Composite film used for cable wrapping layer and preparation method for the same

Abstract

This application provides a composite film for a cable wrapping layer and a preparation method for the same. The composite film for the cable wrapping layer includes a PE film layer, a PET film layer laminated at the PE film layer, an aluminum foil layer laminated at the PET film layer, and a bonding layer arranged between the PET film layer and the aluminum foil layer. The PE film layer is made of raw materials having the following parts by weight: 40-45 parts of LLDPE with a melt index of 0.9-1.1 g/10 min and a density of 0.920-0.922 g/cm.sup.3, 35-40 parts of m-LLDPE with a melt index of 1.9-2.1 g/10 min and a density of 0.917-0.920 g/cm.sup.3 and 15-25 parts of ethylene-vinyl acetate copolymer.

Claims

1. A composite film for a cable wrapping layer comprising a polyethylene (PE) film layer, a polyethylene terephthalate (PET) film layer laminated on the PE film layer, an aluminum foil layer laminated on the PET film layer, and a bonding layer arranged between the PET film layer and the aluminum foil layer; in which the PE film layer is made of raw materials having the following parts by weight: 40-45 parts of linear low-density polyethylene (LLDPE) with a melt index of 0.9-1.1 g/10 min and a density of 0.920-0.922 g/cm.sup.3, 35-40 parts of linear low-density polyethylene produced using metallocene catalysts (m-LLDPE) with a melt index of 1.9-2.1 g/10 min and a density of 0.917-0.920 g/cm.sup.3 and 15-25 parts of ethylene-vinyl acetate (EVA) copolymer.

2. The composite film for the cable wrapping layer according to claim 1, raw materials of the PE film layer further comprising 3-6 parts by weight of modified montmorillonite which is prepared by crushing montmorillonite, modifying the crushed montmorillonite with a pretreatment agent, and treating the pretreated montmorillonite with hydrogenated rosin glyceride.

3. The composite film for the cable wrapping layer according to claim 2, wherein the pretreatment agent is composed of sodium lauryl polyoxyethylene ether sulfate, sodium dodecyl sulfate and vinyl tris (β-methoxyethoxy) silane in a weight ratio of 4-6:2-4:1-3.

4. The composite film for the cable wrapping layer according to claim 1, wherein the bonding layer is an EVA film made of raw materials having the following parts by weight: 80-90 parts of the ethylene-vinyl acetate copolymer, 6-8 parts of the m-LLDPE, 3-5 parts of polyvinyl butyral, 2-3 parts of modified montmorillonite, 0.3-0.5 parts of an antioxidant and 1-2 parts of a lubricant; the melt index of the m-LLDPE is 1.9-2.1 g/10 min and the density thereof is 0.917-0.920 g/cm.sup.3; and the modified montmorillonite is prepared by crushing montmorillonite, modifying the crushed montmorillonite with a pretreatment agent, then treating the pretreated montmorillonite with hydrogenated rosin glyceride.

5. The composite film for the cable wrapping layer according to claim 1, wherein a thickness ratio of the PE film layer, the PET film layer and the aluminum foil layer is in a range of 2-4:3-5:2-4.

6. A preparation method for the composite film for the cable wrapping layer according to claim 1 comprising the following steps: (S1) placing a PE film on a first unreeling roller of a laminator at a temperature of 70-80° C. and a tension of 30-40 N, placing a PET film on a second unreeling roller of the laminator at a temperature of 80-90° C. and a tension of 40-45 N, applying the PE film to the PET film at a laminating speed of 80-100 m/min, and laminating the two films with a pressing roller at a pressure of 0.2-0.4 Mpa; and reeling with a laminating roller at a temperature of 40-50° C., a pressure of 0.2-0.4 Mpa and a reeling tension of 30-40 N to obtain an original composite film; and (S2) placing the original composite film on a third unreeling roller of the laminator at a temperature of 70-80° C. and a tension of 30-40 N, placing an EVA film on a fourth unreeling roller of the laminator at a temperature of 60-70° C. and a tension of 10-20 N; applying the EVA film to one side of the PET film of the original composite film at a laminating speed of 80-100 m/min, and laminating the two films with the pressing roller at a pressure of 0.2-0.4 Mpa; and applying a preheated aluminum foil to the original composite film so that the preheated aluminum foil is in contact with the EVA film, and laminating by hot pressing for 30-40 seconds at a temperature of 120-130° C. and a pressure of 3-5 Mpa to obtain a composite film.

