Semiconductor Device With Selective Area Epitaxy Growth Utilizing a Mask to Suppress or Enhance Growth at the Edges
20260039091 ยท 2026-02-05
Assignee
Inventors
Cpc classification
H01S5/50
ELECTRICITY
H01S5/3202
ELECTRICITY
H01S5/1003
ELECTRICITY
International classification
H01S5/32
ELECTRICITY
H01L21/02
ELECTRICITY
H01S5/10
ELECTRICITY
Abstract
A method of Selective Area Epitaxy (SAE) on a semiconductor wafer is disclosed. A dielectric mask is deposited on the wafer surface to define an opening for epitaxial growth. The mask includes a zigzag edge formed by successive straight facets oriented to avoid crystallographic directions associated with unintentional growth enhancement. During SAE, a semiconductor layer is grown in the opening such that edge-growth enhancement at the zigzag edge is suppressed relative to straight edges aligned with [011] or [0
Claims
1. A method of Selective Area Epitaxy (SAE) on a semiconductor wafer, comprising: depositing a dielectric mask on a surface of the semiconductor wafer, the dielectric mask covering a first area of the surface and leaving a second area of the surface exposed as an opening for epitaxial growth, the dielectric mask including a zigzag edge at a boundary between the first area and the second area; and growing, by SAE, a semiconductor layer in the second area such that edge-growth enhancement at the zigzag edge is suppressed relative to a straight mask edge aligned parallel to a crystallographic direction of enhanced growth of the semiconductor wafer.
2. The method of claim 1, wherein the semiconductor wafer comprises indium phosphide (InP) oriented in or near a (100) crystal plane.
3. The method of claim 1, wherein the crystallographic direction of enhanced growth comprises a [011] or [0-1-1] direction of the semiconductor wafer.
4. The method of claim 1, wherein the dielectric mask comprises silicon dioxide (SiO.sub.2), silicon nitride (Si.sub.3N.sub.4), or a combination thereof.
5. The method of claim 1, wherein straight facets of the zigzag edge are oriented at one or more angles of approximately 34, 124, 214, or 304 relative to a [011] direction.
6. The method of claim 5, wherein straight facets of the zigzag edge are oriented at one or more angles of approximately 56, 146, 236, or 326 relative to the [011] direction.
7. The method of claim 1, wherein the zigzag edge comprises two alternating facet orientations that differ by 20 to 120 in a plane of the wafer.
8. The method of claim 1, wherein no individual straight facet of the zigzag edge exceeds 10 m in length without a change in orientation.
9. The method of claim 1, wherein the zigzag edge is disposed along portions of the dielectric mask oriented within 15 of [011] or [0-1-1] directions of the semiconductor wafer.
10. The method of claim 1, wherein the SAE is performed in a metal-organic chemical vapor deposition (MOCVD) reactor under conditions that promote epitaxy on the second area and inhibit deposition on the dielectric mask.
11. The method of claim 1, wherein the semiconductor layer comprises indium phosphide (InP), indium gallium arsenide (InGaAs), indium gallium arsenide phosphide (InGaAsP), or aluminum indium gallium arsenide (AlInGaAs).
12. The method of claim 1, further comprising, subsequent to the growing, integrating the semiconductor layer into a photonic integrated circuit comprising at least one of: a modulator, a semiconductor optical amplifier, a laser, a detector, a variable optical attenuator, or a phase shifter.
13. A semiconductor device formed by Selective Area Epitaxy (SAE), comprising: a semiconductor wafer having a surface; a dielectric mask disposed on the surface and covering a first area of the surface, the dielectric mask leaving a second area of the surface exposed as an opening for epitaxial growth; the dielectric mask including a zigzag edge at a boundary between the first area and the second area; and a semiconductor epitaxial layer grown in the second area such that edge-growth enhancement at the zigzag edge is suppressed relative to a straight mask edge aligned parallel to a crystallographic direction of enhanced growth of the semiconductor wafer.
14. The semiconductor device of claim 13, wherein the semiconductor wafer comprises indium phosphide (InP) oriented in or near a (100) crystal plane.
15. The semiconductor device of claim 13, wherein the crystallographic direction of enhanced growth comprises a [011] or [0-1-1] direction of the semiconductor wafer.
16. The semiconductor device of claim 13, wherein the dielectric mask comprises silicon dioxide (SiO.sub.2), silicon nitride (Si.sub.3N.sub.4), or a combination thereof.
17. The semiconductor device of claim 13, wherein straight facets of the zigzag edge are oriented at one or more angles of approximately 34, 124, 214, or 304 relative to a [011] direction.
18. The semiconductor device of claim 17, wherein straight facets of the zigzag edge are oriented at one or more angles of approximately 56, 146, 236, or 326 relative to the [011] direction.
