A crosslinking agent composition for water-compatible resins which comprises a hydrophobic crosslinking agent, a water-soluble organic compound, one or more oily media selected from among hydrocarbon-based solvents and ketone-based solvents having a solubility parameter of 9.0 (cal/cm.sup.−3).sup.1/2 or less, and an aqueous medium. The crosslinking agent composition can improve the storage stability of a water-compatible resin composition. The water-compatible resin composition which contains this crosslinking agent composition can give cured objects satisfactory in terms of water resistance and solvent resistance and is suitable also for use in wet-on-wet coating.

The present invention relates to a copolymer (A) having a glass transition temperature T.sub.g of at least −30° C. obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent and in the presence of at least one initiator, where the mixture of monomers (a) to be polymerized comprises (a1) 10 to 60 mol % of at least one monomer of the formula (I) below

##STR00001## where R.sub.1=C.sub.1 to C.sub.4 alkoxy, R.sub.2=C.sub.1 to C.sub.4 alkyl, and m=0 to 2, and (a2) 40 to 90 mol % of at least one olefinically unsaturated monomer selected from the group consisting of monomers of the formulae H.sub.2C═CH.sub.2—(C═O)—O—R.sub.x, H.sub.2C═CH(CH.sub.3)—(C═O)—O—R.sub.x, and H.sub.2C═CH.sub.2—O—(C═O)—R.sub.x, where R.sub.x is an alkyl radical having 1 to 20 carbon atoms,
and where the sum total of the molar fractions of the monomers (a1) and (a2), based on the total molar amount of monomers (a) used, is at least 90 mol %, and where the copolymerization is carried out at a temperature from 60 to 200° C. and at a pressure of at least 2 bar.

[Problem] To obtain a thermosetting resin composition that has curing performance at a lower temperature and uses transesterification capable of also suitably coping with conversion into an aqueous form as a curing reaction.

[Solution] A thermosetting resin composition containing a resin component (A), which includes a structure (a) represented by the following general formula (1) and a hydroxy group (b), and a transesterification catalyst (B).

##STR00001##

n=0 to 20

R.sub.1 is an alkyl group having 50 or less carbon atoms.

R.sub.3 is hydrogen or an alkyl group having 10 or less carbon atoms.

Described herein is an aqueous basecoat composition including a silane-based additive as hardener/self-crosslinking material to improve adhesion of the basecoat to the under—and overlying coating layers, as well as the cohesion property of the basecoat itself. Also described herein is a mixer system for preparing an aqueous refinish basecoat composition including at least one base color component, at least one pigment-free component, at least one hardening component including the silane-based additive and optionally at least one rheology module as well as a method to prepare an aqueous basecoat composition from said mixer system. Further, described herein is a method of coating a substrate with the basecoat composition and a clearcoat composition and jointly curing the basecoat and clearcoat composition as well as to a coated substrate obtained from the method. Finally, described herein is a method of using the silane-based compound as hardening additive in aqueous basecoat compositions.

The present invention addresses the problem of providing an aqueous paint composition that has a relatively high solid content ratio and that is capable of forming a coating film having excellent brilliance. The present invention provides an aqueous paint composition that contains (A) a water-dispersible hydroxy-containing acrylic resin, (B) a flake-effect pigment, and (C) a water-dispersible cellulose-based rheology control agent, wherein the content of the flake-effect pigment (B) is within a range of 1 to 50 parts by mass based on 100 parts by mass of the resin solids content in the aqueous paint composition, and the aqueous paint composition has a solids content of more than 10 mass % and 35 mass % or less.

Provided is an aqueous coating composition which has excellent storage stability and whereby high coating film performance in terms of hardness, water resistance, etc., can be exhibited even when the aqueous coating composition is cured at a relatively low temperature. Disclosed is an aqueous coating composition which contains (A) a resin containing hydroxyl groups and carboxyl groups, (B) a blocked polyisocyanate compound, (C) a phosphate-group-containing compound, and (D) a basic compound, and which has a pH in the range of 7.0-8.2, wherein the basic compound (D) contains a specific quantity of (D1) a basic compound which has an acid dissociation constant (PKa) in the range of 7.0-8.5 and a boiling point in the range of 100-200° C.

Provided is a water-based coating composition capable of exhibiting high coating film performance even when cured at relatively low temperatures. Disclosed is a water-based coating composition including (A) a hydroxyl group-containing resin and (B) a hardener, wherein at least one type of (A) the hydroxyl group-containing resin is a hydroxyl group-containing acrylic resin particle (A1) having a core-shell structure containing a gradient polymer layer.

A storage stable one component aqueous basecoat composition containing a melamine formaldehyde crosslinker and a resin having groups reactive to the melamine formaldehyde crosslinker under acid catalysis is provided. The basecoat composition is curable at a temperature of 110° C. or less when cured wet on wet with a solvent borne clear coat composition containing a polyisocyanate crosslinker. Also provided is a wet on wet two layer coating containing the one component aqueous basecoat and the solvent borne clear coat, a wet on wet three layer coating containing an aqueous primer, the one component aqueous basecoat and the solvent borne clear coat and a cured topcoat coating obtained by curing the wet on wet two layer coating.

A method and a device for manufacturing a base layer (3) having different degrees of hardness is disclosed. Further a workpiece with a base layer (3) manufactured by such method is disclosed.

An aqueous white conductive primer coating composition, includes: a binder component (A); and a carbon nanotube dispersion liquid (B); and a coating film formed by the aqueous white conductive primer coating composition has an L* value of whiteness based on a CIE color-matching function of 80 or more and a surface resistivity of 10.sup.8 Ω/□ or less.