An object of the present invention is to provide an exhaust gas purification catalyst having improved exhaust gas purifying performance (in particular, improved NOx purifying performance) at low to medium temperature, and, in order to achieve the object, the present invention provides an exhaust gas purification catalyst (10A) including: a substrate (20); and a catalyst layer (30 or 40) formed on the substrate (20), wherein the catalyst layer (30 or 40) contains rhodium element, phosphorus element and a rare earth element other than cerium element, wherein a ratio of a mass of the phosphorus element contained in the catalyst layer (30 or 40) to the mass of the rhodium element contained in the catalyst layer (30 or 40) is from 1 to 10, and wherein a ratio of a mass of the rare earth element other than cerium element in terms of an oxide thereof contained in the catalyst layer (30 or 40) to the mass of the rhodium element contained in the catalyst layer (30 or 40) is from 1 to 5.

This invention provides a catalyst composition characterized in that the catalyst composition comprises one or more rare earth oxophosphorus components.

Disclosed is an exhaust gas purification catalyst carrier which includes a phosphate salt represented by formula: MPO.sub.4 (wherein M represents Y, La, or Al) or a zirconium phosphate represented by formula ZrP.sub.2O.sub.7; an exhaust gas purification catalyst containing a noble metal at least containing Rh and supported on the carrier; and an exhaust gas purification catalyst product having a catalyst support made of a ceramic or metallic material, and a layer of the exhaust gas purification catalyst, the layer being supported on the catalyst support.

Phosphorus tolerant or resistant three-way catalysts (TWC) are disclosed. The TWC may include a substrate defining a plurality of channels. It may include front and rear washcoat portions overlying the substrate and having respective first and second washcoat loadings, the first washcoat loading being at most 2.0 g/in.sup.3 and less than the second washcoat loading. The front washcoat portion may include a catalyst material supported on a support material comprising a cerium oxide, such as ceria or CZO, or a pre-phosphated material, such as AlPO.sub.4, or CePO.sub.4. In one embodiment, the support material may comprise at least 85 wt. % of a cerium oxide or at least 85 wt. % of a phosphate-containing material. The front portion and the underlying substrate may comprise from 3 to 25 vol. % of the three-way catalyst or the front portion may overly up to an initial 15% of an axial length of the substrate.

The present invention relates to a composition for use in a catalyst system in emission control systems comprising a transition alumina based material and rare earth phosphates and to a method for making same.

Embodiments relate to a cerium-containing nano-coating composition, the composition including an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate. The diameter of each crystalline region is less than about 50 nanometers.

A three-phase heterogeneous photocatalyst composition is provided for catalysing dry reforming reactions. The photocatalyst composition is comprised of a photochemically active component, a photothermal component, and a plasmonic material that function synergistically to catalyze dry reforming reactions.

Phosphorus tolerant or resistant three-way catalysts (TWC) are disclosed. The TWC may include a substrate defining a plurality of channels. It may include front and rear washcoat portions overlying the substrate and having respective first and second washcoat loadings, the first washcoat loading being at most 2.0 g/in.sup.3 and less than the second washcoat loading. The front washcoat portion may include a catalyst material supported on a support material comprising a cerium oxide, such as ceria or CZO, or a pre-phosphated material, such as AlPO.sub.4, or CePO.sub.4. In one embodiment, the support material may comprise at least 85 wt. % of a cerium oxide or at least 85 wt. % of a phosphate-containing material. The front portion and the underlying substrate may comprise from 3 to 25 vol. % of the three-way catalyst or the front portion may overly up to an initial 15% of an axial length of the substrate.

The invention relates to a catalyst carrier for exhaust gas purification catalyst which contains a metal phosphate containing Zr, and it provides a new catalyst carrier which exhibits excellent NOx purification performance in a high temperature region. The invention proposes a carrier for exhaust gas purification catalyst containing a metal phosphate which has a NASICON type structure and contains Zr.

Embodiments relate to a cerium-containing nano-coating composition, the composition including an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate. The diameter of each crystalline region is less than about 50 nanometers.