Self-aligned supervia and metal direct etching process to manufacture self-aligned supervia
11488864 · 2022-11-01
Assignee
Inventors
Cpc classification
H01L21/76885
ELECTRICITY
H01L21/76897
ELECTRICITY
H01L23/5226
ELECTRICITY
H01L23/53252
ELECTRICITY
H01L23/53266
ELECTRICITY
International classification
H01L21/768
ELECTRICITY
H01L23/522
ELECTRICITY
Abstract
A semiconductor device structure includes: at least one inter-metal layer stacked in a vertical direction; and a 1.sup.st via structure penetrating the at least one inter-metal layer, wherein, in the at least one inter-metal layer, a 1.sup.st vertical side of the 1.sup.st via structure does not contact a barrier metal pattern while a 2.sup.nd vertical side of the 1.sup.st via structure opposite to the 1.sup.st vertical side of the 1.sup.st via structure contacts the barrier metal pattern.
Claims
1. A via structure comprising: at least one inter-metal layer stacked in a vertical direction; a 1.sup.st via structure penetrating the at least one inter-metal layer; a lower metal pattern; and an etch stop layer formed on a top surface of the lower metal pattern, the etch stop layer comprising a 1.sup.st hole through which the top surface of the lower metal pattern is exposed, wherein, in the at least one inter-metal layer, a 1.sup.st vertical side of the 1.sup.st via structure does not contact a barrier metal pattern while a 2.sup.nd vertical side of the 1.sup.st via structure opposite to the 1.sup.st vertical side of the 1.sup.st via structure contacts the barrier metal pattern, wherein the 1.sup.st vertical side of the 1.sup.st via structure contacts the at least one inter-metal layer comprising only a single inter-metal layer, wherein the 2.sup.nd vertical side of the 1.sup.st via structure contacts the at least one inter-metal layer comprising at least two inter-metal layers through the barrier metal pattern, wherein the 1.sup.st via structure vertically lands on the top surface of the lower metal pattern exposed through the 1.sup.st hole, and wherein the single inter-metal layer is formed directly on the etch stop layer without overlapping the 1.sup.st hole.
2. The via structure of claim 1, wherein the 1.sup.st via structure is self-aligned in the 1.sup.st hole formed at the etch stop layer.
3. The via structure of claim 1, further comprising a 2.sup.nd via structure formed in parallel with the 1.sup.st via structure in a vertical direction, wherein a 1.sup.st vertical side of the 2.sup.nd via structure does not contact the barrier metal pattern while a 2.sup.nd vertical side of the 2.sup.nd via structure opposite to the 1.sup.st vertical side of the 2.sup.nd via structure contacts the barrier metal pattern.
4. The via structure of claim 3, wherein the 1.sup.st vertical side of the 2.sup.nd via structure contacts the at least one inter-metal layer comprising the single inter-metal layer, and wherein the 2.sup.nd vertical side of the 2.sup.nd via structure contacts the at least one inter-metal layer comprising at least two other inter-metal layers through the barrier metal pattern.
5. The via structure of claim 4, wherein the etch stop layer further comprises a 2.sup.nd hole through which the top surface of the lower metal pattern is exposed, and wherein the 2.sup.nd via structure vertically land on the top surface of the lower metal pattern exposed through the 2.sup.nd hole.
6. The via structure of claim 5, wherein the 1.sup.st and 2.sup.nd via structures are self-aligned in the 1.sup.st and 2.sup.nd holes formed at the etch stop layer, respectively.
7. A via structure comprising: at least one inter-metal layer stacked in a vertical direction; a 1.sup.st via structure penetrating the at least one inter-metal layer; a 2.sup.nd via structure formed in parallel with the 1.sup.st via structure in a vertical direction; and a 3.sup.rd via structure formed between the 1.sup.st and 2.sup.nd via structures in parallel with the 1.sup.st and 2.sup.nd via structures in the vertical direction, wherein, in the at least one inter-metal layer, a 1.sup.st vertical side of the 1.sup.st via structure and a 1.sup.st vertical side of the 2.sup.nd via structure do not contact a barrier metal pattern while a 2.sup.nd vertical side of the 1.sup.st via structure opposite to the 1.sup.st vertical side of the 1.sup.st via structure and a 2.sup.nd vertical side of the 2.sup.nd via structure opposite to the 1.sup.st vertical side of the 2.sup.nd via structure contact the barrier metal pattern, wherein an air gap is formed between the 1.sup.st via structure and the 3.sup.rd via structure, and between the 2.sup.nd via structure and the 3.sup.rd via structure, and wherein another inter-metal layer is formed above the air gap between the 1.sup.st via structure and the 3.sup.rd via structure and between the 2.sup.nd via structure and the 3.sup.rd via structure.
