An all-solid secondary battery includes: a cathode layer; an anode layer; and a solid electrolyte between the cathode layer and the anode layer, wherein the anode layer includes an anode current collector and a first anode active material layer on the anode current collector, the first anode active material layer includes a modified ordered mesoporous carbon, and an oxygen content of a surface of the modified ordered mesoporous carbon is about 3 atomic percent to about 10 atomic percent, based on a total content of the surface, when determined by an X-ray photoelectron spectroscopy spectrum of the surface of the modified ordered mesoporous carbon.

In a metal negative electrode, a current collector includes a through-hole or a recess provided to extend from a front surface of a planar plate toward a back surface of the planar plate. A distance from a midpoint of a joining boundary to a point on a surface of the current collector is designated as a region dividing distance, the point defining a distance less than a maximum distance between the midpoint and a side or a surface of the current collector. In the current collector, a first region is a region defined by distances from the midpoint, the distances being a distance equal to the region dividing distance and distances greater than the region dividing distance, and, in the current collector, a second region is a region defined by distances from the midpoint that are less than the region dividing distance. A volume reduction ratio of the first region is greater than a volume reduction ratio of the second region, the volume reduction ratio of the first region being a ratio with respect to a volume of the first region determined assuming that the through-hole or the recess is not present, the volume reduction ratio of the second region being a ratio with respect to a volume of the second region determined assuming that the through-hole or the recess is not present.

The present invention provides: an electrode mixture manufacturing method comprising the processes of introducing a first binder, an electrode active material, and a conductive material into an extruder, performing a first mixing of the first binder, the electrode active material, and the conductive material in the extruder, additionally introducing a second binder into the extruder and performing a second mixing, and yielding an electrode mixture resulting from the first mixing and the second mixing; an electrode mixture manufactured thereby; and an electrode manufacturing method using the electrode mixture.

An embodiment provides a binder for a non-aqueous electrolyte rechargeable battery including a copolymer (A) and a copolymer (B), wherein the copolymer (A) includes a unit (a-1) derived from a (meth)acrylic acid-based monomer, and a unit (a-2) derived from a (meth)acrylonitrile monomer, and the copolymer (B) includes a unit (b-1) derived from an aromatic vinyl-based monomer; and a unit (b-2) derived from an ethylenic unsaturated monomer which is at least one of an unsaturated carboxylic acid alkylester monomer, a (meth)acrylic acid-based monomer, a unsaturated carboxylic acid amide monomer, or combinations thereof.

An anode for a secondary battery including an anode active material and a secondary battery including the anode and having improved stability and reduced resistance are disclosed. In an aspect, the anode active material includes a silicon-based active material having a specific surface area (BET) in a range from 0.5 m.sup.2/g to 5 m.sup.2/g, a first carbon-based active material having an average particle diameter (D50) in a range from 1 μm to 4 μm, and a second carbon-based active material having an average particle diameter greater than that of the first carbon-based active material.

Embodiments of the present disclosure generally relate to carbon materials for battery electrodes and methods for preparing such carbon materials. More specifically, embodiments relate to methods for coating a carbon film onto nano-ordered carbon particles to produce carbon-coated particles which can be used as an anode material within a battery, such as a lithium-ion battery, a sodium-ion battery, other types of batteries. In one or more embodiments, a method for producing carbon-coated particles is provided and includes positioning nano-ordered carbon particles within a processing region of a processing chamber, purging the processing region containing the nano-ordered carbon particles with an inert gas, heating the nano-ordered carbon particles to a temperature of about 700° C. or greater during an annealing process, and depositing a carbon film on the nano-ordered carbon particles to produce carbon-coated particles during a vapor deposition process.

Provided are methods for solid state pretreatment of active materials (e.g., prelithiation of silicon monoxide) while forming treated negative active material structures. Also provided are the formed structures, negative electrodes comprising these structures, and electrochemical cells comprising these electrodes. In some examples, silicon monoxide structures are mixed with lithium hydroxide structures or some other lithium-containing structures. The mixture is heated in an inert environment to form treated negative active material structures. These treated structures comprise various lithium-containing components, some of which trap lithium. When an electrochemical cell, formed with these treated negative active material structures, is initially charged and additional new lithium ions are introduced into the negative electrodes (e.g., from the positive electrode), a larger portion of these new lithium ions forms reversible components (rather than irreversible components) in the negative electrode than, for example, in a conventional cell without any such treatment.

Systems and methods utilizing aqueous-based polymer binders for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and an aqueous-based suspension-solution binder composition comprising a water soluble (aqueous-based) polymer as part of a multi-component binder composition that also contains an water insoluble polymer. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.

Composites comprising an exfoliated graphite support material having a degree of graphitization g in an range of 50 to 93%, obtained by XRD Rietveld analysis, which is coated with ZnO nanoparticles. These composites are produced by three different methods: A) (syn) the method comprises the following consecutive steps: i) a Zn(II)salt is dissolved in a solvent ii) graphite and a base are added simultaneously iii) the mixture is stirred under impact of ultrasound iv) the solvent is removed from the suspension or B) (pre) the method comprises the following consecutive steps: i) graphite is suspended in a solvent and exfoliated via impact of ultrasound ii) a Zn(II)salt and a base are added simultaneously forming nano-ZnO particles iii) the mixture is stirred iv) the solvent is removed from the suspension or C) (post) the method comprises the following steps: i) a Zn(II)salt and a base are mixed in a solvent in a first reactor forming nano-ZnO particles ii) graphite is exfoliated via impact of ultrasound in a second reactor iii) both suspensions of i) and ii) are mixed together iv) after step iii) the solvent is removed from the suspension. These coated composites may be tempered in a further step and again coated and again tempered.

A negative active material for a rechargeable lithium battery and a rechargeable lithium battery, the negative active material including a composite including silicon particles, metal particles, and a first amorphous carbon; and a second amorphous carbon surrounding on the composite.