Protective thermal sleeve for portable electronic devices and pharmaceuticals
11254091 · 2022-02-22
Assignee
Inventors
Cpc classification
G06K19/07758
PHYSICS
B32B1/00
PERFORMING OPERATIONS; TRANSPORTING
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
B32B2255/10
PERFORMING OPERATIONS; TRANSPORTING
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B2307/4023
PERFORMING OPERATIONS; TRANSPORTING
A45C11/00
HUMAN NECESSITIES
B32B5/18
PERFORMING OPERATIONS; TRANSPORTING
A45C2011/003
HUMAN NECESSITIES
B32B5/245
PERFORMING OPERATIONS; TRANSPORTING
A45C2011/002
HUMAN NECESSITIES
B32B5/02
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B5/24
PERFORMING OPERATIONS; TRANSPORTING
B32B27/06
PERFORMING OPERATIONS; TRANSPORTING
B32B5/18
PERFORMING OPERATIONS; TRANSPORTING
A45C11/00
HUMAN NECESSITIES
B32B5/02
PERFORMING OPERATIONS; TRANSPORTING
B32B1/00
PERFORMING OPERATIONS; TRANSPORTING
G06K19/077
PHYSICS
Abstract
Protective sleeves for portable electronic devices or thermally sensitive pharmaceuticals are provided. More particularly, embodiments relate to a protective sleeve that is capable of protecting a portable electronic device or a thermally sensitive pharmaceutical enclosed within from multiple environmental effects, including heat, cold, water, impact forces from being dropped, and germs and bacteria. In embodiments, provided is a protective sleeve comprising: an outer layer of material with a reflective surface; and an inner layer of material with a protective surface that can include an antimicrobial agent; wherein the outer layer of material and the inner layer of material are layered together and configured to receive a portable electronic device or thermally sensitive pharmaceutical. A thermal masking material and products thereof which can be used in a variety of applications where reduced visibility and heat detection is desired such as military, law enforcement, and hunting are also described.
Claims
1. A protective sleeve comprising a cavity, wherein the cavity is capable of holding an electronic device or a thermally sensitive pharmaceutical, and wherein the protective sleeve further comprises: a first layer which is a reflective layer comprising a reflective metalized surface; a second layer comprising nylon, wherein the first layer is bonded to the second layer to provide the first layer with increased durability; a third layer comprising a foam material; and a fourth innermost layer comprising a textile material comprising an antimicrobial agent, wherein the fourth innermost layer has at least one side that forms the cavity within the protective sleeve; wherein the first layer, the second layer, the third, and the fourth innermost layer are in a stacked configuration.
2. The protective sleeve of claim 1, wherein the fourth innermost layer contacts the electronic device or the thermally sensitive pharmaceutical held within the cavity of the protective sleeve.
3. The protective sleeve of claim 1, wherein the first layer is polyester film, and wherein the first layer is laminated by heat and pressure to the second layer comprising nylon.
4. The protective sleeve of claim 1, further comprising a colored or printed outer surface material.
5. The protective sleeve of claim 1, wherein the textile material comprises microfleece or polyester.
6. The protective sleeve of claim 1, wherein the reflective metalized surface of the first layer is oriented facing toward the cavity.
7. The protective sleeve of claim 1, wherein the reflective metalized surface of the first layer is oriented facing away from the cavity and towards an outside environment.
8. The protective sleeve of claim 1, wherein the first layer comprises one or more coating wherein the coating is chosen from one or more of a water repellant coating, a non-breathable coating, a non-porous coating, a hydrophobic coating, a UV blocking coating, or a UV filtering coating, or combinations thereof.
9. The protective sleeve of claim 1, further comprising one or more of: a) a woven tag; b) pull tabs; c) a tether attachment point; d) a user ID; e) a radiofrequency identification (RFID) or Bluetooth low energy (BLW) beacon system capable of alerting when the sleeve is lost; f) a radiofrequency identification (RFID) or Bluetooth low energy (BLW) beacon system capable of determining and/or transmitting the location of the sleeve; and/or g) a closure.
10. The protective sleeve of claim 1, wherein the protective sleeve is capable of floating in water when the electronic device or the thermally sensitive pharmaceutical is held within the cavity.
