A reactor system for decomposing at least one of a per- or polyfluoroalkyl substance (PFAS) is provided. The system includes a material having an interior surface that defines a compartment; a subaqueous liquid in the compartment; and an electron donor in the subaqueous liquid, the electron donor configured to release a hydrated electron upon ultraviolet (UV) irradiation. The reactor system is configured so that when the electron donor releases a hydrated electron into the subaqueous liquid, the hydrated electron has a longer lifespan relative to an electron released in normal bulk phase water, and when a PFAS is present within the subaqueous liquid, the hydrated electron is capable of reductively defluorinating the PFAS and to generate fluoride ions (F). A method of operating the system to decompose PFAS is also provided.

A reactor system for decomposing at least one of a per- or polyfluoroalkyl substance (PFAS) is provided. The system includes a material having an interior surface that defines a compartment; a subaqueous liquid in the compartment; and an electron donor in the subaqueous liquid, the electron donor configured to release a hydrated electron upon ultraviolet (UV) irradiation. The reactor system is configured so that when the electron donor releases a hydrated electron into the subaqueous liquid, the hydrated electron has a longer lifespan relative to an electron released in normal bulk phase water, and when a PFAS is present within the subaqueous liquid, the hydrated electron is capable of reductively defluorinating the PFAS and to generate fluoride ions (F). A method of operating the system to decompose PFAS is also provided.

An adsorbent and photocatalytic decontamination gel consisting of a colloidal solution comprising, preferably consisting of: 8% to 30% by weight, preferably 10% to 30% by weight, more preferably 15% to 20% by weight, better still 15% to 20% by weight, the value 15% being excluded, even better still 16% to 20% by weight, for example 20% by weight of TiO.sub.2, optionally doped, relative to the weight of the gel; optionally 0.01% to 10% by weight, preferably 0.1% to 5% by weight, relative to the weight of the gel, of at least one dye and/or of at least one pigment; optionally 0.1% to 2% by weight, relative to the weight of the gel, of at least one surfactant; optionally 0.05% to 5% by weight, preferably 0.05% to 2% by weight, relative to the weight of the gel, of at least one superabsorbent polymer; and the balance of solvent.

The object of the invention is a functional protective material, especially with the function of protecting against chemical and/or biological poisons and/or noxious materials, such as combat agents, wherein the functional protective material comprises a multilayer construction. The multilayer construction has a two-dimensional backing material, especially a textile backing material and a membrane, which is assigned to the backing material and, in particular, is connected therewith. The membrane is provided with a reactive finish, especially with a component having catalytic activity preferably with respect to chemical and/or biological poisons and/or noxious matter. The adsorption filter material is suitable particularly for use in ABC protection objects (such as ABC protective clothing).

The object of the invention is a functional protective material, especially with the function of protecting against chemical and/or biological poisons and/or noxious materials, such as combat agents, wherein the functional protective material comprises a multilayer construction. The multilayer construction has a two-dimensional backing material, especially a textile backing material and a membrane, which is assigned to the backing material and, in particular, is connected therewith. The membrane is provided with a reactive finish, especially with a component having catalytic activity preferably with respect to chemical and/or biological poisons and/or noxious matter. The adsorption filter material is suitable particularly for use in ABC protection objects (such as ABC protective clothing).

A method and system for curing and safely disposing of resin-tainted articles is based on a specially configured curing chamber having unique structural and functional means allowing the insertion of the articles, curing of the articles and gravity dropping the articles from the chamber. The resin-tainted or resin-carrying waste articles, such as paper towels, gloves and resin tanks, may be produced as a result of 3D printing and related processes and are safely processed with a minimum amount of user handling in a very compressed time frame. LED sources operating at 405 nm, and other wavelengths, are positioned in the lower surface of a hinged top lid of the chamber and a slidably retractable floor tray retains the articles during curing. On completion of the curing cycle, the articles are gravity dropped by sliding the floor tray to its open position thereby depositing the cured articles into an external trash can for safe disposal.

A method and system for curing and safely disposing of resin-tainted articles is based on a specially configured curing chamber having unique structural and functional means allowing the insertion of the articles, curing of the articles and gravity dropping the articles from the chamber. The resin-tainted or resin-carrying waste articles, such as paper towels, gloves and resin tanks, may be produced as a result of 3D printing and related processes and are safely processed with a minimum amount of user handling in a very compressed time frame. LED sources operating at 405 nm, and other wavelengths, are positioned in the lower surface of a hinged top lid of the chamber and a slidably retractable floor tray retains the articles during curing. On completion of the curing cycle, the articles are gravity dropped by sliding the floor tray to its open position thereby depositing the cured articles into an external trash can for safe disposal.

A composition having a gadolinium-, samarium-, or lanthanum-substituted porous cerium oxide and copper or gold nanoparticles. The composition can be exposed to electromagnetic radiation to form reactive oxygen species in the composition to decompose organophosphonate compounds. The composition may be made by forming a mixture of a cerium salt; a gadolinium, samarium, or lanthanum salt; and an epoxide; forming gel from the mixture; and drying the gel to form an aerogel, a xerogel, or an ambigel. Copper or gold nanoparticles are added or formed at any point in the method.

A system and method for neutralizing chemical or biological agents present within a cavity of a piece of ordnance includes structures configured and operating for engaging the piece of ordnance between two retaining and drilling devices; boring two holes through sidewalls of the piece of ordnance to access the cavity; supply an emulsion through the one of holes to the cavity, and extract the emulsion through the second of the holes from the cavity; circulate the emulsion into a reservoir for mixing, wherein the emulsion contains chemicals to neutralize the chemical or biological agents; and continue circulating the emulsion until the chemical or biological agents have been neutralized.

A system and method for neutralizing chemical or biological agents present within a cavity of a piece of ordnance includes structures configured and operating for engaging the piece of ordnance between two retaining and drilling devices; boring two holes through sidewalls of the piece of ordnance to access the cavity; supply an emulsion through the one of holes to the cavity, and extract the emulsion through the second of the holes from the cavity; circulate the emulsion into a reservoir for mixing, wherein the emulsion contains chemicals to neutralize the chemical or biological agents; and continue circulating the emulsion until the chemical or biological agents have been neutralized.