The present invention relates to ZIF nanoparticles introduced with three kinds of ligands, a method for preparing the same, a hybrid membrane including the same, and a gas separation method using the hybrid membrane. Nanoparticles of a zeolitic imidazolate framework (ZIF) into which three kinds of ligands are introduced, the nanoparticles comprising metal ions, and an organic ligand bound to the metal ion, wherein the organic ligand comprises an imidazole-based first organic ligand, alkylamine-based second organic ligand, and third organic ligand comprising at least one amine group substituted on the ring.

A composite film framework that includes a support; a metal oxide layer on the support; and a metal organic framework film on the metal oxide layer 2, wherein a metal atom is shared by a metal oxide in the metal oxide layer and a metal organic framework in the metal organic framework film at an interface between the metal oxide layer and the metal organic framework film.

Compositions are provided for efficient uranium extraction, for example from wastewater, seawater, or other water sources. The compositions can include a functionalized porous organic polymer functionalized with one or more uranium binding moieties, e.g. having a plurality of amidoxime or amidrazone groups covalently attached thereto. The compositions can include covalent organic frameworks, porous aromatic frameworks, and various porous organic polymers, especially those having a hierarchical pore size distribution over a range of pore sizes. The compositions can have functional groups such as amidoxime or an amidrazone covalently attached thereto. The hierarchical pore size distribution can be determined based upon at least 60% of the pore sizes in the range of pore sizes having a pore volume of at least 0.01 cm.sup.3 g.sup.−1 in the pore size distribution at 77 K. Methods of making the compositions and methods of using the compositions are also provided.

Water harvesting systems and methods of making and using such water harvesting systems, for capturing water from surrounding air using configurations that reduce overall energy costs and improves water harvesting cycle efficiency in the water harvesting system. In particular embodiments, the water harvesting system can be configured for dehumidification-humidification of air, and a method in the water harvesting system for dehumidification-humidification to control moisture level in the air conditioned by the water harvesting system. The systems and methods use sorbent materials, such as metal-organic frameworks, to adsorb water from the air. The systems and methods desorb this water in the form of water vapor, and the water vapor can be condensed into liquid water and collected to dehumidify air conditioned by the water harvesting system. The collected liquid water can be sprayed to humidify air conditioned by the water harvesting system.

The present invention relates to a method and apparatus for providing and/or receiving audible sound. In particular, the invention relates to apparatus, such as a micro speaker, which includes an active region which comprises an adsorbent element in the form of a self-supporting monolith-like element with a porous reticulated structure. The adsorbent element includes adsorbent material which comprises microporous organic polymer (MOP) material. The apparatus of the present invention is suitable for use in an electronic device, for example a mobile or portable electronic device, to provide improved audible sound.

A method to make metal-organic frameworks (MOFs) in which a first aqueous solution of a transition metal salt is mixed with a second aqueous solution of an imidazole or alkyl-substituted imidazole to yield a product solution containing MOF crystals. The MOF crystals are used to fabricate electrodes for electrochemical detection of nitro-aromatic compounds.

Provided are methods for storing a gas. An example method comprises providing a vessel containing a manifold system and an adsorbent, the manifold system comprising: a gas tubing, a filter disposed over openings in the gas tubing, a pressure relief valve, and an inlet coupled to the gas tubing and the vessel. The method further comprises introducing the gas into the manifold system via the inlet; circulating the gas in the gas tubing; flowing the gas through the openings in the gas tubing; and adsorbing the gas onto the adsorbent.

Provided herein are atmospheric water harvesting systems that are tailored with an optimal adsorption threshold, based on energy cost and water availability considerations. The systems include a plurality of adsorbent modules, each containing metal organic frameworks of various adsorption thresholds. Such a design enables real time adjustment to achieve optimal harvesting conditions in changing atmospheric conditions, whether for daily or seasonal humidity variations.

Provided herein are water harvesting systems, as well as methods of making and using such systems, for capturing water from surrounding air using a design that reduces overall energy costs of the systems and improve water harvesting cycle efficiency. The systems and methods use sorbent materials, such as metal-organic frameworks, to adsorb water from the air. The systems and methods desorb this water in the form of water vapor, and the water vapor is condensed into liquid water and collected. The liquid water is suitable for use as drinking water.

A storage system for reversibly storing and releasing a gas such as hydrogen includes storage elements each having a storage volume with a storage material such as a metal-organic framework (MOF) for reversibly adsorbing or physiosorbing the gas, a gastight housing surrounding the storage volume and having a gas inlet/outlet which is in fluid-conducting communication with the storage volume, and at least one non-fluid activating element or activating layer configured to, when in an activation state, release the gas stored in the MOF and/or increases the rate of release relative to an unactivated state. The activating element or layer may surround and/or penetrate the storage material. The activating element may be controlled by an associated control to enter the activation state.