19. The semiconductor device of claim 13, wherein no individual straight facet of the zigzag edge exceeds 10 m in length without a change in orientation.
20. The semiconductor device of claim 13, wherein the semiconductor epitaxial layer forms part of a photonic integrated circuit comprising at least one of: a modulator, a semiconductor optical amplifier, a laser, a detector, a variable optical attenuator, or a phase shifter.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0020] The present disclosure is illustrated and described herein with reference to the various drawings, in which like reference numbers are used to denote like system components/method steps, as appropriate, and in which:
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DETAILED DESCRIPTION OF THE DISCLOSURE
[0040] Again, the present disclosure provides a design whereby an optical amplifier is efficiently monolithically integrated with a deeply-etched ridge waveguide modulator, and, in particular, a multi-growth modulator formed on an InP wafer, such as that provided in U.S. Pat. No. 9,182,546, for example. The design enables the re-use of existing undoped overgrowth in the TWE modulator for the purpose of current blocking. Subsequent deep etching of the current-blocked buried ridge provides for independent control of the confinement factor and enables efficient coupling to a deeply-etched modulator. Thus, the present disclosure provides a means to re-use an overgrowth that already exists in the standard modulator process sequence, thereby reducing cost, complexity, and problems associated with many epitaxial growths, such as reliability issues. The present disclosure provides better current confinement, and therefore better electrical efficiency, than alternative shallow ridge solutions. The present disclosure decouples current confinement (provided by i-InP blocks described in greater detail herein below) from optical confinement (provided by etched areas described in greater detail herein below). Accordingly, the present disclosure provides an efficient alternative means to couple light from the modulator to the gain section without introducing an additional or new optical element into the design, such as that provided in U.S. Pat. No. 7,184,207, for example.
[0041] In general, the present disclosure provides a modulator with an optical amplifier, including: an N-type layer; a multi-quantum well material disposed on the N-type layer; a P-type layer disposed on the multi-quantum well material opposite the N-type layer; wherein a portion of the N-type layer, the multi-quantum well material, and a portion of the P-type layer collectively form a ridge structure; and a material that is not intentionally doped (undoped, or i-type) disposed on the N-type layer and about side portions of the ridge structure using selective area epitaxy. Optionally, the i-type material is further deeply etched to form a strongly guided structure. The N-type layer includes NInP. The P-type layer includes one of PInGaAs and PInP. The i-type material includes i-InP, but may alternatively be any type of suitable current-blocking material that impedes current flow, such as semi-insulating iron-doped InP. Optionally, over all or some portion of the length, a width of the strongly guided structure is selected to couple efficiently to a strongly guided modulator waveguide.
Monolithically Integrated Gain Element
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[0043] Referring now specifically to
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[0047] In the conventional modulator structure 25 of
Semiconductor Device with Suppressed or Enhanced Selective Area Epitaxy (SAE) Growth
[0048] Also, the present disclosure relates to systems and methods for a semiconductor device with Selective Area Epitaxy (SAE) growth utilizing a mask to suppress or enhance growth at the edges. Again, SAE is a technique for crystal growth on semiconductor surfaces. Areas of the wafer are covered or masked by thin layers of dielectric material (e.g., SiO.sub.2, Si.sub.3N.sub.4, etc.). In a crystal growth reactor, such as a Metal-Organic Vapor-Phase Deposition (MOCVD) chamber, crystal growth proceeds selectively only on those areas not covered by the mask. This disclosure provides a process for producing a semiconductor device containing areas of selective growth in an arbitrary orientation without unwanted growth enhancement and corresponding defects at the exterior edges of the masked areas. Specifically, the process includes variable profiles on the mask edges that can be used to suppress or enhance growth at the edges.
[0049] By way of an enabling technology,
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[0054] Variously, the present disclosure notes that specific, preferred angles for the mask 102, the adaptation of a shape and/or orientation of the mask 102, and/or zigzag edges of the mask 102 can lead to suppression (or enhancement) of growth at the edges of the mask 102. That is, the mask 102 includes a specific geometry that suppresses or enhances the intentional growth enhancement at the edge of the mask 102 without compromising the intended growth enhancement, which is the purpose of SAE. The effect of unintentional enhancement at a mask edge is anisotropic on the wafer surface, i.e., it has a different value when measured in a different direction. Along one directional axis, the effect is strong, but along the perpendicular axis, it is weak. This is illustrated in
[0055] In an embodiment, by placing a zigzag pattern or other angular patterns along the edge susceptible to enhancement, almost none of that boundary is parallel to the line along which the unintentional enhancement occurs.
