A process may involve treating calcium sulfate separated from phosphoric acid with acid to obtain a suspension comprising purified calcium sulfate, separating the purified calcium sulfate in solid form from a liquid phase of the suspension, treating the purified calcium sulfate with water or with a salt- and/or chelate ligand-containing aqueous solution to leach rare earths out of the calcium sulfate, separating the further-purified calcium sulfate in solid form from the liquid phase of the suspension, mixing the purified calcium sulfate that is separated off with admixtures and reducing agents to obtain a raw meal mixture for cement clinker production, burning the raw meal mixture to obtain the cement clinker and thereby forming sulfur dioxide as offgas, and feeding the sulfur dioxide as raw material to sulfuric acid production to produce the sulfuric acid.

A process for producing sulfuric acid and cement clinker may use calcium sulfate that is formed as a solid by-product and separated off in phosphoric acid production in a reaction of raw phosphate with sulfuric acid to form phosphoric acid. The process comprises treating calcium sulfate separated from the phosphoric acid with an acid to obtain a suspension comprising purified calcium sulfate, separating the purified calcium sulfate in solid form from the liquid phase of the suspension, mixing the purified calcium sulfate with admixtures and reducing agents to obtain a raw meal mixture for cement clinker production, burning the raw meal mixture to obtain the cement clinker, with formation of sulfur dioxide as offgas, and subjecting the sulfur dioxide formed to offgas purification and feeding the sulfur dioxide as raw material to sulfuric acid production to produce the sulfuric acid. The sulfuric acid produced may be used as starting material in phosphoric acid production.

The disclosure discloses a production method for producing cement and co-producing sulfuric acid from phosphogypsum. The method includes: pretreating and purifying the phosphogypsum to reduce insoluble phosphorus, water-soluble phosphorus impurities, and most free water in the phosphogypsum, directly feeding the materials kneaded and granulated with a reducing agent into a reduction and decomposition integrated rotary kiln with a fluidized preheating function, and controlling to carry out step-by-step heating, drying, dehydration, reduction and decomposition in a gas phase atmosphere under pulverized coal combustion; using sulfur dioxide gas generated after reduction and decomposition to produce the sulfuric acid after dust removal and purification; making the materials after reduction and decomposition enter an oxidation calcining kiln for sintering a cement clinker, and controlling to heat, mineralize and sinter the cement clinker in the gas phase atmosphere under the pulverized coal combustion.

The present invention relates to a process for decomposing calcium sulfate (CaSO.sub.4) present in phosphogypsum (PG), comprising the following steps: a) providing a reactor containing phosphogypsum (PG) and a solid source of carbon (C), b) reacting a flow of dioxygen (Oz) with the source of carbon (C) so as to generate carbon oxide (CO), c) reacting carbon oxide (CO) obtained in step a) with calcium sulfate (CaSO.sub.4) of the phosphogypsum to produce calcium oxide (CaO) and sulfoxide (SO.sub.2) according to the following reaction: CaSO.sub.4+CO.fwdarw.CaO+SO.sub.2+CO.sub.2 wherein the mass ratio C/PG is between 0.2 and DA, and the mass ratio 15 O.sub.2/PG is between 0.5 and 1.5.

A process for producing sulfuric acid and cement clinker may use calcium sulfate that is formed as a solid by-product and separated off in phosphoric acid production in a reaction of raw phosphate with sulfuric acid to form phosphoric acid. The process comprises treating calcium sulfate separated from the phosphoric acid with an acid to obtain a suspension comprising purified calcium sulfate, separating the purified calcium sulfate in solid form from the liquid phase of the suspension, mixing the purified calcium sulfate with admixtures and reducing agents to obtain a raw meal mixture for cement clinker production, burning the raw meal mixture to obtain the cement clinker, with formation of sulfur dioxide as offgas, and subjecting the sulfur dioxide formed to offgas purification and feeding the sulfur dioxide as raw material to sulfuric acid production to produce the sulfuric acid. The sulfuric acid produced may be used as starting material in phosphoric acid production.

The present invention relates to a process for decomposing calcium sulfate (CaSO.sub.4) present in phosphogypsum (PG), comprising the following steps: a) providing a reactor containing phosphogypsum (PG) and a solid source of carbon (C), b) reacting a flow of dioxygen (Oz) with the source of carbon (C) so as to generate carbon oxide (CO), c) reacting carbon oxide (CO) obtained in step a) with calcium sulfate (CaSO.sub.4) of the phosphogypsum to produce calcium oxide (CaO) and sulfoxide (SO.sub.2) according to the following reaction: CaSO.sub.4+CO.fwdarw.CaO+SO.sub.2+CO.sub.2 wherein the mass ratio C/PG is between 0.2 and DA, and the mass ratio 15 O.sub.2/PG is between 0.5 and 1.5.

The present invention discloses a resource recovery method and a resource recovery system of desulfurized ash. The resource recovery method comprises: washing desulfurized ash with water, and performing solid-liquid separation to obtain solid residues rich in calcium sulfite and calcium sulfate and a solution rich in calcium hydroxide; preparing the solution into desulfurized slurry; and roasting the solid residues under the action of a reducing agent to obtain flue gas rich in sulfur dioxide and residues rich in calcium oxide. Therefore, the recovery of sulfur and calcium in the desulfurized ash is realized, and no solid waste, liquid waste, gas waste, etc. are produced in the process.

A resource recovery method and a resource recovery system of desulfurized ash. The resource recovery method includes washing desulfurized ash with water, and performing solid-liquid separation to obtain solid residues rich in calcium sulfite and calcium sulfate and a solution rich in calcium hydroxide; preparing the solution into desulfurization slurry; and roasting the solid residues under the action of a reducing agent to obtain flue gas rich in sulfur dioxide and residues rich in calcium oxide. Therefore, the recovery of sulfur and calcium in the desulfurized ash is realized, and no solid waste, liquid waste, gas waste, etc. are produced in the process.