7. The preparation method for the composite film for the cable wrapping layer according to claim 6, wherein the PE film is prepared according to the following method: mixing LLDPE, m-LLDPE and ethylene-vinyl acetate copolymer to obtain a mixture; and after placing the mixture in a film blowing machine, melting the mixture, then extruding and blowing the melted mixture at a temperature of 160-190° C. to obtain the PE film.

8. The preparation method for the composite film for the cable wrapping layer according to claim 6, wherein raw materials of the PE film further comprises 3-6 parts by weight of modified montmorillonite which is prepared by the following method: (S3) grinding and sieving montmorillonite to obtain a montmorillonite powder; and adding 0.05-0.2 parts by weight of a dispersant and 100 parts by weight of water to 10 parts by weight of the montmorillonite powder and stirring thoroughly to obtain a montmorillonite suspension; (S4) adding 0.2-0.4 parts by weight of a pretreatment agent to the montmorillonite suspension, stirring at a speed of 2000-3000 r/min for 10-20_min, drying at a temperature of 80-100° C. for 36-48 h, and crushing and sieving to obtain a pretreated montmorillonite; and (S5) adding 2-4 parts by weight of 10 wt % acetone solution of hydrogenated rosin glyceride to the pretreated montmorillonite, stirring at a speed of 200-400 r/min at a temperature of 30-40° C. for 1 h, standing for 3-5 h, raising the temperature to 85-90° C., and removing an acetone solvent in the 10 wt % acetone solution to obtain a solidified substance; and crushing and sieving the solidified substance to obtain the modified montmorillonite.

9. The preparation method for the composite film for the cable wrapping layer according to claim 8, wherein the dispersant comprises one selected from a group consisting of sodium hexametaphosphate and sodium polycarboxylate.

10. The preparation method for the composite film for the cable wrapping layer according to claim 6, wherein the EVA film is prepared by the following method: premixing 80-90 parts by weight of ethylene-vinyl acetate copolymer, 6-8 parts by weight of m-LLDPE, 3-5 parts by weight of polyvinyl butyral, 2-3 parts by weight of modified montmorillonite, 0.3-0.5 parts by weight of an antioxidant and 1-2 parts by weight of a lubricant to obtain a premix; and melting and extruding the premix at a temperature of 140-180° C. to obtain a melt, and casting the melt into a film to obtain the EVA film.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a cross-sectional view of a known cable; and

(2) FIG. 2 is a cross-sectional view of a layer structure of a wrapping layer according to an example of the present application.

DETAILED DESCRIPTION

(3) This application will be described in detail below in combination with the drawings and examples.

(4) Preparation Example of Modified Montmorillonite

(5) A pretreatment agent in the following Preparation Examples was composed of sodium lauryl polyoxyethylene ether sulfate, sodium lauryl sulfate and vinyl tris (β-methoxyethoxy) silane according to a weight ratio of 5:3:2; the CAS number of the sodium lauryl polyoxyethylene ether sulfate was 9004-82-4, which was selected from the fatty alcohol polyoxyethylene ether sodium sulfate AES with the model of C24E2S provided by Nantong Reform Petro-chemical Co., Ltd.; the sodium lauryl sulfate was selected from K12 sodium lauryl sulfate provided by Shanghai White Cat Co., Ltd.; the vinyl tris (β-methoxyethoxy) silane was selected from A-172 silane coupling agent provided by Hangzhou Sait Polymer Technology Co., Ltd.; the sodium polycarboxylate dispersant was selected from the BG554 sodium polycarboxylate dispersant provided by Dongguan Bogao Chemical Industry; and the hydrogenated rosin glyceride was selected from the hydrogenated rosin glyceride provided by Wuhan Kabuda Chemical Co., Ltd.

