C02F1/4693

Method for producing lithium hydroxide monohydrate from brines

A method for LiOHH.sub.2O production from lithium-bearing multicomponent hydromineral raw materials includes filtering lithium-bearing brine contaminated with suspended particles with regeneration of filters and processing of used regenerate, and obtaining pregnant lithium-bearing brine, isolation of lithium chloride from the brine in the form of a primary concentrate in sorption-desorption modules, and nanofiltration of the primary lithium concentrate from magnesium, calcium and sulfate ions. By means of reverse osmosis, electrodialysis concentration and ion-exchange purification from impurities followed by thermal concentration, the primary lithium concentrate is converted into a pregnant lithium chloride concentrate which is converted into a LiOH solution by membrane electrolysis. The LiOH solution is boiled down, resulting in LiOH.H.sub.2O crystallization.

Electrodialysis process and bipolar membrane electrodialysis devices for silica removal
11577202 · 2023-02-14 · ·

Provided are electrodialysis systems for removing silica from a desalinated water stream and methods for removing silica from a desalinated water stream. For example, described are bipolar membrane electrodialysis devices for removing silica from water comprising one or more anion exchange membranes; one or more bipolar membranes; and a pair of electrodes comprising a positive electrode and a negative electrode. Also described are electrodialysis systems comprising: one or more electrodialysis devices for the removal of dissolved ions and one or more bipolar membrane electrodialysis devices, wherein a product inlet stream of the one or more bipolar membrane electrodialysis devices comprises the product outlet stream of the one or more electrodialysis devices.

METHOD OF EXTRACTING LITHIUM FROM LITHIUM-CONTAINING SOLUTION
20230038391 · 2023-02-09 ·

A method of extracting lithium from a lithium-containing solution according to an exemplary embodiment of the present invention includes: obtaining a lithium chloride solution from the lithium-containing solution; and crystallizing and removing sodium chloride in the obtained lithium chloride solution.

Gas recovery from wastewater

The present invention is in the field of a system for gas recovery from wastewater, a method for treating wastewater, and a method wherein ammonia and carbon dioxide are recovered. Typically a wastewater stream is fed into the system, treated and stripped from ammonia and carbon dioxide, and a cleaner stream is released.

MANAGED ECOSYSTEM UTILIZING PRODUCED WATER FROM OIL AND/OR GAS RECOVERY OPERATIONS AND METHOD FOR SEQUESTERING CARBON DIOXIDE USING SAME
20230233993 · 2023-07-27 ·

Managed ecosystems, methods for producing managed ecosystems and methods for using managed ecosystems for sequestering carbon dioxide are described herein. Produced water is obtained and purified to sustain a managed ecosystem with saline-tolerant vegetation. The managed ecosystem biologically sequesters carbon dioxide by photosynthetically absorbing carbon dioxide from the atmosphere and by decomposition into a layer of sediment on the ecosystem floor.

Cooling pond water treatment system

A method of increasing operational efficiency of a power plant includes determining an average rate of accumulation of scale-forming compounds in a cooling water source, directing water from the cooling water source having a first concentration of scale forming compounds through a treatment system to produce a treated water having a lower concentration of scale-forming components than the first concentration by operating the treatment system with operating parameters selected such that a rate of removal of the scale-forming components from the water in the treatment system is greater than the average rate of accumulation of the scale-forming components, directing the treated water back into the cooling water source, and circulating water including the treated water from the cooling water source through a cooling system of the power plant.

Ion-Selective Composite Membrane
20230226499 · 2023-07-20 ·

The present invention relates to an ion-selective composite membrane having a thickness of between 4 μm and 100 μm, comprising at least one inner layer disposed between two outer layers, wherein: —the outer layers are each formed of a first material comprising a network of nanofibres and/or crosslinked microfibres and pores with a diameter of between 10 nm and 10 μm, —the inner layer is formed of a second material comprising nanoparticles functionalized at the surface by charged groups and/or groups which become charged in the presence of water and having pores with a diameter of between 1 and 100 nm.

PROCESS AND APPARATUS FOR HIGH RECOVERY IN ELECTRODIALYSIS AND ELECTRODEIONIZATION SYSTEMS
20230226494 · 2023-07-20 ·

Electrodeionization and electrodialysis systems which eliminate or substantially prevent the feed water from entering the concentrating compartments, for improving the recovery of product water as well as improving the current efficiency. Electro-osmotically generated flows of water entering from the diluting compartments of the stack constitutes the majority of concentrate feed, leading to the production of high purity, desalinated waters in the diluting compartments and highly concentrate solutions in the concentrate compartments.

Li recovery processes and onsite chemical production for Li recovery processes

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

Method and system for providing ultrapure water with flexible lamp configuration

A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate a continuously variable intensity of the actinic radiation.