11. A protective sleeve comprising a cavity, wherein the cavity is capable of holding an electronic device or a thermally sensitive pharmaceutical, and wherein the protective sleeve further comprises: a first outer layer of a printed or colored material; a second layer comprising a reflective metalized surface; a third layer comprising nylon; a fourth layer comprising a foam material; and a fifth innermost layer comprising a textile material, wherein the textile material comprises an antimicrobial agent, and wherein the fifth innermost layer has one side that forms a center cavity of the protective sleeve; wherein the first layer, the second layer, the third layer, the fourth layer, and the fifth layer are in a stacked configuration.
12. The protective sleeve of claim 11, wherein the reflective metalized surface of the second layer is completely covered.
13. The protective sleeve of claim 11, wherein the reflective surface of the second layer of material is partially covered.
14. The protective sleeve of claim 11, wherein the second layer is bonded to the third layer.
15. The protective sleeve of claim 11, wherein the second layer of material comprises metalized film laminated to nylon.
16. The protective sleeve of claim 11, wherein the first layer of material provides an outer surface comprising printed Rip Stop Nylon or a coated membrane fabric.
17. The protective sleeve of claim 11, wherein the fifth innermost layer comprises microfleece or polyester.
18. The protective sleeve of claim 11, wherein the reflective metalized surface of the second layer is oriented facing toward the center cavity.
19. The protective sleeve of claim 11, wherein the reflective metalized surface of the second layer is oriented facing away from the center cavity and towards the first outer layer.
20. The protective sleeve of claim 11, wherein the first outer layer comprises one or more coating wherein the coating is chosen from one or more of a water repellant coating, a non-breathable coating, a non-porous coating, a hydrophobic coating, a UV blocking coating, or a UV filtering coating, or combinations thereof.
21. The protective sleeve of claim 11, further comprising one or more of: a) a woven tag; b) pull tabs; c) a tether attachment point; d) a user ID; e) a radiofrequency identification (RFID) or Bluetooth low energy (BLW) beacon system capable of alerting when the sleeve is lost; f) a radiofrequency identification (RFID) or Bluetooth low energy (BLW) beacon system capable of determining and/or transmitting the location of the sleeve; and/or g) a closure.
22. The protective sleeve of claim 1, wherein the antimicrobial agent comprises one or more of silver, zeolite, ammonium chloride, triclosan, chitosan, zinc, or combinations thereof.
23. The protective sleeve of claim 11, wherein the antimicrobial agent comprises silver, zeolite, ammonium chloride, triclosan, chitosan, zinc, or combinations thereof.
24. The protective sleeve of claim 1, wherein the antimicrobial agent is located within and/or applied to the first layer and the fourth innermost layer.
25. The protective sleeve of claim 11, wherein the antimicrobial agent is located within and/or applied to the first outer layer and the fifth innermost layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings illustrate certain aspects of embodiments of the present invention, and should not be used to limit the invention. Together with the written description the drawings serve to explain certain principles of the invention.
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DETAILED DESCRIPTION OF VARIOUS EMBODIMENTS OF THE INVENTION
(23) Reference will now be made in detail to various exemplary embodiments of the invention. It is to be understood that the following discussion of exemplary embodiments is not intended as a limitation on the invention. Rather, the following discussion is provided to give the reader a more detailed understanding of certain aspects and features of the invention.
(24) As used herein, the term “about” is understood as within a range of normal tolerance in the art, for example within 2 standard deviations of the mean. The term “about” can be understood as within 10%, 9%, 8%, 7%, 6%, 5%, 4%, 3%, 2%, 1%, 0.5%, 0.1%, 0.05%, or 0.01% of the stated value. Unless otherwise clear from the context, all numerical values provided herein are modified by the term “about.”
(25) As used herein, the term “metallized” (as in “metallized” Mylar®) refers to a material such as a polymer film which has been coated with a thin layer of metal, such as aluminum, chromium, or nickel, typically through a physical vapor deposition (PVD) process. The thin layer of metal can be coated on one surface of the material or both surfaces.
(26) As used herein, the term “laminated” (or variations including “laminate”, “lamination”, and the like) refers to the process or result of creating a composite material by joining two layers together, typically under heat and pressure and through use of an adhesive.