(6) Preparation Example 1 of modified montmorillonite

(7) 1. grinding montmorillonite and sieving it through a 200 mesh sieve to obtain a montmorillonite powder; and adding 0.05 kg sodium hexametaphosphate and 100 kg water to 10 kg montmorillonite powder and stiffing thoroughly at a speed of 1000 r/min for 20 min to obtain a montmorillonite suspension;

(8) 2. adding 0.2 kg pretreatment agent (composed of 0.1 kg sodium lauryl polyoxyethylene ether sulfate, 0.06 kg sodium lauryl sulfate and 0.04 vinyl tris (β-methoxyethoxy) silane) to the montmorillonite suspension, stiffing at a speed of 2000 r/min for 10 min, drying at a temperature 80° C. for 36 h, and conducting crushing and sieving through the 200 mesh sieve to obtain a pretreated montmorillonite; and

(9) 3. adding 2 kg, 10 wt % acetone solution of hydrogenated rosin glyceride to the pretreated montmorillonite, stiffing at a speed of 200 r/min at a temperature of 30° C. for 1 h, keeping the temperature and standing for 3 h, raising the temperature to 85° C., and removing the acetone solvent in the 10 wt % acetone solution by distillation to obtain a solidified substance; crushing and sieving the solidified substance through the 200 mesh sieve to obtain a modified montmorillonite.

(10) Preparation Example 2 of modified montmorillonite: this example was different from the Preparation Example 1 of the modified montmorillonite in that

(11) in step 1, the sodium hexametaphosphate was 0.1 kg;

(12) in step 2, the pretreatment agent was 0.3 kg, the stiffing speed was 2500 r/min, the stiffing time was 15 min, the drying temperature was 90° C., and the drying time was 42 h; and

(13) in step 3, the acetone solution of the hydrogenated rosin glyceride was 3 kg, the stiffing temperature was 35° C., the stiffing speed was 300 r/min, the temperature keeping time was 4 h, and the temperature was raised to 87° C.

(14) Preparation Example 3 of modified montmorillonite: this example was different from the Preparation Example 1 of the modified montmorillonite in that

(15) in step 1, the sodium hexametaphosphate was 0.2 kg;

(16) in step 2, the pretreatment agent was 0.4 kg, the stiffing speed was 3000 r/min, the stiffing time was 20 min, the drying temperature was 100° C., and the drying time was 48 h; and

(17) in step 3, the acetone solution of the hydrogenated rosin glyceride was 4 kg, the stiffing temperature was 40° C., the stirring speed was 400 r/min, the temperature keeping time was 5 h, and the temperature was raised to 90° C.

(18) Preparation Example of Polyethylene (PE) Film

(19) The linear low-density polyethylene (LLDPE) in the following Preparation Examples was selected from the MJA-042 LLDPE with a melt index of 1 g/min and a density of 0.921 g/cm.sup.3 provided by ExxonMobil corporation, US; linear low-density polyethylene produced using metallocene catalysts (m-LLDPE) was selected from 2018 MB m-LLDPE with a melt index of 2 g/min and a density of 0.918 g/cm.sup.3 provided by ExxonMobil corporation, US; and the ethylene-vinyl acetate (EVA) copolymer was selected from the VA930 ethylene-vinyl acetate copolymer with a density of 0.95 g/cm.sup.3 and a VA content of 28% provided by Lotte, Korea.

(20) Preparation Example 1 of PE film: mixing 40 kg LLDPE, 35 kg m-LLDPE and 25 kg ethylene-vinyl acetate copolymer at a high speed of 1000 r/min for 15 min to obtain a mixture; and placing the mixture in a film blowing machine in which a temperature of a first zone of the film blowing machine was 160° C., a temperature of a second zone was 170° C., a temperature of a third zone was 180° C., a temperature of a fourth zone was 190° C., a temperature of a fifth zone was 180° C., and a temperature of a die head was 180° C., melting, extruding, drawing a film at a speed of 30 r/min, and slitting and reeling the film to obtain the PE film with a thickness of 10 μm.

(21) Preparation Example 2 of PE film: this example was different from the Preparation Example 1 of PE film in that raw materials were composed of: 42.5 kg LLDPE, 35 kg m-LLDPE, and 25 kg ethylene-vinyl acetate copolymer.

(22) Preparation Example 3 of PE film: this example was different from the Preparation Example 1 of PE film in that raw materials were composed of: 45 kg LLDPE, 40 kg m-LLDPE, and 15 kg ethylene-vinyl acetate copolymer.

(23) Preparation Example 4 of PE film: this example was different from the Preparation Example 1 of PE film in that 3 kg modified montmorillonite prepared by modified montmorillonite of Preparation Example 1 was added to the mixture.

(24) Preparation Example 5 of PE film: this example was different from the Preparation Example 1 of PE film in that 4.5 kg modified montmorillonite prepared by modified montmorillonite of Preparation Example 2 was added to the mixture.

