A process of producing a surface-modified 3-dimensional article, the process comprising the steps of providing a radiation-curable composition, building-up a 3-dimensional article by radiation-curing the radiation-curable composition layer by layer, preferably by using a stereolithography or digital light processing unit, partially removing radiation-curable composition which sticks to the surface of the 3- dimensional article, treating only a portion of the surface of the 3- dimensional article to which the radiation-curable composition is stuck with particles, applying an additional curing step to the 3-dimensional article, preferably by applying heat and/or radiation. A 3-dimensional article which can be obtained by such a process and a kit of parts comprising such a 3-dimensional article.

A process for making a reinforcing structure (20) for dental prostheses in continuous fiber composite materials is described, comprising the steps of: —a) obtaining a digital three-dimensional model (2) of the patient's palate by means of a three-dimensional scan; —b) defining an operative outline (3;3′) through an offset of at least one portion of said three-dimensional model (2); —c) obtaining a path for at least one height hi of said three-dimensional model, said path being arranged inside said operative outline (3:3′); —d) depositing a continuous filiform element according to said path (9).

Provided is a powder material for forming a three-dimensional object, the powder material containing granulated particles containing: a resin; and inorganic particles of which primary particles have a volume average particle diameter of 1 micrometer or less, wherein the granulated particles have a volume average particle diameter of 10 micrometers or greater but 70 micrometers or less and a BET specific surface area of 6 m.sup.2/g or greater but 8 m.sup.2/g or less.

This invention relates to printable high strength/toughness polymerizable material systems for making dental products such as artificial teeth, dentures, splints, veneers, inlays, onlays, orthodontic appliances, aligners, copings, frame patterns, crowns and bridges and the like. A DLP, stereolithography, modified or their modification and combination based printer is used to cure polymerizable material in several different methods of this invention to build-up the object. The resulting three-dimensional object has good dimensional stability.

A method for making a dental appliance configured to position at least one tooth of a patient includes printing a hardenable liquid resin composition on a major surface of a polymeric material to form a pattern thereon, wherein the hardenable liquid resin composition includes a glass ionomer, a resin modified glass ionomer, and mixtures and combinations thereof. A dental appliance is formed from the polymeric material that includes an arrangement of cavities configured to receive one or more teeth.

A radiation curable composition including at least one radiation hardenable component, a photo-initiator, and a filler material having a population of particulates in an amount greater than or equal to 50% by weight of the printable composition. The population of particulates exhibits a median diameter (D50) of greater than or equal to 0.3 micrometer on a volume-average basis as determined using the Particle Size Test Method, and the radiation curable composition exhibits a viscosity of less than or equal to 150 Pa s when measured using the Viscosity Test Method. A method, apparatus, and systems for producing composite articles by selectively exposing a portion of the radiation curable composition to a source of actinic radiation to at least partially cure the exposed portion of the radiation curable composition, thereby forming a hardened layer, preferably by an additive manufacturing process such as stereophotolithography, are also described. The composite articles may include composite dental restorations.

Network enabled 3D printing and automated processing techniques for oral devices are disclosed herein. An example technique includes receiving, via a network, a data file representative of a mouth of a user, and printing, by a 3D printer, a 3D oral device based on the data file. The example technique may further include automatically ejecting, from the 3D printer, the 3D oral device, and scanning the 3D oral device to generate a 3D scan file of the 3D oral device. The example technique may further include comparing the 3D scan file with the data file to determine at least one feature represented in the 3D scan file that exceeds a deviation threshold relative to a corresponding respective feature represented in the data file; and finishing, by a finishing module, the 3D oral device by smoothing the at least one feature on the 3D oral device.

An assembly useful for thermoforming a dental aligner from polymer sheet material includes (a) a custom dental model having a planar bottom surface and a receptacle formed in said planar bottom surface; and (b) a reusable die removably received in said receptacle.

The present invention relates to a suspension comprising 50-95% by weight of the total suspension (w/w) of at least one metallic material and/or ceramic material and/or polymeric material and/or solid carbon containing material; and at least 5% by weight of the total suspension of one or more fatty acids or derivatives thereof. In addition, the invention relates to uses of such suspension in 3D printing processes.

Orthodontic articles and polymerizable resin compositions are described. The orthodontic article comprises a cured composition comprising the reaction product of free-radically polymerizable resin comprising 30 to 70 wt. %, inclusive, of at least one urethane component, and 25 to 70 wt. %, inclusive, of reactive diluent(s) comprising at least one monofunctional (meth)acrylate monomer. The polymerizable resin comprises no greater than 35 wt. % of reactive diluent(s) having a high affinity for water. Reactive diluent(s) such as monofunctional (meth)acrylate monomers having a high affinity for water have low log P values. In one embodiment, the polymerizable resin comprises at least one acidic monomer.