(27) As used herein, “Mylar®” may be used interchangeably with “biaxially-oriented polyethylene terephthalate (PET) film”, “polyethylene terephthalate (PET) film”, “polyester film”, and similar terminology.
(28) According to embodiments, the protective sleeve may include two layers (outer, inner), three layers (outer, middle and inner), or four layers (outer, first middle layer, second middle layer, inner layer). In embodiments, the protective sleeve may include one or more layer of material in any number of layers. One or more of the layers of the protective sleeve may be bonded together, or may not be bonded together. In embodiments, some, all or none of the layers of material of the protective sleeve may be bonded to another layer in the protective sleeve. In embodiments, some, all or none of the layers of material of the protective sleeve may be bonded to another layer in the protective sleeve. In embodiments, some, all or none of the layers of material of the protective sleeve may be joined together.
(29) Various embodiments described below include a reflective layer such as a metallized Mylar® polyester film laminated to another material such as a Rip Stop Nylon to create a composite material. According to embodiments, the reflective layer may have a reflective surface (e.g. a surface which includes a thin metallic film which is deposited through metallization) and a non-reflective surface, or two reflective surfaces. In some embodiments where the reflective layer has one reflective surface, the composite may be manufactured such that the non-reflective surface is bound directly to the Rip Stop Nylon, such that the reflective surface remains exposed. In other embodiments where the reflective layer has one reflective surface, the composite may be manufactured such that that the reflective surface is bound directly to the Rip Stop Nylon such that the reflective surface is hidden. In embodiments where the reflective layer has two reflective surfaces, one reflective surface will be bound directly to the Rip Stop Nylon and hidden, and one will remain exposed. Thus, in embodiments of the protective sleeve which follow, a reflective surface may face outward (away from the electronic device), inward (toward the electronic device), or both inward and outward. The orientation of the reflective surfaces will depend on the particular application of the protective sleeve (e.g. whether it is intended to protect the device from heat, cold, or both). Further, the reflective surface(s) may be hidden (e.g. covered by another layer) or exposed. Not wishing to be bound by theory, it is the reflective surface(s) of the reflective layer which are believed to primarily trap/reflect infrared energy within or keep infrared energy out of the protective sleeve.
(30) A two-layer embodiment of the invention provides an outer reflective layer and inner protective layer. The outer reflective layer may include Mylar® polyester film, such as a highly-reflective “continuous” metalized Mylar® polyester film, or aluminized polyester film laminated to a Rip Stop Nylon or similar material, and the emissivity of the outer layer may be in the range of about 0.05 to 0.40, such as less than 0.40, less than 0.30, less than 0.20, or less than 0.10. For example, the emissivity can be 0.1 to 0.2, or 0.02 to 0.35, or 0.01 to 0.25, or 0.04 to 0.15, and so on. Further, in embodiments, the outer metalized surface of the outer reflective layer has a reflectivity in the range of between 80% and 100%, with a preferred range between 90% and 100%. The inner protective layer may include a micro-fleece type material (lining) which is capable of protecting the touch screen on the device and preventing scratches.
(31) A three-layer embodiment provides an outer reflective layer, a middle insulation/air space layer, and an inner protective layer. The outer reflective layer may include Mylar® polyester film such as a highly-reflective “continuous” metalized Mylar® polyester film, or aluminized polyester film laminated to a Rip Stop Nylon or similar material, and the emissivity of the outer layer may be less than 0.40 (0.05-0.40 is a preferred range), or in any range provided herein. Further, in embodiments, the outer metalized surface of the outer reflective layer has a reflectivity in the range of between 80% and 100%, with a preferred range between 90% and 100%. The middle insulation layer may include ⅛-⅜″ thick open cell insulation foam which provides buoyancy and additional drop/shock protection for the device. The inside protective layer may include a micro-fleece type material (lining) which protects the touch screen on the device and prevents scratches.
(32) A first four-layer embodiment provides an outer reflective layer, a first middle insulation layer, a second middle insulation layer, an inner protective layer. The outside reflective layer may include Mylar® polyester film or aluminized polyester film or similar material, and the emissivity of outer layer may be less than 0.40 (0.05-0.40 is a preferred range), or in any range provided herein. The first middle insulation layer may include nylon or polyester Rip Stop material similar to 70D Rip Stop Nylon. The second middle insulation layer may include a ⅛-⅜″ thick open cell insulation foam which provides buoyancy and additional drop/shock protection for the device. The inside protective layer may include a micro-fleece type material (lining) which protects the touch screen on the device and prevents scratches.
