for producing spacers, in other words blocks capable of preventing electrostatic coupling between on the one hand the gate and on the other hand the source and drain regions and/or contacts. The thickness of the protection layer 15 can be, for example, between 1 nm and 5 nm, preferably between 1 and 2 nm.
(25) One manner of carrying out anisotropic etching of the protection layer 15 consists, as shown in
(26) By carrying out implantation using a beam oriented parallel to a normal n to a main plane of the substrate (plane defined as passing through the substrate and parallel to the plane [O; x; y] of the orthogonal coordinate system [O; x; y; z] given in
(27) After formation of the lateral protection areas 15c, deposition of a metal material layer 17 (
(28) The metal material 17 is capable of forming a metal-semiconductor compound such as a silicide. The metal material can in particular be a rare earth or at least based on a metal chosen from the following group of metals: Pt, V, Co, or Nb. Advantageously, in this example embodiment, a silicide is chosen that is capable, in certain phases, of having the properties of a superconductor.
(29) The metal layer 17 is typically deposited over the entire surface of the substrate, and in particular covers the regions of the active area 4a that are revealed and that project either side of the lateral protection areas 15c.
(30) At least one thermal annealing process is then carried out allowing a compound to be formed between the metal of the metal layer 17 and the semiconductor material of the active area 4a. In particular, at least one rapid thermal anneal (RTA) and/or at least one laser anneal can be carried out.
(31) For example, for an active area 4a having a thickness of 25 nm and when the layer 17 has a thickness of 10 nm, RTA-type annealing can be carried out at a temperature that can lie in the range 450° C. to 550° C., for a duration that can be between 10 s and 120 s for example.
(32) The lateral protection areas 15c disposed between the metal layer 17 and the gate 9 allow the gate 9 to be preserved and prevent the formation of a compound on the lateral faces of the gate 9. Similarly, in this specific example embodiment wherein a hard mask 11 is preserved on the top face of the gate 9, a compound is prevented from being formed, during this step, on the top face of the gate 9.
(33) Semiconductor regions of the active area 4a projecting from either side of the lateral faces of the gate are thus transformed into regions 19a, 19b of metal-semiconductor compound, such as regions of silicide and in particular a compound or a silicide capable of behaving as a superconductor or similarly to a superconductor. For example, regions 19a, 19b are formed of platinum silicide (PtSi), or cobalt silicide (CoSi2), or vanadium silicide (V3Si), or niobium silicide (NbSi2), or tungsten silicide WSi2.
(34) In the example shown in
(35) In the example shown in
(36) Removal by selective etching of the unreacted metal material 17 can then be carried out. For example, in order to remove Pt or Co, a method respectively using aqua regia (HNO.sub.3:HCl) or SPM (H.sub.2SO.sub.4:H.sub.2O.sub.2:H.sub.2O) can be applied.
(37) These regions 19a, 19b are capable of forming source and drain blocks for the transistor. In particular as a result of the very low thickness of the lateral protection areas 15c formed on the lateral faces of the gate 9 and resting on the active area 4a, the regions 19a, 19b of metal-semiconductor compound are very near a portion of the semiconductor surface layer 4 that is located facing the gate 9.
(38) The interface I.sub.1 between the regions of metal-semiconductor compound and the remaining portion of non-consumed semiconductor material of the semiconductor surface layer 4 is located, as shown in
(39) After having formed source and drain blocks made of a metal-semiconductor compound, insulating spacers 23c can then be produced on these blocks.
(40) As shown in
(41) In the example shown in
(42) Optionally, an area of metal-semiconductor compound can then be produced on the top face of the gate block 9, in addition to connection pads for taking an electrical contact on the source block, the drain block and the gate block.
(43) For this purpose, according to one embodiment, the transistor structure being produced is covered with at least one insulating layer 27, for example made of silicon oxide, in particular of the PMD (pre-metal dielectric) type produced by one or more depositions.
