An electrochemical device which is an alkali metal battery or an alkaline earth metal battery, wherein only a positive electrode is an electrode having a perfluoropolyether group-containing compound in a surface thereof.

Provided is a method for manufacturing an electrode by doping an active material included a layer of an electrode precursor with alkali metal. The electrode precursor and a counter electrode member are brought into contact with a solution containing an alkali metal ion in a dope bath. The counter electrode member includes a conductive base material, an alkali metal-containing plate, and a member having an opening. The member having the opening is located between the conductive base material and the alkali metal-containing plate. The member having the opening is, for example, a resin film having an opening.

The present disclosure provides an electrolytic solution having high reduction stability. An electrolytic solution, wherein the electrolytic solution is used in a fluoride ion battery, and the electrolytic solution includes a Li salt, a F salt, and a trialkyl phosphate.

The present disclosure provides an electrolytic solution having high reduction stability. An electrolytic solution, wherein the electrolytic solution is used in a fluoride ion battery, and the electrolytic solution includes a Li salt, a F salt, and a trialkyl phosphate.

The present invention provides an active electrode material comprising a mixture of (a) at least one niobium oxide and (b) at least one mixed niobium oxide; wherein the mixed niobium oxide has the composition M1.sub.aM2.sub.1-aM3.sub.bNb.sub.12-bO.sub.33-c-dQ.sub.d, wherein: M1 and M2 are different; M1 is selected from Mg, Ca, Sr, Y, La, Ce, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, P, Sb, Bi and mixtures thereof; M2 is Mo or W; M3 is selected from Mg, Ca, Sr, Y, La, Ce, Ti, Zr, Hf, V, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, P, Sb, Bi, and mixtures thereof; Q is selected from F, Cl, Br, I, N, S, Se, and mixtures thereof; 0≤a<0.5; 0≤b≤2; −0.5≤c≤1.65; 0≤d≤1.65; one or more of a, b, c and d does not equal zero; and when a, b, and d equal zero, c is greater than zero. Such materials are of interest as active electrode materials in lithium-ion or sodium-ion batteries.

The present invention provides an active electrode material comprising a mixture of (a) at least one niobium oxide and (b) at least one mixed niobium oxide; wherein the mixed niobium oxide has the composition M1.sub.aM2.sub.1-aM3.sub.bNb.sub.12-bO.sub.33-c-dQ.sub.d, wherein: M1 and M2 are different; M1 is selected from Mg, Ca, Sr, Y, La, Ce, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, P, Sb, Bi and mixtures thereof; M2 is Mo or W; M3 is selected from Mg, Ca, Sr, Y, La, Ce, Ti, Zr, Hf, V, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, P, Sb, Bi, and mixtures thereof; Q is selected from F, Cl, Br, I, N, S, Se, and mixtures thereof; 0≤a<0.5; 0≤b≤2; −0.5≤c≤1.65; 0≤d≤1.65; one or more of a, b, c and d does not equal zero; and when a, b, and d equal zero, c is greater than zero. Such materials are of interest as active electrode materials in lithium-ion or sodium-ion batteries.

A flat-plate type sodium metal battery and an electrochemical device are described. The battery comprises a positive electrode plate and a negative electrode plate, the positive electrode plate provided with a first micro-through-hole arranged in an array on at least part of the surface thereof, the negative electrode plate provided with a second micro-through-hole arranged in an array on at least part of the surface thereof, wherein the first micro-through-hole and the second micro-through-hole have an overlapping area of ≥5% of the total area of the second micro-through-hole of the negative electrode plate. Disposing a first micro-through-hole on the positive electrode plate, and a second micro-through-hole on the negative electrode plate, and setting the aperture size and aperture spacing of micro-through-holes are beneficial to increasing infiltration and penetration of the electrolyte in the positive electrode plate and are conducive to rapid infiltration to large-sized electrode plates.

A flat-plate type sodium metal battery and an electrochemical device are described. The battery comprises a positive electrode plate and a negative electrode plate, the positive electrode plate provided with a first micro-through-hole arranged in an array on at least part of the surface thereof, the negative electrode plate provided with a second micro-through-hole arranged in an array on at least part of the surface thereof, wherein the first micro-through-hole and the second micro-through-hole have an overlapping area of ≥5% of the total area of the second micro-through-hole of the negative electrode plate. Disposing a first micro-through-hole on the positive electrode plate, and a second micro-through-hole on the negative electrode plate, and setting the aperture size and aperture spacing of micro-through-holes are beneficial to increasing infiltration and penetration of the electrolyte in the positive electrode plate and are conducive to rapid infiltration to large-sized electrode plates.

An electrolytic solution is provided and includes an electrolytic solution for an electrochemical device including a magnesium electrode as a negative electrode and a positive electrode, the electrolytic solution containing: a solvent; and a first magnesium salt having a disilazide structure represented by General Formula (1):

(R.sub.3Si).sub.2N  (1) wherein R is an aliphatic hydrocarbon group having 1 or more and 10 or less carbon atoms, and each R may be the same as or different from each other, the electrolytic solution substantially comprising no halogen.

An aluminum battery negative electrode structure includes an aluminum foil and a coating layer. The coating layer is arranged on the aluminum foil. A material of the coating layer includes a high specific surface area carbon material. A specific surface area of the high specific surface area carbon material ranges from 500 m.sup.2/g to 3,000 m.sup.2/g.