(33) A second four-layer embodiment provides an outer protective double layer which includes a layer of printed Rip Stop Nylon or similar material and a highly-reflective “continuous” metalized Mylar® polyester film, or aluminized polyester film laminated to a Rip Stop Nylon or similar material. Further, in embodiments, the surface of the outer reflective layer has a reflectivity in the range of between 80% and 100%, with a preferred range between 90% and 100%. Further, this embodiment includes a middle insulation/air space layer and an inner protective layer. The middle insulation layer may include ⅛-⅜″ thick open cell insulation foam which provides buoyancy and additional drop/shock protection for the device. The inside protective layer may include a micro-fleece type material (lining) which protects the touch screen on the device and prevents scratches.
(34) A third four-layer embodiment provides an outer reflective layer, a first middle insulation layer, a second middle insulation layer, an inner protective layer. The outside reflective layer may include Mylar® polyester film, such as a highly-reflective “continuous” metalized Mylar® polyester film, or aluminized polyester film laminated to a Rip Stop Nylon or similar material, and the emissivity of outer layer may be less than 0.40 (0.05-0.40 is a preferred range), or in any range provided herein. Further, in embodiments, the outer metalized surface of the outer reflective layer has a reflectivity in the range of between 80% and 100%, with a preferred range between 90% and 100%. The first middle insulation layer may include nylon or polyester Rip Stop material similar to 70D Rip Stop Nylon. The second middle insulation layer may include a ⅛-⅜″ thick open cell insulation foam which provides buoyancy and additional drop/shock protection for the device. The inside protective layer may include a micro-fleece type material (lining) which protects the touch screen on the device and prevents scratches.
(35) According to embodiments, a closure can be provided to close the protective sleeve, which closure may be a plastic spring strip closure or other closure system such as a hook and loop closure or similar type of closure. However, according to embodiments, the closure may be configured so that it does not seal the sleeve and thus allows thermal energy to dissipate through. Further, any embodiment may include a woven tag which provides a user ID on the tag.
(36) Turning now to the figures,
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(38) In another embodiment (shown in
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(43) In any embodiment of the invention, the outer surface or layer can be coated with any one or more of a water repellant coating, a non-breathable coating, a non-porous coating, a hydrophobic coating, a UV blocking coating, or a UV filtering coating. Further, any embodiment of the invention can include a closure such as a plastic spring strip closure, hook and loop closure, magnetic closure, and the like. Further, it is preferred that the closure does not seal the sleeve completely to allow thermal energy to dissipate through.
(44) Additionally, any embodiment may include additional features such as a woven tag, easy open pull tabs made of PVC rubber, nylon webbing, or similar materials, one or more tether attachment points, a User ID, and a radiofrequency identification (RFID) or Bluetooth low energy (BLW) beacon system or similar technology for alerting the location of the protective sleeve. Further, in certain embodiments, the protective sleeve may include one or more pockets for holding miscellaneous items. The one or more pockets can be formed on the outside or inside surface(s) of the sleeve and have the same or different material construction as the case or sleeve.
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(47) Additional embodiments include a thermal masking material which includes a colored or printed nylon outer layer and an IR reflective layer with an emissivity within the range of 0.05 to 0.2 constructed of a highly reflective continuous metalized reflective layer such as a metalized reflective polyethylene terephthalate (PET) film (e.g. Mylar®) disposed beneath the colored or printed outer layer. Various materials of the thermal masking material include the following layers of materials:
(48) Material A: Printed Rip Stop Nylon
(49) Material B: IR Reflective material with an emissivity within the range of 0.05-0.2 constructed and constructed of a highly reflective “continuous” metalized Mylar or similar material
(50) Material C: Nylon or polyester ripstop material similar to 70D Rip Stop Nylon
(51) Material D: Layer of open cell flat foam surface or similar consisting of no less than ⅜ of an inch thickness
(52) Material E: Polyester micro-fleece or similar type material
(53) The above materials can be utilized in the thermal masking material in any order, such as in the embodiments below:
(54) Embodiment #1 which is reversible provides the layers/materials in the following order: A, B, C, D, C, B, A.
