C01B21/42

Separation and concentration of nitrate from aqueous solutions and gaseous streams
11634326 · 2023-04-25 · ·

A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A.sup.+][X.sup.−], wherein [A.sup.+] represents a phosphonium or ammonium cation and [X.sup.−] represents a counter anion which is NO.sub.3.sup.−, an halide anion displaceable by NO.sub.3.sup.−, or both, with a fluid which contains HNO.sub.3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 and an aqueous phase consisting of a nitrate-depleted aqueous solution that contains the other mineral acid(s); stripping the nitric acid from said nitrate-loaded ionic liquid to create an aqueous nitrate solution and regenerate ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z≥0 with reduced nitrate loading, or unloaded [A.sup.+][NO.sub.3.sup.−].sub.z=0 ionic liquid.

Separation and concentration of nitrate from aqueous solutions and gaseous streams
11634326 · 2023-04-25 · ·

A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A.sup.+][X.sup.−], wherein [A.sup.+] represents a phosphonium or ammonium cation and [X.sup.−] represents a counter anion which is NO.sub.3.sup.−, an halide anion displaceable by NO.sub.3.sup.−, or both, with a fluid which contains HNO.sub.3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 and an aqueous phase consisting of a nitrate-depleted aqueous solution that contains the other mineral acid(s); stripping the nitric acid from said nitrate-loaded ionic liquid to create an aqueous nitrate solution and regenerate ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z≥0 with reduced nitrate loading, or unloaded [A.sup.+][NO.sub.3.sup.−].sub.z=0 ionic liquid.

SEPARATION AND CONCENTRATION OF NITRATE FROM AQUEOUS SOLUTIONS AND GASEOUS STREAMS
20220017365 · 2022-01-20 ·

A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A.sup.+][X.sup.−], wherein [A.sup.+] represents a phosphonium or ammonium cation and [X.sup.−] represents a counter anion which is NO.sub.3.sup.−, an halide anion displaceable by NO.sub.3.sup.−, or both, with a fluid which contains HNO.sub.3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 and an aqueous phase consisting of a nitrate-depleted aqueous solution that contains the other mineral acid(s); stripping the nitric acid from said nitrate-loaded ionic liquid to create an aqueous nitrate solution and regenerate ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z≥0 with reduced nitrate loading, or unloaded [A.sup.+][NO.sub.3.sup.−].sub.z=0 ionic liquid.

SEPARATION AND CONCENTRATION OF NITRATE FROM AQUEOUS SOLUTIONS AND GASEOUS STREAMS
20220017365 · 2022-01-20 ·

A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A.sup.+][X.sup.−], wherein [A.sup.+] represents a phosphonium or ammonium cation and [X.sup.−] represents a counter anion which is NO.sub.3.sup.−, an halide anion displaceable by NO.sub.3.sup.−, or both, with a fluid which contains HNO.sub.3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 and an aqueous phase consisting of a nitrate-depleted aqueous solution that contains the other mineral acid(s); stripping the nitric acid from said nitrate-loaded ionic liquid to create an aqueous nitrate solution and regenerate ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z≥0 with reduced nitrate loading, or unloaded [A.sup.+][NO.sub.3.sup.−].sub.z=0 ionic liquid.

SEPARATION OF A STRONG ACID FROM ITS SALTS
20210323821 · 2021-10-21 ·

The present invention relates to a process for the separation of strong acid from its salts. In said process, a strong acid salt is reacted with organic weak base (OWB) in the presence of a hydrophilic solvent and CO.sub.2. The cation of the strong acid salt is precipitated to produce a carbonate/bicarbonate salt and the strong acid form a liquid salt with the OWB. The above process is performed in a solution comprising both the strong acid salt and the WBO. In the next step, the strong acid is released from its OWB liquid salt and the OWB is returned to a previous step.

SELECTIVE TREATMENT OF NITRATE FOR BRINE REGENERATION

The present disclosure concerns processes for removal of nitrate from nitrate-rich brines, typically selective removal that permits reclaiming the nitrate after such removal.

SELECTIVE TREATMENT OF NITRATE FOR BRINE REGENERATION

The present disclosure concerns processes for removal of nitrate from nitrate-rich brines, typically selective removal that permits reclaiming the nitrate after such removal.