A method for crystallizing calcium nitrate from an aqueous calcium nitrate composition including from 6 to 12 weight % nitric acid, from 11 to 17 weight % phosphoric acid, and from 36 to 49 weight % dissolved calcium nitrate, which aqueous composition is optionally directly obtainable from digesting phosphate rock in nitric acid. The method includes filling at least one vertical crystallizing tank through an inlet with the aqueous calcium nitrate composition. The crystallizing tank includes a vertical cylindrical section, a first inlet, a first outlet, a second inlet, three concentric banks of cooling coils, an agitator, and a temperature measurement device. The method includes circulating through the banks of cooling coils a cooling fluid, having an initial temperature ranging from −40° C. to −5° C., and rotating the agitator such that a minimum average heat transfer of 400 W/m.sup.2.Math.K is achieved on the cooling coil the most distant from the agitator.

A method for crystallizing calcium nitrate from an aqueous calcium nitrate composition including from 6 to 12 weight % nitric acid, from 11 to 17 weight % phosphoric acid, and from 36 to 49 weight % dissolved calcium nitrate, which aqueous composition is optionally directly obtainable from digesting phosphate rock in nitric acid. The method includes filling at least one vertical crystallizing tank through an inlet with the aqueous calcium nitrate composition. The crystallizing tank includes a vertical cylindrical section, a first inlet, a first outlet, a second inlet, three concentric banks of cooling coils, an agitator, and a temperature measurement device. The method includes circulating through the banks of cooling coils a cooling fluid, having an initial temperature ranging from −40° C. to −5° C., and rotating the agitator such that a minimum average heat transfer of 400 W/m.sup.2.Math.K is achieved on the cooling coil the most distant from the agitator.

The invention relates to a solid particulate calcium nitrate composition having particles with an average particle size of between 0.1 and 1 mm and comprising an anti-caking agent, wherein the anti-caking agent consists of a solid particulate silicate with an average particle size of between 0.05 and 750 m. The invention furthermore relates to a pre-blend binder composition comprising such a solid particulate calcium nitrate composition. Also a dry mortar mix or tile adhesive composition and a dry concrete mix comprising an aggregate and such a pre-blend binder composition. Also a method for producing a solid particulate calcium nitrate composition, the use of a solid particulate silicate as anti-caking agent for a solid particulate calcium nitrate composition and the use of a solid particulate calcium nitrate composition as a setting accelerator for cementitious pre-blend binder composition are disclosed.

The invention relates to a method for producing an anhydrous powder having a calcium nitrate content of between 92 and 99.9 weight %, a water content of between 0.1 and 8 weight %; and a particle size of between 0.05 and 1.5 mm, wherein the method comprises the step of subjecting a calcium nitrate solution having a water content of between 70 and 15 weight % and a calcium nitrate content of between 30 and 85 weight % to a drying step in an industrial turbo-dryer, resulting in the anhydrous calcium nitrate powder. The invention furthermore relates to such an anhydrous calcium nitrate powder and the use of an industrial turbo-dryer to produce such anhydrous calcium nitrate powder.

The invention relates to a method for producing an anhydrous powder having a calcium nitrate content of between 92 and 99.9 weight %, a water content of between 0.1 and 8 weight %; and a particle size of between 0.05 and 1.5 mm, wherein the method comprises the step of subjecting a calcium nitrate solution having a water content of between 70 and 15 weight % and a calcium nitrate content of between 30 and 85 weight % to a drying step in an industrial turbo-dryer, resulting in the anhydrous calcium nitrate powder. The invention furthermore relates to such an anhydrous calcium nitrate powder and the use of an industrial turbo-dryer to produce such anhydrous calcium nitrate powder.

The present disclosure discloses a method, product, and system for cogenerating ferric phosphate through a nitrophosphate fertilizer device. The method comprises the steps of: acid-hydrolyzing phosphate rock with a nitric acid, and separating acid-insoluble substances to obtain an acid-hydrolyzed solution; freezing-crystallizing the acid-hydrolyzed solution, and carrying out solid-liquid separation to obtain a first solution; adding a solution containing sulfate ions to the first solution for reaction to obtain a second solution; subjecting the second solution to a denitrification to obtain a third solution; adding ammonia to the third solution for neutralization, and carrying out solid-liquid separation to obtain an ammonium phosphate solution, and adding an iron source to the ammonium phosphate solution for reaction to prepare a ferric phosphate. The present disclosure utilizes phosphate rock raw material to prepare a high-purity ferric phosphate, and by-product can be directly used for fertilizer preparation or as independent product, without waste.

A method for crystallizing calcium nitrate from an aqueous calcium nitrate composition including from 6 to 12 weight % nitric acid, from 11 to 17 weight % phosphoric acid, and from 36 to 49 weight % dissolved calcium nitrate, which aqueous composition is optionally directly obtainable from digesting phosphate rock in nitric acid. The method includes filling at least one vertical crystallizing tank through an inlet with the aqueous calcium nitrate composition. The crystallizing tank includes a vertical cylindrical section, a first inlet, a first outlet, a second inlet, three concentric banks of cooling coils, an agitator, and a temperature measurement device. The method includes circulating through the banks of cooling coils a cooling fluid, having an initial temperature ranging from 40 C. to 5 C., and rotating the agitator such that a minimum average heat transfer of 400 W/m.sup.2.Math.K is achieved on the cooling coil the most distant from the agitator.

A method for crystallizing calcium nitrate from an aqueous calcium nitrate composition including from 6 to 12 weight % nitric acid, from 11 to 17 weight % phosphoric acid, and from 36 to 49 weight % dissolved calcium nitrate, which aqueous composition is optionally directly obtainable from digesting phosphate rock in nitric acid. The method includes filling at least one vertical crystallizing tank through an inlet with the aqueous calcium nitrate composition. The crystallizing tank includes a vertical cylindrical section, a first inlet, a first outlet, a second inlet, three concentric banks of cooling coils, an agitator, and a temperature measurement device. The method includes circulating through the banks of cooling coils a cooling fluid, having an initial temperature ranging from 40 C. to 5 C., and rotating the agitator such that a minimum average heat transfer of 400 W/m.sup.2.Math.K is achieved on the cooling coil the most distant from the agitator.

The invention relates to a method for producing an anhydrous powder having a calcium nitrate content of between 92 and 99.9 weight %, a water content of between 0.1 and 8 weight %; and a particle size of between 0.05 and 1.5 mm, wherein the method comprises the step of subjecting a calcium nitrate solution having a water content of between 70 and 15 weight % and a calcium nitrate content of between 30 and 85 weight % to a drying step in an industrial turbo-dryer, resulting in the anhydrous calcium nitrate powder. The invention furthermore relates to such an anhydrous calcium nitrate powder and the use of an industrial turbo-dryer to produce such anhydrous calcium nitrate powder.

The invention relates to a method for producing an anhydrous powder having a calcium nitrate content of between 92 and 99.9 weight %, a water content of between 0.1 and 8 weight %; and a particle size of between 0.05 and 1.5 mm, wherein the method comprises the step of subjecting a calcium nitrate solution having a water content of between 70 and 15 weight % and a calcium nitrate content of between 30 and 85 weight % to a drying step in an industrial turbo-dryer, resulting in the anhydrous calcium nitrate powder. The invention furthermore relates to such an anhydrous calcium nitrate powder and the use of an industrial turbo-dryer to produce such anhydrous calcium nitrate powder.