8. The via structure of claim 7, further comprising a lower metal pattern and an etch stop layer formed on a top surface of the lower metal pattern, the etch stop layer comprising three holes through which the top surface of the lower metal pattern is exposed, wherein the 1.sup.st to 3.sup.rd via structures vertically land on the top surface of the lower metal pattern exposed through the three holes.
9. A method of forming a via structure, the method comprising: providing a device structure comprising at least one 1.sup.st inter-metal layer, a lower metal pattern formed below the at least one 1.sup.st inter-metal layer; etching a section of the at least one 1.sup.st inter-metal layer from top thereof to form a 1.sup.st trench exposing at least a section of a top surface of the lower metal pattern; filling the 1.sup.st trench with a via metal; etching at least one section of the via metal from top thereof to form at least one 2.sup.nd trench exposing the top surface of the lower metal pattern so that at least one via structure comprising the via metal is formed at least one side of the at least one 2.sup.nd trench after the etching the at least one section of the via metal; and filling the at least one 2.sup.nd trench with a 2.sup.nd inter-metal layer.
10. The method of claim 9, wherein the etching at least one section of the via metal comprises etching at least one middle section of the via metal from top thereof to form the at least one 2.sup.nd trench exposing the top surface of the lower metal pattern so that at least two via structures comprising the via metal are formed on at least two sides of the at least one 2.sup.nd trench after the etching the at least one middle section of the via metal.
11. The method of claim 9, wherein the filling the 1.sup.st trench with a via metal comprises: layering a barrier metal pattern on a surface of the 1.sup.st trench; and filling the via metal in the 1.sup.st trench on which the barrier metal pattern is layered.
12. A method of forming a via structure in a back-end-of-line (BEOL) interconnect structure, the method comprising: providing a device structure comprising at least one 1.sup.st inter-metal layer, a lower metal pattern formed below the at least one 1.sup.st inter-metal layer, and an etch stop layer formed on a top surface of the lower metal pattern; etching the at least one 1.sup.st inter-metal layer from top thereof to form a 1.sup.st trench exposing at least one section of the top surface of the lower metal pattern; filling the 1.sup.st trench with a via metal; etching at least one section of the via metal from top thereof to form at least one 2.sup.nd trench exposing the etch stop layer on the top surface of the lower metal pattern so that at least one via structure comprising the via metal is formed on at least one side of the at least one 2.sup.nd trench after the etching the at least one section of the via metal; and filling the at least one 2.sup.nd trench with a 2.sup.nd inter-metal layer.
13. The method of claim 12, wherein the etching the at least one 1.sup.st inter-metal layer comprises: forming at least one mask on the at least one 1.sup.st inter-metal layer, and patterning the at least one mask to form at least one opening therein, through photolithography masking; etching the at least one 1.sup.st inter-metal layer and the etch stop layer through the at least one opening to form at least one via hole including at least one hole at the etch stop layer exposing the top surface of the lower metal pattern; removing the at least one mask; and etching the at least one 1.sup.st inter-metal layer at a side of the at least one via hole to form the 1.sup.st trench, of which a bottom comprises the at least one section of the top surface of the lower metal pattern and the etch stop layer.
14. The method of claim 13, wherein the filling the 1.sup.st trench with a via metal comprises self-aligning the via metal in the at least one hole formed at the etch stop layer.
15. The method of claim 14, wherein the etching at least one section of the via metal comprises etching at least one middle section of the via metal from top thereof to form the at least one 2.sup.nd trench exposing the at least one section of the top surface of the lower metal pattern so that at least two via structures comprising the via metal are formed on at least two sides of the at least one 2.sup.nd trench after the etching the at least one middle section of the via metal.
