Methods and systems are provided for an emissions aftertreatment device. In one example, the emissions aftertreatment device may include a catalyst and a high entropy oxygen storage material formed of at least five metal oxides in equal molar proportions. The at least five metal oxides includes one or more rare earth metals as well as other metals with similar chemical properties as the rare earth metals.

The problem to be solved by the present invention is to provide an oxygen storage and release material comprising a ceria-zirconia-based complex oxide improved in ability to remove HC and NOx and a three-way catalyst able to reduce an amount of NOx emission. Further, to solve this problem, an oxygen storage and release material comprising a ceria-zirconia-based complex oxide containing Gd.sub.2O.sub.3 in 0.1 mol % or more and less than 20 mol % and having an ion conductivity of 2×10.sup.−5 S/cm or more at 400° C. is provided. Further, in addition to the above, an oxygen storage and release material having a molar ratio of cerium and zirconium of 0.2 or more and 0.6 or less by cerium/(cerium+zirconium) and an speed of oxygen storage and release “Δt.sub.50” of 20.0 seconds or more or amount of oxygen storage and release of 300 μmol-O.sub.2/g or more etc. was obtained. Further, by applying the oxygen storage and release material to the catalyst, it is possible to assist the purification of exhaust gas as it changes every instant in accordance with the driving conditions and possible to obtain a catalyst with a higher ability to remove harmful components of catalytic precious metals than before. In particular, it is possible to obtain an automotive exhaust gas purification system excellent in ability to remove CO, NOx, and HC.

The problem to be solved by the present invention is to provide an oxygen storage and release material comprising a ceria-zirconia-based complex oxide improved in ability to remove HC and NOx and a three-way catalyst able to reduce an amount of NOx emission. Further, to solve this problem, an oxygen storage and release material comprising a ceria-zirconia-based complex oxide containing Gd.sub.2O.sub.3 in 0.1 mol % or more and less than 20 mol % and having an ion conductivity of 2×10.sup.−5 S/cm or more at 400° C. is provided. Further, in addition to the above, an oxygen storage and release material having a molar ratio of cerium and zirconium of 0.2 or more and 0.6 or less by cerium/(cerium+zirconium) and an speed of oxygen storage and release “Δt.sub.50” of 20.0 seconds or more or amount of oxygen storage and release of 300 μmol-O.sub.2/g or more etc. was obtained. Further, by applying the oxygen storage and release material to the catalyst, it is possible to assist the purification of exhaust gas as it changes every instant in accordance with the driving conditions and possible to obtain a catalyst with a higher ability to remove harmful components of catalytic precious metals than before. In particular, it is possible to obtain an automotive exhaust gas purification system excellent in ability to remove CO, NOx, and HC.

A mixer comprises a tubular housing defining a longitudinal axis along which exhaust gas flows. Injected reductant flows along an injection axis that extends at a non-parallel angle to the longitudinal axis. A first flow guide element extends across and blocks a portion of the tubular housing and includes a first aperture extending therethrough. The first flow guide element is positioned upstream from the reductant inlet such that exhaust gas flowing through the first aperture is impinged by the reductant. A second flow guide element is positioned downstream from the first flow guide element and fixed to the first flow guide element to define a mixing chamber in which injected reductant and exhaust gas mix. An intermediate wall is integrally formed with one of the first and second flow guide elements. The other of the first and second flow guide elements is fixed to the intermediate wall.

A mixer comprises a tubular housing defining a longitudinal axis along which exhaust gas flows. Injected reductant flows along an injection axis that extends at a non-parallel angle to the longitudinal axis. A first flow guide element extends across and blocks a portion of the tubular housing and includes a first aperture extending therethrough. The first flow guide element is positioned upstream from the reductant inlet such that exhaust gas flowing through the first aperture is impinged by the reductant. A second flow guide element is positioned downstream from the first flow guide element and fixed to the first flow guide element to define a mixing chamber in which injected reductant and exhaust gas mix. An intermediate wall is integrally formed with one of the first and second flow guide elements. The other of the first and second flow guide elements is fixed to the intermediate wall.