(55) Embodiment #2 which also is reversible provides the layers/materials in the following order: A, B, C, D, E, D, C, B, A.
(56) Embodiment #3 which is not reversible provides the layers/materials in the following order: A, B, C, D, E.
(57) Embodiment #4 which is not reversible provides the layers in the following order: A, B, C, D.
(58) Embodiment #5 which is not reversible provides the layers in the following order; A, B, C.
(59) Variations of the above embodiments are contemplated which have less layers/materials or layers/materials arranged in a different order, provided that, in embodiments, Material B is always present in at least one layer of the layered construction.
(60) The thermal masking material may have a variety of uses.
(61) In aspects, the invention includes a material comprising a colored or printed outer surface and a continuous metalized reflective surface there beneath.
(62) In aspects, the invention includes a material comprising a colored or printed outer surface and a continuous metalized reflective surface there beneath, wherein the reflective surface is an inner liner.
(63) In aspects, the invention includes a reflective surface disposed between an inner liner and the outer surface.
(64) In aspects, the invention includes a material comprising a colored or printed outer surface and a continuous metalized reflective surface there beneath, wherein the outer surface comprises nylon and the continuous metalized reflective surface is attached or bonded to an underside of the nylon.
(65) In aspects, the invention covers a material comprising a colored or printed outer surface and a continuous metalized reflective surface there beneath, wherein the outer surface comprises Ripstop or nylon with interwoven reinforcement threads arranged in a cross hatch pattern.
(66) In aspects, the invention includes a material comprising a colored or printed outer surface and a continuous metalized reflective surface there beneath, wherein the reflective surface is disposed between the outer layer and an inner layer and the inner layer is water resistant.
(67) In aspects, the invention includes a material comprising a colored or printed outer surface and a continuous metalized reflective surface there beneath, wherein the reflective surface is disposed between the outer layer, which is water resistant, and an inner layer, which is porous.
(68) In aspects, the invention includes tape comprising a colored or printed outer surface or layer, a continuous metalized reflective middle layer, and an innermost surface or layer comprising an adhesive.
(69) In aspects, the invention includes a method of using said tape for one or more of a sniper blind, clothing, camouflage clothing, camouflage covering, or camouflage sniper blind, or combinations thereof.
(70) In aspects, the invention includes a method of using said tape to cover equipment, whereby an air gap is disposed between the equipment and the material. This method may further comprise circulating cooled air in the air gap.
(71) In aspects, the invention includes a method of using said tape to cover a human, whereby an air gap is disposed between the human and the material. This method may further comprise circulating cooled air in the air gap.
(72) In aspects, the invention includes a thermal masking product comprising a first, second, and third surface layered together, wherein the second surface is a reflective surface and is disposed between the first surface and the third surface such that the reflective surface of the second surface is completely or partially covered.
(73) In aspects of the thermal masking product, the second surface is infrared (IR) reflective with an emissivity of 0.5 to 0.20.
(74) In aspects of the thermal masking product, the second surface comprises metalized polyester film.
(75) In aspects of the thermal masking product, the thermal masking product is a thermal masking tape wherein the first and/or third surfaces comprise an adhesive.
(76) In aspects of the thermal masking product, the first surface comprises printed Rip Stop Nylon, nylon with interwoven reinforcement threads arranged in a cross hatch pattern, or a coated membrane fabric.
(77) In aspects of the thermal masking product, the product is an article of clothing.
(78) In aspects of the thermal masking product, the second surface is laminated to the first surface, and the first or third surfaces comprise nylon.
(79) In aspects of the thermal masking product, the second surface comprises metalized polyester film.
(80) In aspects of the thermal masking product, the metalized polyester film has a reflectivity in the range of 80% to 100%.
(81) In aspects of the thermal masking product, the second layer of material further comprises interwoven reinforcement threads arranged in a cross hatch pattern.
(82) In aspects of the thermal masking product, the first surface is an outer surface comprising a coating chosen from one or more of a water repellant coating, a non-breathable coating, a non-porous coating, a hydrophobic coating, a UV blocking coating, or a UV filtering coating, or combinations thereof.
