A system and method for utilizing fuel as an on-board reductant for selective catalytic reduction of NOx is provided and includes a controller for controlling an engine to produce a lean first exhaust stream and a rich second exhaust stream that are received in respective first and second passageways of a dual path aftertreatment system. The rich second exhaust stream reacts with NOx stored in a NOx storage and reduction catalyst of the second passageway to regenerate this catalyst and generate ammonia. The first exhaust stream and the second exhaust stream having the generated ammonia are combined in a downstream common passageway to form a combined lean exhaust gas stream where the ammonia carried therein is stored or used by an SCR catalyst of the common passageway for NOx reduction. The engine is subsequently controlled to produce a rich first exhaust stream and a lean second exhaust stream.

The present disclosure provides catalyst compositions for NOx conversion and catalytic articles incorporating such catalyst compositions. Certain catalyst compositions include a zeolite with a silica-to-alumina ratio from 5 to 20 and sufficient Cu exchanged into cation sites of the zeolite such that the zeolite has a Cu/Al ratio of 0.1 to 0.5 and a CuO loading of 1 to 15 wt. %; and a copper trapping component in a concentration in the range of 1 to 20 wt. %, the copper trapping component including a plurality of particles having a particle size of about 0.5 to 20 microns. Certain catalyst compositions include, as the copper trapping component, alumina present as a plurality of alumina particles with a D.sub.90 particle size distribution in the range of 0.5 microns to 20 microns.

In a process for adapting an amount of reducing agent for a removal of nitrogen oxides from the gases in an exhaust line, a first alignment of the amounts of nitrogen oxides measured by upstream and downstream sensors is performed without injection of agent and with a catalyst of the system emptied of ammonia. A second alignment of the estimated reduction of nitrogen oxides with the measured reduction is performed by a difference between amounts of nitrogen oxides upstream and downstream during a substoichiometric injection of reducing agent without creating a store of ammonia in a catalyst of the system with a first correction of the amount of agent. A third alignment of an estimated efficiency of retaining nitrogen oxides with a efficiency measured by the sensors is performed, this third alignment taking place via a second correction of the amount of reducing agent injected as an adaptive correction.

A method for operating a motor vehicle having an exhaust gas aftertreatment device involves an on-board electronic computing device receiving consumption information characterizing consumption of a reducing agent by the exhaust gas aftertreatment device and tank information characterizing a filling level of a reducing agent tank. Tank information is evaluated together with the consumption information with regard to a divergence, and upon determination of the divergence between the tank information and the consumption information, error information is stored in a blockchain characterizing the motor vehicle, and an action of the motor vehicle is triggered.

Methods and systems are provided for adjusting a regeneration scheme in response to ageing of a first catalyst and a second catalyst. In one example, a method may include determining a first ageing of the first catalyst and a second ageing of the second catalyst and updating factors of the regeneration scheme based on the first ageing and the second ageing.

An aftertreatment system for treatment of exhaust gases exiting an engine includes a first Selective Catalytic Reduction (SCR) device in fluid communication with the engine. The first SCR device receives the exhaust gases exiting the engine for reducing a first quantity of oxides of nitrogen (NOx) present in the exhaust gases. The aftertreatment system also includes an oxidation catalyst in fluid communication with the first SCR device. The oxidation catalyst receives the exhaust gases exiting the first SCR device for oxidizing ammonia present in the exhaust gases into a second quantity of NOx. The aftertreatment system further includes a second SCR device in fluid communication with the oxidation catalyst. The second SCR device receives the exhaust gases exiting the oxidation catalyst for reducing the second quantity of NOx.

Certain catalytic articles, systems or methods provide for excellent NOx conversion and are especially suitable for low temperature NOx conversion. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles or systems contain an upstream SCR composition and a downstream LNT composition. The substrate(s) may advantageously be electrically heated.

Provided is an exhaust gas purification apparatus having a control device that monitors the transition of a detection value of each of an upstream NOx sensor and a downstream NOx sensor, and when the NOx purification rate of the SCR catalyst falls to a value of a first threshold or lower, generates an abnormality detection signal indicating that an over storage state has occurred in an SCR catalyst if the amount of change in the detection value of the upstream NOx sensor per unit time is at least a second threshold and the amount of change in the detection value of the downstream NOx sensor per unit time is at most a third threshold.

Provided is a combustion system using a catalyst having better denitration efficiency at low temperatures, during a selective catalytic reduction reaction in which ammonia is used as a reducing agent.

This combustion system comprises: a combustion device that combusts fuel; an exhaust path through which flows exhaust gas generated from the combustion of fuel in the combustion device; a dust collection device that is arranged on the exhaust path and collects ash dust/dust in the exhaust gas; and a denitration device that is arranged on the exhaust path and removes nitrogen oxides from the exhaust gas by means of a denitration catalyst, wherein the denitration device is arranged downstream of the dust collection device on the exhaust path, and the denitration catalyst contains vanadium oxide including vanadium pentoxide and has a defect site in which an oxygen atom is deficient in a crystal structure of the vanadium pentoxide.

Methods and systems are provided for a vehicle. In one example, a method may include acquiring measurements from at least one exhaust emission sensor of the vehicle, the exhaust emission sensor positioned to measure one of NO.sub.x, NH.sub.3, and O.sub.2 levels in exhaust gas of the vehicle. The measurements may be input into a machine learning model trained to output a predicted real-time amount of at least one exhaust gas constituent in the exhaust gas and operations of an emissions aftertreatment system may be assessed and adjusted based on the predicted real-time amount of the at least one exhaust gas constituent.