(25) Preparation Example 6 of PE film: this example was different from the Preparation Example 1 of PE film in that 6 kg modified montmorillonite prepared by modified montmorillonite of Preparation Example 3 was added to the mixture.

(26) Preparation Example 7 of PE film: this example was different from the Preparation Example 1 of PE film in that raw materials were free of the ethylene-vinyl acetate copolymer.

(27) Preparation Example of EVA Film

(28) The ethylene-vinyl acetate copolymer in the following Preparation Examples was selected from the EVA42-60 ethylene-vinyl acetate copolymer with a VA content of 42% provided by Arkema, US; m-LLDPE was selected from 2018 MB m-LLDPE with a melt index of 2 g/10 min and a density of 0.918 g/cm.sup.3 provided by ExxonMobil Corporation, US, and the modified montmorillonite was selected from the modified montmorillonite prepared by Preparation Example 1.

(29) Preparation Example 1 of EVA film: mixing 80 kg ethylene-vinyl acetate copolymer, 6 kg m-LLDPE, 3 kg polyvinyl butyral, 2 kg modified montmorillonite, 0.5 kg antioxidant 1010, and 1 kg polyethylene wax for 10 min at a speed of 1000 r/min to obtain a premix; placing the premix in a twin-screw extruder in which a temperature of a first zone of the twin-screw extruder is 140° C., a temperature of a second zone is 150° C., a temperature of a third zone is 170° C., a temperature of a fourth zone is 180° C., a temperature of a fifth zone is 180° C., a temperature of a die head is 170° C., and a speed of a screw is 50 r/min, melting, extruding to obtain a melt, casting the melt at a temperature of 180° C. through a casting machine to form a film, and reeling the film and cooling down to obtain the EVA film with a thickness of 3 μm.

(30) Preparation Example 2 of EVA film: this example was different from the Preparation Example 1 of EVA film in that raw materials were composed of: 85 kg ethylene-vinyl acetate copolymer, 7 kg m-LLDPE, 4 kg polyvinyl butyral, 2.5 kg modified montmorillonite, 0.4 kg antioxidant 1010, and 1.5 kg polyethylene wax.

(31) Preparation Example 3 of EVA film: this example was different from the Preparation Example 1 of EVA film in that raw materials were composed of: 90 kg ethylene-vinyl acetate copolymer, 8 kg m-LLDPE, 5 kg polyvinyl butyral, 3 kg modified montmorillonite, 0.5 kg antioxidant 1010, and 2 kg polyethylene wax.

(32) Preparation Example 4 of EVA film: this example was different from the Preparation Example 1 of EVA film in that raw materials were free of modified montmorillonite.

(33) Preparation Example 5 of EVA film: this example was different from the Preparation Example 1 of EVA film in that raw materials were free of m-LLDPE and polyvinyl butyral.

EXAMPLES

Example 1

(34) Referring to FIG. 2, a composite film for a cable wrapping layer includes a PE film layer 51, a polyethylene terephthalate (PET) film layer 52 laminated on the PE film layer 51, an aluminum foil layer 53 laminated on the PET film layer 52, and a bonding layer 54 arranged between the PET film layer 52 and the aluminum foil layer 53. During use, the PE film layer 51 contacts with an insulation layer of the cable.

(35) A preparation method for the composite film of the cable wrapping layer included the following steps:

(36) S1, placing a PE film prepared in the Preparation Example 1 of PE film on a first unreeling roller of a laminator at a temperature of 70° C. and a tension of 30 N, placing a PET film on a second unreeling roller of the laminator at a temperature of 80° C. and a tension of 40 N, applying the PE film to the PET film at a laminating speed of 80 m/min, and laminating the two by a pressing roller at a pressure of 0.2 Mpa; and reeling by a laminating roller at a temperature of 40° C., a pressure of 0.2 Mpa and a reeling tension of 30 N to obtain an original composite film; and

(37) S2, placing the original composite film on a third unreeling roller of the laminator at a temperature of 70° C. and a tension of 30 N, placing an EVA film (prepared in the Preparation Example 1 of EVA film) on a fourth unreeling roller of the laminator at a temperature of 60° C. and a tension of 10 N; applying the EVA film to one side of the PET film of the original composite film at a laminating speed of 80 m/min, and laminating the two films with the pressing roller at a pressure of 0.2 Mpa; and applying a preheated aluminum foil to the original composite film so that the aluminum foil is in contact with the EVA film, and laminating the original composite film and the aluminum foil by hot pressing for 30 s at a temperature of 120° C. and a pressure of 3 Mpa to obtain a composite film with a thickness ratio of the PE film layer, the PET film layer and the aluminum foil layer being 3:4:3.