16. The method of claim 12, wherein the filling the 1.sup.st trench with the via metal comprises: layering a barrier metal pattern on a surface of the 1.sup.st trench; and filling the via metal in the 1.sup.st trench on which the barrier metal pattern is layered.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Example embodiments of the inventive concept will be more clearly understood from the following detailed description taken in conjunction with the accompanying drawings in which:
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DETAILED DESCRIPTION OF THE EMBODIMENTS
(18) The embodiments described herein are all example embodiments, and thus, the inventive concept is not limited thereto, and may be realized in various other forms. Each of the embodiments provided in the following description is not excluded from being associated with one or more features of another example or another embodiment also provided herein or not provided herein but consistent with the inventive concept. For example, even if matters described in a specific example or embodiment are not described in a different example or embodiment thereto, the matters may be understood as being related to or combined with the different example or embodiment, unless otherwise mentioned in descriptions thereof. In addition, it should be understood that all descriptions of principles, aspects, examples, and embodiments of the inventive concept are intended to encompass structural and functional equivalents thereof. In addition, these equivalents should be understood as including not only currently well-known equivalents but also equivalents to be developed in the future, that is, all devices invented to perform the same functions regardless of the structures thereof. For example, a MOSFET described herein may take a different type or form of a transistor as long as the inventive concept can be applied thereto.
(19) It will be understood that when an element, component, layer, pattern, structure, region, or so on (hereinafter collectively “element”) of a semiconductor device is referred to as being “over,” “above,” “on,” “below,” “under,” “beneath,” “connected to” or “coupled to” another element the semiconductor device, it can be directly over, above, on, below, under, beneath, connected or coupled to the other element or an intervening element(s) may be present. In contrast, when an element of a semiconductor device is referred to as being “directly over,” “directly above,” “directly on,” “directly below,” “directly under,” “directly beneath,” “directly connected to” or “directly coupled to” another element of the semiconductor device, there are no intervening elements present. Like numerals refer to like elements throughout this disclosure.
(20) Spatially relative terms, such as “over,” “above,” “on,” “upper,” “below,” “under,” “beneath,” “lower,” and the like, may be used herein for ease of description to describe one element's relationship to another element(s) as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of a semiconductor device in use or operation in addition to the orientation depicted in the figures. For example, if the semiconductor device in the figures is turned over, elements described as “below” or “beneath” other elements would then be oriented “above” the other elements. Thus, the term “below” can encompass both an orientation of above and below. The semiconductor device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
(21) As used herein, expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list. For example, the expression, “at least one of a, b, and c,” should be understood as including only a, only b, only c, both a and b, both a and c, both b and c, or all of a, b, and c.
(22) It will be understood that, although the terms first, second, third, fourth etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish one element from another element. Thus, a first element discussed below could be termed a second element without departing from the teachings of the inventive concept.
(23) It will be also understood that, even if a certain step or operation of manufacturing an inventive apparatus or structure is described later than another step or operation, the step or operation may be performed later than the other step or operation unless the other step or operation is described as being performed after the step or operation.
(24) Many embodiments are described herein with reference to cross-sectional illustrations that are schematic illustrations of the embodiments (and intermediate structures). As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, the embodiments should not be construed as limited to the particular shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, an implanted region illustrated as a rectangle will, typically, have rounded or curved features and/or a gradient of implant concentration at its edges rather than a binary change from implanted to non-implanted region. Likewise, a buried region formed by implantation may result in some implantation in the region between the buried region and the surface through which the implantation takes place. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the actual shape of a region of a device and are not intended to limit the scope of the present inventive concept. Further, in the drawings, the sizes and relative sizes of layers and regions may be exaggerated for clarity.
(25) For the sake of brevity, conventional elements of semiconductor devices including BEOL elements may or may not be described in detail herein.
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(27) Referring to
(28) Each of the 1.sup.st to 3.sup.rd inter-metal layers 210 to 230 may include a dielectric material such as a low-k material, and thus, may be referred to as an inter-metal dielectric (IMD) layer. The low-k material includes at least Si, C, O, H (SiCOH). However, the inventive concept is not limited thereto, and thus, different types of material may be used for the inter-metal layer.
(29) 1.sup.st to 3.sup.rd etch stop layers 211, 221 and 231 are formed underneath the 1.sup.st inter-metal layer and between the 1.sup.st to 3.sup.rd inter-metal layers, respectively, to stop a later etching processes performed thereat. Each of the 1.sup.st to 3.sup.rd etch stop layers 211, 221 and 231 may include two layers respectively formed of aluminum nitride (AlN) and oxide doped carbide (ODC), not being limited thereto, according to an embodiment. The ODC layer may be used as a hermetic barrier against moisture.
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(31) The 1.sup.st mask 310 may be formed of, for example, a metal hard mask layer of titanium nitride (TiN) and a block cut hard mask layer of silicon oxynitride (SiON) or silicon dioxide (SiO.sub.2) above the metal hard mask layer.
