The present invention is directed to selective catalytic reduction catalysts that combine SCR activity with NOx absorber activity. In particular, the disclosed catalytic article includes a substrate having a first and a second material disposed thereon, wherein the first material includes a selective catalytic reduction (SCR) catalyst composition and the second material includes a nitrogen oxides (NOx) absorber composition, wherein the NOx absorber composition does not substantially oxidize ammonia, and wherein the catalytic article is effective to abate NOx from an engine exhaust gas stream. Emission treatment systems for treating an exhaust gas including a catalytic article of the invention are provided, particularly systems that include an injector adapted for the addition of ammonia to the exhaust gas stream located upstream of the catalytic article.

Disclosed herein are emission treatment systems, articles, and methods for selectively reducing NOx compounds. The systems include a hydrogen generator, a hydrogen selective catalytic reduction (H.sub.2-SCR) article, and one or more of a diesel oxidation catalyst (DOC) and/or a lean NOx trap (LNT) and/or a low temperature NOx adsorber (LTNA). Certain articles may comprise a zone coated substrate and/or a layered coated substrate and/or an intermingled coated substrate of one or more of the H.sub.2-SCR and/or DOC and/or LNT and/or LTNA catalytic compositions.

Systems, apparatuses, assemblies, and methods for diesel exhaust fluid (DEF) dosing can include a body defining an injector adaptor inlet and an injector adaptor outlet; and an injector mount or interface extending from the body. The injector mount can be between the first and second ends of the injector adaptor. The injector adaptor outlet can define an area greater than an area of the injector adaptor inlet. In a side view of the injector adaptor, at a bottom side of the body, a first straight line can extend along the body from the injector adaptor inlet to the injector adaptor outlet, and at a top side of the body opposite the bottom side, a second straight line can extend along the body from the injector adaptor inlet to the injector adaptor outlet. The second straight line can be at an acute angle relative to the first straight line.

A heater for use in heating a fluid flow through a passageway is provided that includes a continuous resistive heating element having a predefined shape that is directly exposed to the fluid flow. The predefined shape includes a cross-sectional geometry that provides a required heat distribution, structural strength, and reduced back pressure within the passageway. The predefined shape may include airfoils, while the cross-sectional geometry provides a required heat distribution, structural strength, and reduced back pressure within the passageway.

The present disclosure relates to copper-containing molecular sieve catalysts that are highly suitable for the treatment of exhaust containing NOx pollutants. The copper-containing molecular sieve catalysts contain ion-exchanged copper as Cu.sup.+2 and Cu(OH).sup.+1, and DRIFT spectroscopy of the catalyst exhibits perturbed T-O-T vibrational peaks corresponding to the Cu.sup.+2 and Cu(OH).sup.+1. In spectra taken of the catalytic materials, a ratio of the Cu.sup.+2 to the Cu(OH).sup.+1 peak integration areas preferably can be ≥1. The copper-containing molecular sieve catalysts are aging stable such that the peak integration area percentage of the Cu.sup.+2 peak (area Cu.sup.+2/(area Cu.sup.+2+area Cu(OH).sup.+1)) increases by ≤20% upon aging at 800° C. for 16 hours in the presence of 10% H.sub.2O/air, compared to the fresh state.

The present disclosure provides a method of preparing a SCR (Selective Catalytic Reduction) catalyst including preparing a synthetic mother liquid that includes a source of silica and alumina including zeolite A and silica, a structure-inducing material, a complexing material, and a solvent, reacting the synthetic mother liquid to prepare CHA zeolite, and ion-exchanging the prepared CHA zeolite with a transition metal.

Provided are a high-performance Cu—P co-supported zeolite and the like having excellent thermal endurance and catalyst performance. A Cu—P co-supported zeolite comprising at least a small pore size zeolite, and an extra-backbone copper atom and an extra-backbone phosphorus atom supported on the small pore size zeolite, wherein a silica-alumina ratio (SiO.sub.2/Al.sub.2O.sub.3) is 7 or more and 20 or less, a ratio of the copper atom to a T atom (Cu/T) is 0.005 or more and 0.060 or less, a ratio of the phosphorus atom to the T atom (P/T) is 0.005 or more and 0.060 or less, and a ratio of the phosphorus atom to the copper atom (P/Cu) is 0.1 or more and 3 or less.

A metal oxide catalyst synthesized using supercritical carbon dioxide extraction is provided, wherein the metal oxide catalyst includes an active site containing at least one type of metal oxide and a support for loading the active site and the metal oxide is an oxide of a metal selected from the group consisting of transition metals (atomic number 21 to 29, 39 to 47, 72 to 79, or 104 to 108), lanthanide (atomic number 57 to 71), post-transition metals (atomic number 13, 30 to 31, 48 to 50, 80 to 84, and 112), and metalloids (atomic number 14, 32 to 33, 51 to 52, and 85) in the periodic table, and a combination thereof.

An engine exhaust aftertreatment system having an organization and arrangement of certain selected components which achieve significant catalytic reduction of the known NOx pollutants (NO and NO.sub.2) in tailpipe-out exhaust, while also achieving significant catalytic reduction of sulfate pollutants in tailpipe-out exhaust.

The present invention relates to a method for diagnosing aftertreatment of exhaust gases resulting from combustion, wherein at least a first substance resulting from said combustion is reduced by supplying additive to an exhaust gas stream resulting from said combustion and use of a first reduction catalytic converter. The method includes: estimating an accumulated expected reduction of said first substance during a first period of time, determining an accumulated actual reduction of said first substance during a period of time at least substantially overlapping said first period of time, and generating a signal indicating a fault in said reduction of said first substance when said accumulated actual reduction differs from said accumulated expected reduction by a predetermined difference in occurrence of said first substance. The invention also relates to a corresponding system.