(83) In aspects, the invention includes a thermal masking product comprising three or more of the following layers:
(84) A. printed Rip Stop Nylon;
(85) B. an IR Reflective material with an emissivity within the range of 0.05 to 0.4;
(86) C. nylon;
(87) D. open or closed cell insulation foam; and/or
(88) E. microfleece or similar material
(89) wherein layer “B” is always present in the thermal masking product and is disposed between any one or more of layers A, C, D, or E.
(90) In aspects, the thermal masking product is reversible and comprises the layers in the following order: A, B, C, D, C, B, and A.
(91) In other aspects, the thermal masking product is not reversible and comprises the layers in the following order: A, B, C, D, C, B, and A.
(92) In other aspects, the thermal masking product is reversible and comprises the layers in the following order: A, B, C, D, E, D, C, B, and A.
(93) In other aspects, the thermal masking product is not reversible and comprises the layers in the following order: A, B, C, D, E, D, C, B, and A.
(94) In other aspects, the thermal masking product is reversible and comprises the layers in the following order: A, B, C, D, and E.
(95) In other aspects, the thermal masking product is not reversible and comprises the layers in the following order: A, B, C, D, and E.
(96) In other aspects, the thermal masking product is reversible and comprises the layers in the following order: A, B, C, and D.
(97) In other aspects, the thermal masking product is not reversible and comprises the layers in the following order: A, B, C, and D.
(98) In other aspects, the thermal masking product is reversible and comprises the layers in the following order: A, B, and C.
(99) In other aspects, the thermal masking product is not reversible and comprises the layers in the following order: A, B, and C.
(100) In other aspects, the thermal masking product is reversible and comprises the layers in the following order: C, B, and A.
(101) In other aspects, the thermal masking product is not reversible and comprises the layers in the following order: C, B, and A.
(102) In other aspects, the thermal masking product is an article of clothing.
(103) In other aspects of the thermal masking product, layer B is laminated to layer A or layer C.
(104) In aspects of the thermal masking product, layer B comprises polyester film.
(105) In aspects of the thermal masking product, layer B comprises metalized polyester film.
(106) In aspects of the thermal masking product, layer B is laminated to layer A or layer C and the thermal masking product comprises nylon with interwoven reinforcement threads arranged in a cross hatch pattern.
(107) In aspects of the thermal masking product, the metalized polyester film has a reflectivity in the range of 80% to 100%.
(108) In aspects of the thermal masking product, it is a plurality of plates configured to fit together to cover a piece of equipment.
(109) Various dimensions, materials, designs and embodiments provided in this disclosure are not intended to be limiting but are rather provided by way of example only. An artisan of ordinary skill is capable of modifying the dimensions of the protective sleeve to accommodate mobile or portable electronic devices of different dimensions, including a flip phone, smart phone, tablet, and laptop computer, according to the manufacturing specifications of a particular electronic device. The interior dimensions can thus be modified to accommodate electronic devices of different sizes. Further, other embodiments of the invention may include materials which have equivalent capabilities to those discussed herein, which may be apparent to a person who is skilled in the art.
(110) The present invention has been described with reference to particular embodiments having various features. In light of the disclosure provided above, it will be apparent to those skilled in the art that various modifications and variations can be made in the practice of the present invention without departing from the scope or spirit of the invention. One skilled in the art will recognize that the disclosed features may be used singularly, in any combination, or omitted based on the requirements and specifications of a given application or design. When an embodiment refers to “comprising” certain features, it is to be understood that the embodiments can alternatively “consist of” or “consist essentially of” any one or more of the features. Other embodiments of the invention will be apparent to those skilled in the art from consideration of the specification and practice of the invention.
(111) It is noted in particular that where a range of values is provided in this specification, each value between the upper and lower limits of that range is also specifically disclosed. The upper and lower limits of these smaller ranges may independently be included or excluded in the range as well. The singular forms “a,” “an,” and “the” include plural referents unless the context clearly dictates otherwise. It is intended that the specification and examples be considered as exemplary in nature and that variations that do not depart from the essence of the invention fall within the scope of the invention. Further, all of the references cited in this disclosure are each individually incorporated by reference herein in their entireties and as such are intended to provide an efficient way of supplementing the enabling disclosure of this invention as well as provide background detailing the level of ordinary skill in the art.