[0056] Through growth experiments on III-V semiconductor materials (specifically, InP wafers oriented in the (100) plane), it has been determined that mask 102 edges aligned along certain crystallographic axes exhibit an undesirable degree of enhanced crystal growth, particularly in the [011] or [0
[0057] Also, it has been determined that the converse of the above is also true: along specific crystallographic directions the undesirable enhanced crystal growth is suppressed and, indeed, transits through zero enhancement as a function of angle relative to the [011] or [0
[0058] For InP wafers 150 oriented on the (100) plane (the wafer 100), for example, growth enhancement passes through a null when an SAE mask 102 edge is aligned with one of the angles (preferred angles) below relative to the [011] direction 164, collected into two series.
TABLE-US-00001 Series 1: 34 degrees 124 degrees 214 degrees 304 degrees
TABLE-US-00002 Series 2: 56 degrees 146 degrees 236 degrees 326 degrees
[0059] Each series contains four angular directions, with each direction separated by 90 degrees from the other three in the series. For a (100)-oriented InP wafer 150, there are a total of eight orientations available for enhancement- and defect-free SAE mask 102 edges. Specifically, the graph 160 illustrates series 1, 2 in a graph format relative to the [011] direction 164. Note, while the angles in the series 1, 2 are specified relative to the [011] direction 164, those skilled in the art will appreciate these angles for the mask 102 edges could also be specified relative to any direction, including the [0
[0060]
[0061] The use of the mask 102 with the InP wafer 150 is utilized to form a semiconductor device with SAE, fabricated via a process of growing an epitaxial layer onto a semiconductor wafer 150. In an embodiment, the semiconductor device includes 1) a first area covered by the mask 102 which inhibits crystal growth on the semiconductor wafer 150 surface, 2) a second area, complementary (adjacent) to the first area and not covered by the mask 102, which allows crystal growth on the semiconductor wafer 150, and 3) a perimeter of the mask 102 enclosing the first area and serving as a boundary between the first area and the second area, wherein most of the length of the perimeter is substantially aligned along a preferred crystal direction that provides reduced growth enhancement on the semiconductor wafer 150.
[0062] Also, the semiconductor wafer 150 can have portions where growth enhancement is desired and portions where growth enhancement is not desired, and this disclosure provides a degree of freedom to meet both needs. For example, enhanced growth can be desired for a spot-size converter, and minimal growth can be desired for a traveling-wave electrode.
[0063] In an embodiment, the mask 102A is in the shape of a quadrilateral, namely a polygon with four edges (or sides) and four vertices or corners. That is, the perimeter can be the quadrilateral. The key is that any of the four sides fall in line with the preferred angles.
[0064] In another embodiment, the mask 102B is in the shape of a series of zigzag patterns, namely the perimeter includes a series of small corners that fall in line with the preferred angles.
[0065] The semiconductor wafer surface 150 is composed of a compound of group III and group V elements. In an embodiment, the semiconductor wafer surface 150 is InP cut near the (100) orientation. The preferred crystal direction is one or more of the following angles relative to the [011] direction, in approximate degrees: 34, 124, 214, 304, 56, 146, 236, 326. Note, each of the last four numbers is (360one of the first four numbers) and vice versa, i.e., 326=36034; 236=360124, etc.
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[0067] The perimeter can have a shape of a quadrilateral or a series of zigzag patterns. The semiconductor wafer can include a compound of group III and group V elements. The semiconductor wafer can be Indium Phosphide (InP), and the plane can be near a (100) orientation. The preferred crystal direction can be one or more of angles having approximate degrees of 34, 124, 214, 304, 56, 146, 236, and 326, relative to a [011] direction of the semiconductor wafer.
[0068] In an embodiment, a mask is for a spot size converter, and the preferred crystal direction is selected to provide the maximum growth enhancement. In another embodiment, a mask is for a traveling-wave electrode, and the preferred crystal direction is selected to provide the reduced growth enhancement.
[0069] Also, a semiconductor device can be formed by the process 180.
[0070] In another embodiment, a semiconductor device, for fabrication via a process of growing an epitaxial layer onto a semiconductor wafer via Selective Area Epitaxy (SAE), includes a first area covered by a mask which inhibits crystal growth on a surface of the first area; a second area, adjacent to the first area and not covered by a mask, which allows crystal growth on a surface of the second area; and a perimeter of the mask serving as a boundary between the first area and the second area, wherein multiple sides of the perimeter are substantially aligned along a preferred crystal direction relative to an orientation of the semiconductor wafer, to minimize or maximize growth enhancement at edges of the substantially aligned sides.
[0071]
[0072] Although the present disclosure has been illustrated and described herein with reference to preferred embodiments and specific examples thereof, it will be readily apparent to those of ordinary skill in the art that other embodiments and examples may perform similar functions and/or achieve like results. All such equivalent embodiments and examples are within the spirit and scope of the present disclosure, are contemplated thereby, and are intended to be covered by the following claims.