The present invention relates to an exhaust gas treatment system for treating exhaust gas from a lean burn combustion engine, wherein said exhaust gas comprises hydrocarbons and NOx, the exhaust gas treatment system comprising: (i) a means for injecting hydrocarbons into an exhaust gas stream; (ii) a diesel oxidation catalyst (DOC) comprising a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises one or more platinum group metals, wherein the one or more platinum group metals comprise platinum; (iii) a means for injecting a nitrogenous reducing agent into an exhaust gas stream; and (iv) a multifunctional catalyst (MFC) comprising an oxidation catalyst, and a selective catalytic reduction (SCR) catalyst for the selective catalytic reduction of NOx, wherein the MFC comprises a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises the oxidation catalyst and the SCR catalyst, wherein the oxidation catalyst comprises one or more platinum group metals, wherein the one or more platinum group metals comprise palladium and/or platinum, and wherein the SCR catalyst comprises a zeolitic material loaded with copper and/or iron; wherein the means for injecting hydrocarbons, the DOC, the means for injecting a nitrogenous reducing agent, and the MFC are located in sequential order in a conduit for exhaust gas, wherein the means for injecting hydrocarbons into an exhaust gas stream is located upstream of the DOC, wherein the DOC is located upstream of the MFC, and wherein the means for injecting a nitrogenous reducing agent into the exhaust gas stream is located between the DOC and the MFC. Furthermore, the present invention relates to a method for the treatment of exhaust gas using the exhaust gas treatment system according to the present invention, and to a method for the preparation of an exhaust gas treatment system according to the present invention.

A method of manufacturing a catalyst article, the method comprising: providing an anionic complex comprising a PGM and a carboxylate ion; providing a support material; applying the anionic complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.

A method for diagnosing a NOx sensor is provided. The method includes receiving data indicative of operating conditions of an engine or an aftertreatment system; determining, during a first period of time, that an amount of NOx output from the aftertreatment system satisfies a low NOx operating mode condition; determining, during a second period of time, that operating conditions for ammonia slip are present based on data regarding operation of the aftertreatment system; responsive to the determination that operating conditions for ammonia slip are present, determining that the amount of NOx output from the aftertreatment system satisfies a high NOx operating mode condition; comparing a difference between a minimum value from the first period of time and a maximum value from a second period of time to a diagnostic threshold; and responsive to the difference being less than the diagnostic threshold, setting an alert.

A thermal diffusion unit is fluidly connected to a combustion engine via a flue line. The thermal diffusion unit has a plurality of plates assembled in a parallel configuration, including a pair of heating plates having a heating fluid gap extending therebetween and a pair of cooling plates having a cooling fluid gap extending therebetween. A diffusion sheet is positioned between the pair of heating plates and the pair of cooling plates, such that the diffusion sheet interfaces on a first side with one of the heating plates and interfaces on an opposite side with one of the cooling plates. The diffusion sheet includes a plurality of interconnected thermal diffusion cells arranged in a repeating pattern, at least one heated passage fluidly connecting adjacent thermal diffusion cells, and at least one cooled passage fluidly connecting adjacent thermal diffusion cells.

Provided are a method and an ICE system, including an internal combustion engine including a first and a second set of cylinders. A first and a second EGR valve control flow of exhaust gas from the cylinders to an EGR conduit. A controller controls the closing of the second EGR valve, thereby preventing flow of exhaust gas from the second set of cylinders to the EGR conduit. The second EGR valve is upstream of a turbine. The controller is configured to activate a fuel injector for late post injection of fuel into the second set of cylinders when the second EGR valve is closed, so that at least a part of the fuel that exits the second set of cylinders is uncombusted. An exhaust gas aftertreatment system receives and treats exhaust gas which is not recirculated in the EGR conduit, and includes an oxidation catalyst for combustion.