A positive electrode, a lithium secondary battery comprising the same, and a method of manufacturing the same are provided. The positive electrode comprises a positive electrode current collector; a positive electrode active material layer including a free-standing film positive electrode material manufactured by a dry process, taking advantage of strong self-cohesive force of sulfur-carbon composite under pressure condition; and a binding layer bonding the positive electrode active material layer and the positive electrode current collector.

This application describes an electrode material comprising particles of an electrochemically active material dispersed in a polymer binder, where the polymer binder is an acidic polymer or a mixture comprising a binder soluble in an aqueous solvent or a non-aqueous solvent (e.g. NMP) and an acidic polymer. The application also further relates to processes for the preparation of the electrode material and electrodes containing the material, as well as to the electrochemical cells and their use.

This application describes an electrode material comprising particles of an electrochemically active material dispersed in a polymer binder, where the polymer binder is an acidic polymer or a mixture comprising a binder soluble in an aqueous solvent or a non-aqueous solvent (e.g. NMP) and an acidic polymer. The application also further relates to processes for the preparation of the electrode material and electrodes containing the material, as well as to the electrochemical cells and their use.

The present disclosure relates to a method of making an electrochemically active material, which comprises metal nanostructures encapsulated in LaF.sub.3 shells. The electrochemically active material may be included in an electrode of an F-shuttle battery that includes a liquid electrolyte, which, optionally, allows the F-shuttle batteries to operate at room temperature.

A positive electrode material for a lithium ion secondary battery includes an olivine-type phosphate-based compound represented by General Formula LixAyDzPO.sub.4 and carbon, and, in transmission electron microscopic observation of a cross section of a secondary particle that is an agglomerate of primary particles of the olivine-type phosphate-based compound, a 300-point average value of filling rates of the carbon that fills insides of voids having a diameter of 5 nm or larger that are formed by the primary particles is 30 to 70%. A is any one of Co, Mn, Ni, Fe, Cu, and Cr, D is any one of Mg, Ca, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, Sc, and Y, and x, y, and z satisfy 0.9<x<1.1, 0<y≤1.0, 0≤z<1.0, and 0.9<y+z<1.1.

The present invention relates to a double slit coating die, and an electrode active material coating apparatus comprising same, the double slit coating die comprising first to fourth blocks which are positioned sequentially adjacent to each other, and having a structure in which the positions of the first and second blocks can move in a direction tilted at an angle θ with respect to the interface between the second and third blocks. The present invention has the effects of preventing slip surfaces between blocks constituting the die from spreading apart, and reducing offset in a coating process.

Disclose are a cathode of an all-solid lithium battery, and a secondary battery system using the same. The cathode includes a lithium composite, and a method of manufacturing the lithium composite comprises: dispersing a solid electrolyte to be uniformly distributed in the pores of a mesoporous conductor to provide a solid electrolyte composite, and coating the solid electrolyte composite on the surface of a lithium compound including nonmetallic solids such as S, Se, and Te.

Disclose are a cathode of an all-solid lithium battery, and a secondary battery system using the same. The cathode includes a lithium composite, and a method of manufacturing the lithium composite comprises: dispersing a solid electrolyte to be uniformly distributed in the pores of a mesoporous conductor to provide a solid electrolyte composite, and coating the solid electrolyte composite on the surface of a lithium compound including nonmetallic solids such as S, Se, and Te.

High-performance flexible batteries are promising energy storage devices for portable and wearable electronics. The major obstacle to develop flexible batteries is the shortage of flexible electrodes with excellent electrochemical performance. Another challenge is the limited progress in the flexible batteries beyond Li-ion because of safety concerns for the Li-based electrochemical system. Accordingly, a self-supported tin sulfide (SnS) porous film (PF) was fabricated as a flexible cathode material in Al-ion battery, which delivers a high specific capacity of 406 mAh/g. A capacity decay rate of 0.03% per cycle was achieved, indicating a good stability. The self-supported and flexible SnS film also shows an outstanding electrochemical performance and stability during dynamic and static bending tests. Microscopic images demonstrated that the porous structure of SnS is beneficial for minimizing the volume expansion during charge/discharge. This leads to an improved structural stability and superior long-term cyclability.

A method of producing a powder mass for a lithium battery, the method comprising: (a) providing a solution containing a sulfonated elastomer dissolved in a solvent or a precursor in a liquid form or dissolved in a solvent; (b) dispersing a plurality of particles of a cathode active material in the solution to form a slurry; and (c) dispensing the slurry and removing the solvent and/or polymerizing/curing the precursor to form the powder mass, wherein the powder mass comprises multiple particulates and at least a particulate comprises one or a plurality of particles of a cathode active material being encapsulated by a thin layer of sulfonated elastomer having a thickness from 1 nm to 10 μm, a fully recoverable tensile strain from 2% to 800%, and a lithium ion conductivity from 10.sup.−7 S/cm to 5×10.sup.−2 S/cm at room temperature.