A negative electrode includes a negative electrode current collector, a first negative electrode active material layer disposed on the negative electrode current collector, and a second negative electrode active material layer disposed on the first negative electrode active material layer, wherein the second negative electrode active material layer includes a second negative electrode active material and a second conductive material, and the second negative electrode active material includes a silicon-based active material and a carbon-based active material, wherein the silicon-based active material includes SiO.sub.X (0≤X<2), and the second conductive material includes a carbon nanotube structure in which a plurality of single-walled carbon nanotube units are bonded side by side, and a particulate conductive material, wherein in the second negative electrode active material layer, the weight ratio of the carbon nanotube structure and the particulate conductive material is 12.7:87.3 to 0.5:99.5.

A positive-electrode active material containing a compound that has a crystal structure belonging to the space group FM-3M and is represented by the composition formula (1):
Li.sub.xMe.sub.yO.sub.αF.sub.β  (1) wherein Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, and Al, and the following conditions are satisfied. 1.3≤x≤2.2, 0.8≤y≤1.3, 1≤α≤2.93, 0.07≤β≤2.

A positive-electrode active material containing a compound that has a crystal structure belonging to the space group FM-3M and is represented by the composition formula (1):
Li.sub.xMe.sub.yO.sub.αF.sub.β  (1) wherein Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, and Al, and the following conditions are satisfied. 1.3≤x≤2.2, 0.8≤y≤1.3, 1≤α≤2.93, 0.07≤β≤2.

A lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner. An automated machine based system, apparatus and methods assessing and inspecting the quality of such vitreous solid electrolyte sheets, electrode sub-assemblies and lithium electrode assemblies can be based on spectrophotometry and can be performed inline with fabricating the sheet or web (e.g., inline with drawing of the vitreous Li ion conducting glass) and/or with the manufacturing of associated electrode sub-assemblies and lithium electrode assemblies and battery cells.

Provided are electrolytic solution absorbing particles that have an electrolytic solution retention property and can increase a lithium ion transport characteristic, as well as a self-supporting sheet that includes the same, a lithium-ion secondary battery electrode that includes the same, a separator that uses the same, and a lithium-ion secondary battery that uses the same. These particles are particles wherein a resin layer that can absorb an electrolytic solution is provided on a surface of a highly dielectric oxide solid. Specifically, these particles are electrolytic solution absorbing particles that have the resin layer that can absorb the electrolytic solution on the surface of the highly dielectric oxide solid.

A lithium secondary battery is disclosed herein. In some embodiments, a lithium secondary battery includes a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, where the negative electrode active material consists of a silicon-based material, a separator disposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte solution, wherein the non-aqueous electrolyte solution includes a lithium salt including LiPF.sub.6 and LiN(FSO.sub.2).sub.2, an additive including a sultone-based compound, and an organic solvent including a non-fluorine-based linear carbonate solvent and a fluorine-based cyclic carbonate solvent.

A lithium ion secondary battery includes a pair of exterior films having outer edges bonded together in a stacked state to form an internal space, a battery body housed in the internal surface, a positive electrode tab terminal connected to the battery body in between the pair of exterior films and extending to an outside, and a negative electrode tab terminal connected to the battery body in between the pair of exterior films and extending to the outside. The pair of exterior films each include a first resin layer constituting an inner surface, the inner surfaces opposing each other. The inner surface of at least one of the pair of exterior films has a plurality of projections arranged thereon apart from each other.

The present disclosure relates to an ionic liquid-based quasi-solid-state electrolyte in a lithium battery and a preparation method thereof. The quasi-solid-state electrolyte is of a porous network structure, which is obtained by a condensation reaction of a lithium salt, ionic liquid, a silane coupling agent and a catalyst, and has a high ionic conductivity. The quasi-solid-state electrolyte can stabilize a stripping/deposition process of lithium metal and inhibit growth of lithium dendrites, and shows a low overpotential and long-term cycle stability in a constant current polarization process. The interface impedance of a lithium metal sheet and the quasi-solid-state electrolyte is low, and is hardly increased with the age of the battery.

To provide an electrode for a non-aqueous electrolyte secondary battery which retains the shape while retaining a discharge capacity at a high rate. An electrode for a non-aqueous electrolyte secondary battery has a current collector and an electrode active material layer arranged on a surface of the current collector, and is used for a non-aqueous electrolyte secondary battery having a liquid volume coefficient of 1.4 to 2.0, in which the electrode active material layer includes an electrode active material and a binder including polyvinylidene fluoride (PVdF), and the polyvinylidene fluoride (PVdF) is in a non-crystallized state and is included in the range of 0.5 to 3.3% by volume with respect to the total volume of the electrode in the electrode active material layer.

To provide an electrode for a non-aqueous electrolyte secondary battery which retains the shape while retaining a discharge capacity at a high rate. An electrode for a non-aqueous electrolyte secondary battery has a current collector and an electrode active material layer arranged on a surface of the current collector, and is used for a non-aqueous electrolyte secondary battery having a liquid volume coefficient of 1.4 to 2.0, in which the electrode active material layer includes an electrode active material and a binder including polyvinylidene fluoride (PVdF), and the polyvinylidene fluoride (PVdF) is in a non-crystallized state and is included in the range of 0.5 to 3.3% by volume with respect to the total volume of the electrode in the electrode active material layer.