Provided is a preparation method and use method of a material for deep purification of HF electronic gas. A metal fluoride-loaded activated carbon material AC/MFx.nH20 is prepared, and a mixed gas flow of carbonyl fluoride and high-purity nitrogen is used to deeply dehydrate the material to obtain the material for deep purification of HF electronic gas AC/MFx. This kind of material has fluoride that can form crystal water to form hydrated metal fluoride, and has strong water absorption properties. Moreover, the anhydrous fluoride and activated carbon do not have to face the problem of being corroded by HF, and the collapse of framework structure and the secondary pollution to HF from reaction products would not be caused. The material has the advantages of high purity and extremely low moisture content when being used for efficiently removing moisture in HF.

The present disclosure relates to a method of making an electrochemically active material, which comprises metal nanostructures encapsulated in LaF.sub.3 shells. The electrochemically active material may be included in an electrode of an F-shuttle battery that includes a liquid electrolyte, which, optionally, allows the F-shuttle batteries to operate at room temperature.

A technique for obtaining anhydrous hydrogen fluoride (AHF) from an aqueous solution of hexafluorosilicic acid (HSA). A method for obtaining hydrogen fluoride from an aqueous solution of hexafluorosilicic acid can include mixing a solution of hexafluorosilicic acid with a sulfuric acid solution, desorbing the hydrogen fluoride from the resultant solution of sulfuric acid, treating it with sulfuric acid and condensing the anhydrous hydrogen fluoride from unabsorbed gasses. The generated gaseous products are then burned in a fire of hydrogen-containing fuel and an oxygen-containing oxidant, yielding a solid silicon dioxide. The remaining products are cooled and yield condensed anhydrous hydrogen fluoride.

The present disclosure relates to a method of making an electrochemically active material, which comprises metal nanostructures encapsulated in LaF.sub.3 shells. The electrochemically active material may be included in an electrode of an F-shuttle battery that includes a liquid electrolyte, which, optionally, allows the F-shuttle batteries to operate at room temperature.

A hydrogen fluoride gas removal device has: a hydrogen fluoride gas removal treatment machine that is configured to perform a treatment of removing hydrogen fluoride gas from the mixed gas by bringing the mixed gas into contact with a removal agent for removing the hydrogen fluoride gas from the mixed gas; a removal agent supply machine that is configured to supply the removal agent to the hydrogen fluoride gas removal treatment machine; a removal agent recycling treatment machine that is configured to perform a recycling treatment on the used removal agent to improve hydrogen fluoride gas removal performance of the removal agent; and a recycling-treated removal agent transport machine that is configured to transport the recycling-treated removal agent to supply the removal agent to the removal agent supply machine.

A composition is provided including aqueous hydrogen fluoride; and a cross-linked copolymer comprising acrylamide units cross-linked with an acrylic acid salt. The cross-linked polymer has an average liquid aqueous hydrogen fluoride absorption capacity of less than 40 grams aqueous hydrogen fluoride per gram of cross-linked polymer.

A method for separating halocarbons and, in particular, a method for separating (Z)-1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(Z), or simply 1233zd(Z)) and 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa, or simply 244fa) via distillation by adding a third component, hydrogen fluoride (HF), forming a binary azeotrope of 1233zd(Z) and HF. The binary 1233zd(Z)/HF azeotrope may then be recovered from the distillation column as an overhead stream which includes only a relatively minor amount of 244fa, while the 244fa may be recovered from the distillation column as a bottoms stream which includes only relatively minor amounts of 1233zd(Z) and HF.

Provided is a preparation method and use method of a material for deep purification of HF electronic gas. A metal fluoride-loaded activated carbon material AC/MFx.Math.nH.sub.2O is prepared, and a mixed gas flow of carbonyl fluoride and high-purity nitrogen is used to deeply dehydrate the material to obtain the material for deep purification of HF electronic gas AC/MFx. This kind of material has fluoride that can form crystal water to form hydrated metal fluoride, and has strong water absorption properties. Moreover, the anhydrous fluoride and activated carbon do not have to face the problem of being corroded by HF, and the collapse of framework structure and the secondary pollution to HF from reaction products would not be caused. The material has the advantages of high purity and extremely low moisture content when being used for efficiently removing moisture in HF.

A method of recovering hydrogen fluoride (HF) in a fluorocarbon production process, including absorbing hydrogen fluoride (HF) from an organic stream into water and distilling the hydrogen fluoride (HF) and water solution to produce a recovered hydrogen fluoride (HF) product. The recovered hydrogen fluoride (HF) product may then be used in a variety of fluorocarbon manufacturing processes.