Methods for embedding photocatalytic titanium dioxide in concrete surfaces to reduce pollutants via photocatalytic reactions are provided herein. One method includes mixing a solvent compound with an anatase titanium dioxide (TiO.sub.2) photocatalyst, applying an amount of concrete treatment compound to an upper surface of the concrete, the concrete treatment compound comprising a mixture of a liquid carrier compound with the anatase titanium dioxide (TiO.sub.2) photocatalyst.

The present disclosure is directed to processing for preparing crystalline pure-silica and heteroatom-substituted LTA frameworks in fluoride media using a simple organic structure-directing agent (OSDA), having a structure of Formula (I): ##STR00001##
where substituents R.sup.1 to R.sup.9 are defined herein. Aluminosilicate LTA is an active catalyst for the methanol to olefins reaction with higher product selectivities to butenes as well as C5 and C6 products than the commercialized catalysts. Titanosilicate LTA is an active catalyst for the epoxidation of allyl alcohol using aqueous H.sub.2O.sub.2.

Provide is a catalytic converter including a substrate which includes regions having different cell densities, in which exhaust gas purification performance is superior in all the regions of the substrate. A catalytic converter 10 includes catalyst layers in which a noble metal catalyst is supported on a support in surfaces of cell walls 2 of a substrate 1 having a cell structure in a longitudinal direction of the substrate 1 in which gas flows, in which the substrate 1 has a first region 1A having a relatively high cell density and a second region 1B having a relatively low cell density, and a ratio of a thickness of a catalyst layer 3A in the second region 1B to a thickness of a catalyst layer 3 in the first region 1A is in a range of more than 0.95 times and 1.2 times or less.

The manufacturing method includes a step of mixing a coarse particle zeolite, a fine particle zeolite, and a raw material of an inorganic bonding material to prepare a zeolite raw material; a step of forming the prepared zeolite raw material into a honeycomb shape to prepare a honeycomb formed body; and a step of firing the prepared honeycomb formed body to prepare the honeycomb structure. In the step of preparing the zeolite raw material, as the coarse particle zeolite, a chabazite type zeolite having a specific average particle diameter, the fine particle zeolite having a specific average particle diameter, the raw material of the inorganic bonding material which includes at least basic aluminum lactate is used.

A core-shell oxide material comprises: a core which comprises a ceria-zirconia based solid solution powder having at least one ordered phase of a pyrochlore phase and a κ phase; and a shell which comprises an alumina based oxide disposed on at least a portion of a surface of the core.

Provide is a new carrier for exhaust gas purification catalyst which exhibits excellent catalytic activity, particularly catalytic activity at a low temperature. Proposed is a carrier for exhaust gas purification catalyst composed of particles which contain a silicate or phosphate containing one kind or two or more kinds among the elements belonging to Group 1 and Group 2 in the periodic table.

A honeycomb structure is formed of a porous ceramic material and has pores in the structural body, wherein cerium dioxide is present in a state that it is incorporated in the structural body in the ceramic material, and at least a part of cerium dioxide particles is exposed on pore surfaces of the pores. The ceramic material includes cordierite or silicon carbide as a major component, the ratio of the cerium dioxide to the ceramic material is in the range of from 1.0% by mass to 10.0% by mass, and at least a part of catalyst particulates of a platinum group element such as platinum or palladium is loaded by the cerium dioxide particles.

The honeycomb structure includes a honeycomb structure body having porous partition walls, and a plugging portion disposed in one of open ends of each cell, a thickness of the partition walls is 0.30 mm or more and 0.51 mm or less, a cell density is 30 cells/cm.sup.2 or more and 93 cells/cm.sup.2 or less, a filtration area (cm.sup.2) of inflow cells included per cm.sup.3 of the honeycomb structure body is defined as an inflow side filtration area G (cm.sup.2/cm.sup.3), a value obtained by dividing a pore volume Vp (cm.sup.3) formed in the partition walls by a total volume Va (L) including the cells is defined as a pore volume ratio A (cm.sup.3/L), and in this case, a product of the inflow side filtration area G (cm.sup.2/cm.sup.3) and the pore volume ratio A (cm.sup.3/L) is 1800 cm.sup.2/L or more and 3200 cm.sup.2/L or less.

A process of forming a direct NOx catalyst includes the steps of providing a palladium salt, providing a silicon oxide support material, mixing the palladium salt and silicon oxide support material in an aqueous solution, evaporating the aqueous solution forming a solid, calcining the solid, and then exposing the calcined solid to a pretreatment gas at a specified temperature to form a desired direct NOx catalyst. When the process includes exposing the calcined solid to helium gas at a temperature of from 650 to 1000° C. the catalyst may include a mixture of palladium and palladium oxide having a particle size of from 5 to 150 nm where the palladium particles are discrete particles without sintering and the mixture may include 41% by weight palladium oxide and 51% by weight palladium metal.

Uses are disclosed for a new crystalline molecular sieve designated SSZ-102 synthesized using an N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent. SSZ-102 has ESV framework topology.