(32) Referring to
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(34) After the planarization of the 2.sup.nd mask 320, another photolithography masking is performed, in which a 3.sup.rd mask 330 is layered on the 2.sup.nd mask 320, and then, is patterned to form two openings H1 and H2 through which two sections of a top surface of the 2.sup.nd mask 320 is exposed. Here, like the 1.sup.st mask 310, the 3.sup.rd mask 330 may also be formed of, for example, a metal hard mask layer of TiN and a block cut hard mask layer of SiON or SiO.sub.2 above the metal hard mask layer.
(35) Referring to
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(39) According to an embodiment, the via metal 204 may be formed of at least one of ruthenium (Ru) and molybdenum (Mo) for a direct etching thereon to be performed in a later step.
(40) The via metal 204 is further formed on the top surfaces of the 3.sup.rd layer 230 remaining after the etching process shown in
(41) In
(42) According to an embodiment, after the direct-etching process performed on the via metal 204 without using the convention damascene process, a vertical side S1 the supervia 204S1 and a vertical side S3 of 204S2 facing the 3.sup.rd trench T3 do not contact any barrier metal pattern while another vertical side S2 of the supervia 204S1 and another vertical side S4 of the super via 20452 contact the barrier metal pattern 205S formed in the 2.sup.nd trench T2.
(43) In
(44) The inter-metal layer 240 formed herein between the two supervias 20451 and 20452 may be a single layer, in which case the vertical side S1 of the supervia 20451 and the vertical side S3 of the supervia 20452 face a single inter-metal layer while the other vertical side S2 of the supervia 20451 and the other vertical side S4 of the supervia 20452 face two inter-metal layers, that is, the 2.sup.nd and 3.sup.rd inter-metal layers 220 and 230, through the barrier metal pattern 205S, according to an embodiment.
(45) According to the above-described method, the supervias 20451 and 20452 having a high aspect ratio are easily formed without a concern of reaching down to the lower metal pattern 201 to which the supervias 20451 and 20452 are intended to be connected. Further, due to the additional masking and etching process including the supervia etching step shown in
(46) Referring back to
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(48) According to an embodiment, the supervia etching step performed in reference to
(49) As a result of the above process, an additional supervia 20353 in addition to the two supervias 20451 and 20452 with two trenches T4 and T5 therebetween may be obtained as shown in
(50) Meantime, as the direct etching is applied to the via metal 204 from its top surface exposed between the three sections of the 4.sup.th mask 340 as describe above, the additional supervia 20453 obtained by the direct etching does not contact any barrier metal pattern at its two vertical sides S5 and S6 facing the two trenches T4 and T5, respectively.
(51) After the three supervias 20451 to 20453 and the two trenches T4 and T5 are formed, an inter-metal layer 250 having low conformality such as silicon carbon nitride (SiCN) may be deposited in the two trenches T4 and T5 by plasma enhanced chemical vapor deposition (PECVD), according to an embodiment. Due to its less conformal characteristics, the inter-metal layer 250 may not fill the two trenches T4 and T5 entirely, and thus, an air gap AIR may be formed between the inter-metal layer 250 and the etch stop layer 221 at the bottom of the two trenches T4 and T5, according to an embodiment. With this air gap formed between the supervias 20451 to 20453, possible capacitance between the supervias 20451 to 20453 may be lowered than when the two trenches T4 and T5 are filled in with other low-k materials such as SiCOH.
(52) As the inter-metal layer 250 formed in the two trenches T4 and T5 may be a single layer, in which case the two vertical sides S5 and S6 of the supervia 20453 faces a single inter-metal layer and the air gap AIR, according to an embodiment.