(44) In the example embodiment shown in
(45) After having deposited the insulating layer 27, planarisation by CMP can be carried out so as to reveal the hard mask 11 (
(46) The hard mask 11 is then removed to reveal the gate 9, whereas the rest of the structure is typically protected by the insulating layer 27 (
(47) Then, an area based on metal-semiconductor compound is formed on said top face of the gate block 9. For this purpose, a method comprises the deposition of at least one metal 29 such as nickel for example, or a metal alloy, for example an alloy of Ni and Pt (
(48) At least one thermal annealing process is then carried out to form a metal-semiconductor compound 31 on the top face of the gate block 9 (
(49) For example, when the material 29 is made of NiPt (10%), annealing can be carried out at a temperature that can lie in the range 200° C. to 300° C., for a duration that can be between 10 s and 60 s for example.
(50) Removal by selective etching of the unreacted metal material 29 can then be carried out (
(51) In the specific example embodiment shown in
(52) For example, when the compound 31 is made of (NiPt).sub.2Si, annealing can be carried out at a temperature that can lie in the range 350° C. to 500° C., for a duration that can be between 1 s and 60 s for example in order to form a NiPtSi compound.
(53) Such an implementation option, wherein a gate contact is formed independently of the source and drain contacts and wherein different metal-semiconductor compounds can be provided between the gate on the one hand and the source and drain regions on the other hand, can be provided in particular due to costs, or due to the thickness of the silicides.
(54) Once the area of compound 33 has been produced on the gate block, the structure being produced can be covered with at least one insulating layer 37, for example made of silicon oxide (
(55) Holes 39a, 39b are then formed through the insulating layers 37, 27, 25 so as to reveal the regions 19a, 19b made of a metal-semiconductor compound (
(56) In the specific example embodiment shown in
(57) Then, the rest of the holes 39a, 39b are filled with a metal 43 such as W for example.
(58) Alternatively, the thin diffusion barrier layer 42 can be replaced by a fluorine-free tungsten layer (W*) as described, for example, in the document entitled “Advanced characterizations of fluorine-free tungsten film and its application as low resistance liner for PCRAM”, by Rodriguez et al., Materials Science in Semiconductor Processing 71 (2017) 433-440. The thin tungsten layer is, in this case, deposited without using a fluorine-based precursor such as WF.sub.6. Then, filling can be completed by conventional deposition of metal 43 such as tungsten.
(59) Advantageously, a filling material that is also capable of having superconducting properties can be used, and chosen, for example, from the group consisting of: Al, TiN, V or Nb in order to preserve a superconducting continuity to other components.
(60) In the specific example embodiment shown in
(61) In the case whereby the transistor that is being produced is of the JoFET type, in other words a Josephson junction transistor, it is brought to be placed at a temperature such that the regions of metal-semiconductor compound 19a, 19b thereof and wherein the source and drain are formed, adopt the behaviour of a superconductor.
(62) For example a platinum silicide, in particular PtSi, can behave as a superconductor at a temperature that is below a critical temperature of about 0.5 or 1 K. A cobalt silicide, in particular CoSi2, can behave as a superconductor at a temperature that is below a critical temperature that lies in the range 1 to 3 K. A vanadium silicide, in particular V3Si, can behave as a superconductor at a temperature that is below a critical temperature of about 15 K. This document considers placing a transistor such as that described hereinabove at a temperature that lies, for example, in the range 10 K to 15 K.
(63) One alternative to the example method described hereinabove and more particularly to the formation of the regions 19a, 19b of metal-semiconductor compound is shown in
(64) After having deposited at least one metal material layer 17, a first thermal annealing process is then carried out allowing a compound to be formed between the metal of the metal layer 17 and the semiconductor material of the active area 4a.
(65) In the example embodiment shown in
(66) The metal 17 can then be removed (
(67) At least one second thermal annealing process is then carried out so as to extend the regions of metal-semiconductor compound.
(68) This further thermal annealing is then carried out so as to extend the regions 19a, 19b of metal-semiconductor compound and thus transform the areas 411a, 411b into areas of metal-semiconductor compound. This further thermal annealing process is preferably carried out so as to form regions of metal-semiconductor compound which, as shown in
(69) In either of the example embodiments given hereinabove, the gate against which the lateral protection areas 15c and the spacers 23c are formed can be a definitive gate and on which an electrical contact area is produced.
(70) According to one alternative to the method described hereinabove, a replacement of the gate can be carried out according to a so-called “gate last” method.