Patent classifications
B01D53/8612
WET DESULFURIZATION PROCESS USING A SUSPENSION BED
Provided is a wet desulfurization process using a suspension bed. The process comprises mixing desulfurization slurry with a hydrogen sulfide containing gas to obtain a first mixture, and passing the first mixture into a suspension bed reactor from bottom to top, with controlling the first mixture to have a dwell time of 5-60 minutes in the reactor to allow they contact and react sufficiently with each other; and subjecting a second mixture obtained from the reaction to gas liquid separation to produce a purified gas. The process of the present invention may reduce the hydrogen sulfide content in the hydrogen sulfide containing gas from 2.4-140 g/Nm.sup.3 to 50 ppm or less, so that the desulfurization efficiency is 98% or more. The process of the present invention is simple and reasonable, with high desulfurization and regeneration efficiency, simple equipment, little occupation of land and low investment, which is very suitable for industrial promotion.
Process for purification and conversion of carbon dioxide using renewable energy
The present invention is generally directed to processes and systems for the purification and conversion of CO.sub.2 into low-carbon or zero-carbon high quality fuels and chemicals using renewable energy. In one aspect, the present invention provides a process for producing a stream comprising at least 90 mol % CO.sub.2. In certain cases, the CO.sub.2 stream is processed to make low carbon fuels and chemicals. In this process at least a portion of the CO.sub.2 is reacted with a stream comprising H.sub.2 in a Reverse Water Gas Shift (RWGS) reactor to produce a product stream that comprises CO.
Heterogeneous desulfurization catalyst
A two or particularly three-phase process, and corresponding apparatus, desulfurizes sour hydrocarbon gas, e.g., natural gas, generally better than known, using a fixed-bed, two-phase processes in terms of the amount of H.sub.2S scavenged and the breakthrough time of H.sub.2S. The three-phase process is effective in scavenging H.sub.2S at ambient temperature and pressure, using a copper salt catalyst impregnated on alumina or other generally inert support, which is regenerable.
GAS TREATMENT METHOD
It is an object of the present invention to downsize facility for removing or reducing concentration of hydrogen sulfide and oxygen in gas and reduce facility cost. Syngas g contains hydrogen sulfide and oxygen as target constituents of removal or reduction in concentration. Hydrogen sulfide content and oxygen content in the syngas g are measured in a preceding measurement part 13. Then, the syngas g is contacted with desulfurizing agent 14a including iron oxide. Selection is made whether to further execute deoxidization in a deoxidizing part 16 or omit or simplify the deoxidization according to results of measurements in the preceding measurement part 13.
Air cleaner for fuel cell system
An air cleaner for a fuel cell system includes a housing, a first filter, and a second filter. The first filter is arranged inside the housing and collects dust contained in air. The second filter is arranged side by side with the first filter in an air flowing direction inside the housing and adsorbs impure gas contained in air. The first filter includes a filtering member, which has nonwoven fabric and filter paper adhered to the nonwoven fabric. The filter paper is located on a downstream side in the air flowing direction of the nonwoven fabric and has a higher packing density than the nonwoven fabric. The second filter includes a base member having a honeycomb structure with through-holes and adsorbent, which is provided on inner surfaces of the through-holes and adsorbs the impure gas.
Systems, devices, compositions, and/or methods for de-sulphurizing acid gases
Certain exemplary embodiments can provide a system, machine, device, manufacture, circuit, composition of matter, and/or user interface adapted for and/or resulting from, and/or a method and/or machine-readable medium comprising machine-implementable instructions for, activities that can comprise and/or relate to, reacting reactants comprising a ferric/ferrous chelate and a sour gas stream.
A DEVICE, PROCESS, AND CATALYST INTENDED FOR DESULFURIZATION AND DEMERCAPTANIZATION OF GASEOUS HYDROCARBONSD
This application is in the field of technologies for desulfurization and demercaptanization of gaseous hydrocarbons. The device includes a catalytic reactor loaded with a catalyst solution in an organic solvent, a means of withdrawal sulfur solution from the reactor into the sulfur-separating unit, and a sulfur-separating unit. The said device has at least means of supplying gaseous hydrocarbon medium to be purified and oxygen-containing gas into the reactor, and a means of outletting the purified gas from the reactor. The sulfur-separation unit includes a means of sulfur extraction. The reactor design and the catalyst composition provide conversion of at least 99.99% of hydrogen sulfide and mercaptans into sulfur and disulfides. The catalyst is composed of mixed-ligand complexes of transition metals. The technical result achieved by use of claimed invention is single-stage purification of gaseous hydrocarbons from hydrogen sulfide and mercaptans with remaining concentration of SH down up to 0.001 ppm.
A DEVICE, PROCESS, AND CATALYST INTENDED FOR DESULFURIZATION/DEMERCAPTANIZATION/DEHYDRATION OF GASEOUS HYDROCARBONSD
This application is in the field of technologies for desulfurization and demercaptanization of raw gaseous hydrocarbons (including natural gas, tail gas, technological gas, etc, including gaseous media). It can be used for simultaneous dehydration and desulfurization/demercaptanization of any kind of raw gaseous hydrocarbons.
Process for removing hydrogen sulfide from sour gases with ZIF-67 supported on mixed metal oxides
A method for removing hydrogen sulfide (H.sub.2S) from a H.sub.2S-containing gas composition, including charging an aqueous media to a reactor under continuous agitation, dispersing particles of a composite in the aqueous media to form a composite mixture, continuously agitating the composite mixture, introducing the H.sub.2S-containing gas composition to the reactor containing the composite mixture under continuous agitation and passing the H.sub.2S-containing gas composition through the composite mixture, and adsorbing and removing H.sub.2S from the gas composition by the composite mixture to form a purified gas composition. The composite contains a CuMnAl mixed metal oxide (MMO) and zeolitic imidazolate framework-67 (ZIF-67) nanoparticles. The ZIF-67 nanoparticles are dispersed between layers of the CuMnAl MMO.
TITANIUM-DIOXIDE-BASED DOUBLE-LAYER HOLLOW MATERIAL, PREPARATION METHOD THEREOF, AND APPLICATION THEREOF IN PHOTOCATALYTIC TREATMENT OF HYDROGEN SULFIDE
A preparation method of a titanium-dioxide-based double-layer hollow material includes the following steps: (1) using polystyrene nanospheres with particle size of 180 nm as a template, tetrabutyl titanate as a precursor, to prepare hollow titanium dioxide by calcining; (2) subjecting said hollow titanium dioxide to carboxylation modification to prepare carboxylated titanium dioxide; and (3) dispersing said carboxylated titanium dioxide in ethanol, using chromic nitrate nonahydrate as an assembly agent and trimesic acid as a crosslinking agent to carry out layer-by-layer self-assembly so as to prepare the titanium-dioxide-based double-layer hollow material.