One object of the present invention is to provide a gas-liquid separating device which can efficiently recover a target gas from a mixture containing at least a gas and a liquid in a gas-liquid coexistence state, and the present invention provides a gas-liquid separating device which separates and recovers a gas and a liquid from a mixture containing the gas and the liquid in a gas-liquid coexistence state, wherein the gas-liquid separating device includes an airtight space in which the mixture containing the gas and the liquid in a gas-liquid coexistence state is supplied and the mixture is stored as a mixture separated into gas and liquid, a supply path for supplying the mixture containing the gas and the liquid in a gas-liquid coexistence state into the airtight space, a gas recovery path for discharging the gas in the airtight space to the outside of the airtight space, a first decompressor which is provided in the gas recovery path and recovers the gas from the airtight space, a liquid recovery path for discharging the liquid in the airtight space to the outside of the airtight space, and a second decompressor which is provided in the liquid recovery path and configured to recover the liquid from the airtight space.

The apparatus includes one or more cylindrical housings connected to one another, a jacket on an outer side of a housing, an inner cylinder disposed at least in an interior of a first cylindrical housing, a heat insulation gasket, inner members, a corrosive high temperature gas inlet disposed on the heat insulation gasket, a gas and liquid phase outlet disposed at a bottom of the housing or a bottom of a last housing and a coolant inlet and outlet connected to an interior of the jacket. The heat insulation gasket seals the first cylindrical housing and a top of the inner cylinder in the interior of the first cylindrical housing. The inner members are distributed along a wall of the housing, communicate an interior of the jacket with an interior of the housing, and distribute a liquid in the interior of the jacket to the interior of the housing.

A gaseous species can be separated from an aqueous donor mixture and absorbed in an aqueous recipient mixture using a membrane separation apparatus while maintaining a large temperature difference (e.g. greater than 30° C.) between the two aqueous mixtures. A composite membrane is employed which comprises a non-porous membrane adjacent a porous membrane. The non-porous membrane is permeable to the gaseous species. The porous membrane has a porosity greater than 50% and is hydrophobic. In one embodiment, the composite membrane is oriented such that the porous membrane faces the aqueous recipient mixture and is impermeable thereto at the recipient mixture pressure. The invention is particularly suitable for separating chlorine dioxide from chlorine dioxide reaction liquor and absorbing in chilled water.

A method for preparing chlorine gas through catalytic oxidation of hydrogen chloride is carried out by one-time hydrogen chloride feeding and multi-stage oxygen feeding, one-time oxygen feeding and multi-stage hydrogen chloride feeding, or both, returning a product gas stream without separation thereof, and optionally carrying out heat insulation means. In the present invention, excessive reaction heat concentration is prevented, therefore, the method of the present invention is a chlorine gas recovery method implemented through the Deacon catalytic oxidation of hydrogen chloride that may be industrialized.

The invention relates to a method for separating chlorine from a gaseous anode outlet stream mass flow of an electrochemical cell reactor. In a first aspect, the method makes use of an absorption step, wherein an anode outlet stream mass flow of the electrochemical cell reactor is exposed to an organic solvent being essentially immiscible with water for achieving an exergy-efficient separation of chlorine and hydrogen chloride. In a further aspect, the method makes use of absorption step, wherein the anode outlet stream mass flow is exposed to an ionic liquid, wherein the hydrogen chloride is dissolved in said ionic liquid, thereby forming a gas flow containing essentially chlorine and a solution mass flow comprising the ionic liquid and the hydrogen chloride. The hydrogen chloride is desorbed from the solution mass flow in a desorption step. In another aspect, the method makes use of a distillation step, wherein the anode outlet stream mass flow is separated at a static pressure of at least 2 bar for an exergy-efficient separation.

The present invention provides a method for producing high-purity hydrogen chloride, comprising the steps of: purifying each of crude hydrogen and crude chlorine as raw materials to a purity of 99.999% or higher; reacting an excessive molar amount of the purified hydrogen with the purified chlorine at a temperature ranging from 1,200° C. to 1,400° C. to synthesize hydrogen chloride; converting the hydrogen chloride to a liquid state by compression; and purifying the hydrogen chloride and separating unreacted hydrogen by fractional distillation. The invention also provides a system for carrying out the method. According to the method and system, an environmentally friendly production process can be provided, which can easily produce a large amount of hydrogen chloride having a purity of 3 N (99.9%)−6 N (99.9999%) in a cost-effective manner and enables energy consumption to be significantly reduced.

One object of the present invention is to provide a gas-liquid separating device which can efficiently recover a target gas from a mixture containing at least a gas and a liquid in a gas-liquid coexistence state, and the present invention provides a gas-liquid separating device which separates and recovers a gas and a liquid from a mixture containing the gas and the liquid in a gas-liquid coexistence state, wherein the gas-liquid separating device includes an airtight space in which the mixture containing the gas and the liquid in a gas-liquid coexistence state is supplied and the mixture is stored as a mixture separated into gas and liquid, a supply path for supplying the mixture containing the gas and the liquid in a gas-liquid coexistence state into the airtight space, a gas recovery path for discharging the gas in the airtight space to the outside of the airtight space, a first decompressor which is provided in the gas recovery path and recovers the gas from the airtight space, a liquid recovery path for discharging the liquid in the airtight space to the outside of the airtight space, and a second decompressor which is provided in the liquid recovery path and configured to recover the liquid from the airtight space.

The invention relates to a method for separating chlorine from a gaseous anode outlet stream mass flow of an electrochemical cell reactor. In a first aspect, the method makes use of an absorption step, wherein an anode outlet stream mass flow of the electrochemical cell reactor is exposed to an organic solvent being essentially immiscible with water for achieving an exergy-efficient separation of chlorine and hydrogen chloride. In a further aspect, the method makes use of absorption step, wherein the anode outlet stream mass flow is exposed to an ionic liquid, wherein the hydrogen chloride is dissolved in said ionic liquid, thereby forming a gas flow containing essentially chlorine and a solution mass flow comprising the ionic liquid and the hydrogen chloride. The hydrogen chloride is desorbed from the solution mass flow in a desorption step. In another aspect, the method makes use of a distillation step, wherein the anode outlet stream mass flow is separated at a static pressure of at least 2 bar for an exergy-efficient separation.

The invention relates to a storage medium and to a method for using a storage medium based on ionic compounds, which can reversibly absorb and store chlorine and chlorine from process gases, and which can release the same again by changing the ambient conditions, wherein the storage medium can be reused for this task after discharge.

A method includes depositing graphene into a hardener, mixing the hardener and the graphene to produce a homogeneous composite mixture, adding a resin material to the composite mixture to produce an epoxy graphene material, coating a structure with the epoxy graphene material, aligning the graphene sheets in the in-plane orientation, and curing the epoxy graphene material.