(38) Example 2 was different from Example 1 in that the composite film of the cable wrapping layer was prepared according to the following method: in S1, the PE film was selected from the Preparation Example 2 of PE film, the temperature of the first unreeling roller was 75° C. and the tension thereof was 35 N; the temperature of the second unreeling roller was 85° C. and the tension thereof was 42 N; the laminating speed was 90 m/min; and the pressure of the pressing roller was 0.3 Mpa; and the temperature of the laminating roller was 45° C., the pressure was 0.3 Mpa, and the unreeling tension was 35 N; and

(39) in S2, the temperature of the third unreeling roller was 75° C. and the tension thereof was 35 N; the EVA film was selected from Preparation Example 2 of EVA film; the temperature of the fourth unreeling roller was 65° C. and the tension thereof was 15 N; the laminating speed was 90 m/min; the pressure of the pressing roller was 0.3 Mpa; and the laminating temperature of the hot pressing was 45° C., the pressure was 4 Mpa, and the time was 35 s.

(40) Example 3 was different from Example 1 in that the composite film of the cable wrapping layer was prepared according to the following method: in S1, the PE film was selected from Preparation Example 3 of PE film, the temperature of the first unreeling roller was 80° C. and the tension thereof was 40 N; the temperature of the second unreeling roller was 90° C. and the tension thereof was 45 N; the laminating speed was 100 m/min; the pressure of the pressing roller was 0.4 Mpa; and the temperature of the laminating roller was 50° C., the pressure was 0.4 Mpa, and the unreeling tension was 40 N; and

(41) In S2, the temperature of the third unreeling roller was 80° C. and the tension thereof was 40 N; the EVA film was selected from Preparation Example 3 of EVA film; the temperature of the fourth unreeling roller was 70° C. and the tension thereof was 20 N; the laminating speed was 100 m/min; the pressure of the pressing roller was 0.4 Mpa; and the laminating temperature of the hot pressing was 130° C., the pressure was 5 Mpa, and the time was 40 s.

(42) Example 4 was different from Example 1 in that the PE film was selected from the Preparation Example 4 of PE film.

(43) Example 5 was different from Example 1 in that the PE film was selected from the Preparation Example 5 of PE film.

(44) Example 6 was different from Example 1 in that the PE film was selected from the Preparation Example 6 of PE film.

Comparison Example

(45) Comparison Example 1: this example was different from Example 1 in that the PE film was selected from the Preparation Example 7 of PE film and the raw materials for preparing the PE film were free of the ethylene vinyl acetate copolymer.

(46) Comparison Example 2: this example was different from Example 1 in that the EVA film was selected from the Preparation Example 4 of EVA film.

(47) Comparison Example 3: this example was different from Example 1 in that the EVA film was selected from the Preparation Example 5 of EVA film.

(48) Performance Test

(49) The performances of the composite film prepared in Examples 1-6 and comparison Examples 1-3 were tested according to the following methods, and the results were shown in Table 1.

(50) Tensile strength and elongation at break: test according to GB/T13022-1991 “plastics-determination of tensile properties of films”.

(51) Tear strength: test according to GB/T16578.1-2008 “plastics-film and sheeting-determination of tear resistance-part 1: trouser tear method”.

(52) Strip strength: In order to verify the bonding force between each layer of the composite film, a composite film sample with a size of 100×50 mm was cut and was placed in an area at a temperature of (23±2°) C. with a relative humidity of (50±5)% for 40 h. The PE film and the PET film, and the PET film and the aluminum foil were respectively striped by 30 mm in advance. The sample was placed in a tensile testing machine for peeing at a striping speed of 100 mm/min. The strip strength between the PE film and the PET film and the strip strength between the PET film and the aluminum foil were tested, respectively.

(53) Since the material of the wrapping layer is used to wrap the conductors by twisting, the PE film of the composite film not only contacts with the insulation layer of the cable, but also overlaps with the aluminum foil during the twisting. Therefore, it is necessary to test the strip strength between the PE film and the insulation layer (PVC material) and the strip strength between the PE film and the aluminum foil.

