This disclosure relates to an SO.sub.2-based electrolyte for a rechargeable battery cell containing at least one conducting salt of the Formula (I) ##STR00001##
wherein M is a metal selected from the group consisting of alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements and aluminum; x is an integer from 1 to 3; the substituents R, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from the group consisting of C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.1 alkenyl, C.sub.2-C.sub.1 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl, and C.sub.5-C.sub.14 heteroaryl; and Z is aluminum or boron.

This disclosure relates to an SO.sub.2-based electrolyte for a rechargeable battery cell containing at least one conducting salt of the Formula (I) ##STR00001##
wherein M is a metal selected from the group consisting of alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements and aluminum; x is an integer from 1 to 3; the substituents R, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from the group consisting of C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.1 alkenyl, C.sub.2-C.sub.1 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl, and C.sub.5-C.sub.14 heteroaryl; and Z is aluminum or boron.

The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A.sub.3-xH.sub.xOX, in which 0≦x≦1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.

The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A.sub.3-xH.sub.xOX, in which 0≦x≦1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.

There is provided a secondary battery including a cathode, an anode including an anode active material layer and a coating film, and an electrolytic solution. The anode active material layer includes a titanium-containing compound, and a surface of the anode active material layer is coated with the coating film. The electrolytic solution includes one or more of unsaturated cyclic carbonate esters. Porosity of a portion of the anode active material layer measured with use of a mercury intrusion technique is within a range from 30% to 50% both inclusive. The portion of the anode active material layer is cut together with a portion of the coating film from a surface of the coating film to a depth of 10 μm.

There is provided a secondary battery including a cathode, an anode including an anode active material layer and a coating film, and an electrolytic solution. The anode active material layer includes a titanium-containing compound, and a surface of the anode active material layer is coated with the coating film. The electrolytic solution includes one or more of unsaturated cyclic carbonate esters. Porosity of a portion of the anode active material layer measured with use of a mercury intrusion technique is within a range from 30% to 50% both inclusive. The portion of the anode active material layer is cut together with a portion of the coating film from a surface of the coating film to a depth of 10 μm.

A solid electrolyte for an alkali metal solid state battery, the solid electrolyte comprising a mixture of two different alkali metal conducting salts and a semi-interpenetrating network (sIPN) of a crosslinked and a non-crosslinked polymer, wherein the semi-interpenetrating network is greater than or equal to 50 wt.-% and less than or equal to 80 wt.-% of a non-crosslinked polymer selected from the group consisting of polyethylene oxide (PEO), polycarbonate (PC), polycaprolactone (PCL), chain end modified derivatives of these polymers or mixtures of at least two components thereof; and greater than or equal to 10 wt.-% and less than or equal to 50 wt.-% of a polycarbonate of crosslinkable polyalkyl carbonate monomers having a carbon number greater than or equal to 2 and less than or equal to 15 based on the single monomer as the crosslinked polymer.

A solid electrolyte for an alkali metal solid state battery, the solid electrolyte comprising a mixture of two different alkali metal conducting salts and a semi-interpenetrating network (sIPN) of a crosslinked and a non-crosslinked polymer, wherein the semi-interpenetrating network is greater than or equal to 50 wt.-% and less than or equal to 80 wt.-% of a non-crosslinked polymer selected from the group consisting of polyethylene oxide (PEO), polycarbonate (PC), polycaprolactone (PCL), chain end modified derivatives of these polymers or mixtures of at least two components thereof; and greater than or equal to 10 wt.-% and less than or equal to 50 wt.-% of a polycarbonate of crosslinkable polyalkyl carbonate monomers having a carbon number greater than or equal to 2 and less than or equal to 15 based on the single monomer as the crosslinked polymer.

An electrolyte composition for a battery is provided. The electrolyte composition includes a lithium salt in a carbonate-based solution and lithium difluoro(oxalate)borate present in the electrolyte composition in an amount from 0.1 part by weight to 5 parts by weight based on 100 parts by weight of the electrolyte composition.

An electrolyte composition for a battery is provided. The electrolyte composition includes a lithium salt in a carbonate-based solution and lithium difluoro(oxalate)borate present in the electrolyte composition in an amount from 0.1 part by weight to 5 parts by weight based on 100 parts by weight of the electrolyte composition.