A method of producing a pre-selenized (selenium-preloaded) active cathode layer for a rechargeable alkali metal-selenium cell; the method comprising: (a) preparing an integral layer of mesoporous structure having pore sizes from 0.5 nm to 50 nm (preferably from 0.5 nm to 5 nm) and a specific surface area from 100 to 3,200 m.sup.2/g; (b) preparing an electrolyte comprising a solvent and a selenium source; (c) preparing an anode; and (d) bringing the integral layer and the anode in ionic contact with the electrolyte and imposing an electric current between the anode and the integral layer (serving as a cathode) to electrochemically deposit nanoscaled selenium particles or coating on the graphene surfaces. The selenium particles or coating have a thickness or diameter smaller than 20 nm (preferably <10 nm, more preferably <5 nm or even <3 nm) and preferably occupy a weight fraction of at least 70% (preferably >90% or even >95%).

A liquid composition for an electrode composite material is provided. The liquid composition comprises an active material, a dispersion medium, and a polymerizable compound. A viscosity of the liquid composition at 25 degrees C. is a viscosity at which the liquid composition is dischargeable from a liquid discharge head.

A Lithium-transition-metal-phosphate compound of formula Li.sub.0.9+xFe.sub.1-yM.sub.yPO.sub.4) in the form of secondary particles made of agglomerates of spherical primary particles wherein the primary particles have a size in the range of 0.02-2 pm and the secondary particles a mean size in the range of 10-40 pm and a BET surface of 16-40 m.sup.2/g, a process for its manufacture and the use thereof.

A Lithium-transition-metal-phosphate compound of formula Li.sub.0.9+xFe.sub.1-yM.sub.yPO.sub.4) in the form of secondary particles made of agglomerates of spherical primary particles wherein the primary particles have a size in the range of 0.02-2 pm and the secondary particles a mean size in the range of 10-40 pm and a BET surface of 16-40 m.sup.2/g, a process for its manufacture and the use thereof.

Provided is a method of manufacturing a lithium secondary battery, the method including: preparing positive and negative metal foams having a plurality of first pores; controlling first pore sizes of the metal foams depending on an application; filling the first pores with a slurry obtained by mixing a positive electrode active material or a negative electrode active material, a binder, a conductive material, and an organic solvent; heat-treating the metal foams to form second pores having a size smaller than those of the first pores. The first pore size of the metal foam can be controlled, so that a high capacity and high output battery can be manufactured depending on the usage.

Provided is a method of manufacturing a lithium secondary battery, the method including: preparing positive and negative metal foams having a plurality of first pores; controlling first pore sizes of the metal foams depending on an application; filling the first pores with a slurry obtained by mixing a positive electrode active material or a negative electrode active material, a binder, a conductive material, and an organic solvent; heat-treating the metal foams to form second pores having a size smaller than those of the first pores. The first pore size of the metal foam can be controlled, so that a high capacity and high output battery can be manufactured depending on the usage.

A process is provided comprising submerging a substrate in an electrochemical deposit bath having at least a metal salt and saccharin. In embodiments, the film is further treated with anodization, and in other cases chemical vapor deposition. Films are also provided formed by the disclosed processes. The films are nanoporous on at least a portion of a surface of the films. Also disclosed are electronic devices having the films disclosed, including lithium-ion batteries, storage devices, supercapacitors, electrodes, semiconductors, fuel cells, and/or combinations thereof.

In the case in which a lithium metal is used in order to increase the capacity of a lithium secondary battery, reversibility of charging and discharging is reduced due to dendrite, etc. A lithium metal having LiF deposited thereon exhibits high stability, whereby reversibility of charging and discharging is increased. In addition, in the case in which LiF is deposited, the lithium metal, which is a negative electrode material, is not consumed, and the shape of a lithium metal electrode is not greatly changed.

In the case in which a lithium metal is used in order to increase the capacity of a lithium secondary battery, reversibility of charging and discharging is reduced due to dendrite, etc. A lithium metal having LiF deposited thereon exhibits high stability, whereby reversibility of charging and discharging is increased. In addition, in the case in which LiF is deposited, the lithium metal, which is a negative electrode material, is not consumed, and the shape of a lithium metal electrode is not greatly changed.

A positive electrode for a lithium-sulfur battery and a lithium-sulfur battery including the same, and in particular, a positive electrode for a lithium-sulfur battery including an active material, a conductive material, a binder and an additive, wherein the additive includes an organic acid lithium salt, the organic acid lithium salt including a dicarboxyl group. By including a dicarboxyl group-including organic acid lithium salt as the additive, the positive electrode for the lithium-sulfur battery is capable of enhancing capacity and lifetime properties of the lithium-sulfur battery through enhancing lithium ion migration properties.