(54) The strip strength between PE film and PVC was tested by the following method. The composite film sample with the size of 120×50 mm and a PVC board with a size of 100×50×10 mm were placed in an area at a temperature of (23±2°) C. with a relative humidity of (50±5)% for 40 h. After the PVC board was heated to 60° C., one side of the PE film of the composite film sample was immediately attached to the PVC board so that the composite film and the PVC board were completely overlapped in the width direction. A static pressure of 830 Pa was applied on the overlapping part of the composite film and PVC board for 30 minutes to obtain a composite film/PVC sample. The sample was placed in the tensile testing machine for striping at a striping speed of 100 mm/min to test the strip strength between the composite film and PVC.

(55) The strip strength between the PE film and aluminum foil was tested by the following method. The composite film sample with a size of 100×50 mm was cut and placed in an area at a temperature of (23±2°) C. with a relative humidity of (50±5)% for 40 h. Two composite film samples were overlapped so that they were completely overlapped in the width direction, and the PE film layer of one composite film overlapped on the aluminum foil layer of the other composite film. The length of the overlapping part in the length direction was 30 mm, and the total length of the overlapped sample was 170 mm A static pressure of 830 Pa was applied on the overlapping part for 30 minutes to obtain an overlapped composite film/composite film sample. The sample was placed in the tensile testing machine for striping at a striping speed of 100 mm/min to test the strip strength between the PE film and the aluminum foil.

(56) TABLE-US-00001 TABLE 1 property test table of composite film prepared in Examples 1-6 and comparison Examples 1-3 Comparison Comparison Comparison Items Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 1 Example 2 Example 3 Tensile Longitudinal 132.1 131.7 132.0 143.5 142.1 143.0 110.3 132.1 132.1 strength, direction Mpa Transverse 134.9 132.4 133.3 145.2 143.6 143.9 115.3 134.9 134.9 direction Elongation Longitudinal 143.2 140.9 141.6 171.1 170.1 170.5 121.1 143.2 143.2 at break, % direction Transverse 163.2 161.1 164.7 182.2 182.0 182.1 143.2 163.2 163.2 direction Tear Longitudinal 165.2 164.6 165.8 173.9 174.0 174.3 152.1 165.2 165.2 resistance, direction N/mm Transverse 172.3 172.0 172.1 181.7 181.5 181.8 160.4 172.3 172.3 direction Peel PE film/ 6.8 6.8 6.7 8.9 8.7 8.8 1.9 6.8 6.8 strength, PET film N/cm PET film/ 9.3 9.1 9.3 9.3 9.3 9.3 9.3 8.8 8.4 aluminum foil PE film/ 5.0 5.2 5.0 8.1 8.0 80 1.8 5.0 5.0 PVC board PE film/ 5.4 5.5 5.4 8.5 8.4 8.4 2.2 5.4 5.4 aluminum foil

(57) Combining Example 1 and Comparison Example 1 with Table 1, it can be seen that the tensile strength and tear strength of the composite film and the strip strength of PE film/PET film, PE film/PVC board, and PE film/aluminum foil in Example 1 were significantly better than the tensile strength, tear strength and peel strength of the composite film in Comparison Example 1, showing that the adding of the ethylene-vinyl acetate copolymer in the PE film can significantly increase the self-bonding of the PE film, thereby improving the bonding strength between the PE film and the PET film and the bonding strength between the PVC and the aluminum foil.

(58) Combining Example 1 and Example 4 with Table 1, it can be seen that the tensile strength and tear strength of the composite film and the strip strength of PE film/PET film, PE film/PVC board, and PE film/aluminum foil in Example 4 were significantly better than the tensile strength, tear strength and strip strength of the composite film in Comparison Example 1, showing that the adding of the modified montmorillonite in the PE film can significantly increase the self-bonding of the PE film, thereby improving the bonding strength between the PE film and the PET film and the bonding strength between the PVC and the aluminum foil.

(59) Combining Example 1, Comparison Example 2 and Comparison Example 3 with Table 1, it can be seen that the strip strength of PET film/aluminum foil in Comparison Example 2 and Comparison Example 3 were significantly lower than the strip strength of PET film/aluminum foil in Example 1, showing that the adding of the modified montmorillonite, m-LLDPE and polyvinyl butyral in the EVA film can significantly increase the bonding strength between the EVA film and the aluminum foil and the bonding strength between the EVA film and the PET film.