(53) According to an embodiment, the above methods for forming supervias may also be applied to forming regular vias such as the vias 103 and 203 shown in
(54) In the previous embodiments described in reference to
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(56) In operation S20, a BEOL interconnect structure is provided on a substrate, where the BEOL interconnect structure includes 1.sup.st to 3.sup.rd inter-metal layers 210, 220 and 230 stacked in this order, a lower metal pattern 201 formed in the 1.sup.st inter-metal layer, and an etch stop layer 221 formed on a top surface of the lower metal pattern 201, as shown in
(57) In operation S30, photolithography masking is performed such that a 1.sup.st mask 310 is formed above the 3.sup.rd inter-metal layer 230, of which a section is patterned to provide a space for etching down the 3.sup.rd inter-metal layer 230, as shown in
(58) In operation S40, a section of the 3.sup.rd inter-metal layer 230 is etched down using the 1.sup.st mask 310 patterned in the previous operation to form a 1.sup.st trench T1, of which bottom and side surfaces are defined by a top surface of the 2.sup.nd inter-metal layer 220, the patterned 1.sup.st mask 310 and the etched 3.sup.rd inter-metal layer 230, as shown in
(59) In operation S50, the 1.sup.st trench T1 is filled with a 2.sup.nd mask 320 extended to and above top surfaces of the patterned 1.sup.st mask 310 and then planarized, after which another photolithography masking is performed to layer a 3.sup.rd mask 330 on the 2.sup.nd mask 320 and pattern the 3.sup.rd mask to have two openings H1 and H2 through which two sections of a top surface of the 2.sup.nd mask 320 are exposed, as shown in
(60) In operation S60, supervia etching is performed on the 2.sup.nd mask 320 and the 2.sup.nd inter-metal layer 220 from the two openings H1 and H2 using the patterned 3.sup.rd mask 330 and the patterned 1.sup.st mask 310 to form two supervia holes SH1 and SH1 penetrating the 3.sup.rd inter-metal layer 230 and the 2.sup.nd inter-metal layer 220, and two small holes R1 and R2 connected to the two supervia holes SH1 and SH2 and penetrating the 2.sup.nd etch stop layer 221 to expose a top surface of the lower metal pattern 201 through the two openings H1 and H2, as shown in
(61) In operation S70, the 2.sup.nd and 3.sup.rd masks 320 are removed by an ashing and/or etching process leaving the 2.sup.nd inter-metal layer 220 between the two supervia holes SH1 and SH2 and below 2.sup.nd mask 320 prior to its removal, as shown in
(62) In operation S80, using the 1.sup.st mask 310, the 2.sup.nd inter-metal layer 220 between the two supervia holes SH1 and SH2 and above the 2.sup.nd etch stop layer 221 between the small holes R1 and R2 is etched away, and then, the 1.sup.st mask 310 is stripped off, by which a 2.sup.nd trench T2 including the supervia holes SH1 and SH2 is formed with its bottom surface defined by the 2.sup.nd etch stop layer 221 and the top surface of the lower metal pattern 201 exposed through the two small holes R1 and R2 at the etch stop layer 221, as shown in
(63) In operation S90, a barrier metal pattern 205S is layered on the 2.sup.nd trench T2, and then, a via metal 204 is deposited on the barrier metal pattern 205S to fill in the 2.sup.nd trench T2. Due to the apparently lower aspect ratio of width and depth of the 2.sup.nd trench T2 than that of the related art supervia hole, the via metal 204 is easily filled in the 2.sup.nd trench T2. Further, due to the two holes R1 and R2 at the etch stop layer 221 formed by the etching process in
(64) In operation S100, a 4.sup.th mask 340 is formed on two sections at the top surface of the via metal 204, and then, using the 4.sup.th mask 340, the via metal 204 is direct-etched to form a 3.sup.rd trench T3 having supervias 204S1 and 20452, below the 4.sup.th mask 340, self-aligned in the two holes R1 and R2, as shown in
(65) In operation S110, the 3.sup.rd trench T3 is filled out with another inter-metal layer 240, and the 4.sup.th mask 340 is removed to finish the BEOL interconnect structure including the two supervias 20451 and 20452, as shown in
(66) The above operations of forming two supervias may also apply to forming three or more supervias as shown in
(67) According to the above-described embodiments, a wide trench having a lower aspect ratio of width and depth is used to form a supervia structure from which a number of desired supervias can be obtained. Further, by using an additional photolithography masking process, a self-aligned supervia can be formed. In addition, by forming an air gap between supervias, occurrence of unwanted capacitance between the supervias may be prevented. The foregoing method of forming supervias may also apply to regular via structures.
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(69) Referring to
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(71) Referring to
(72) At least the microprocessor 610, the memory 620 and/or the RAM 550 in the electronic system 600 may include one or more via or supervia structures described in the above embodiments.
(73) The foregoing is illustrative of exemplary embodiments and is not to be construed as limiting thereof. For example, one or more steps described above for manufacturing a supervia may be omitted to simplify the process. Although a few exemplary embodiments have been described, those skilled in the art will readily appreciate that many modifications are possible in the above embodiments without materially departing from the inventive concept.