A system for an efficient and sustainable electrochemical treatment of wastewater comprises a reactor tank, a first electrolyzer with a stack of electrolytic cells, each electrolytic cell comprising an anode of a first composition, and a second electrolyzer with a stack of electrolytic cells, each electrolytic cell comprising an anode of a second composition, and a contaminant concentration measuring device for monitoring the contaminant concentration in the reactor tank to the first or to the second electrolyzer. Wastewater to be treated is supplied from the reactor tank to the first electrolyzer until the contaminant concentration becomes substantially constant as measured by the contaminant removal rate being around 0 mg/h, which indicates the buildup of byproducts generated in the first electrolyzer, at which time the wastewater is supplied from the reactor tank to the second electrolyzer with anodes which can efficiently treat the byproducts of the reaction in the first electrolyzer.

An electrolyte solution production device includes: an electrolysis unit that includes a stacked body having conductive film stacked and interposed between electrodes adjacent to each other and is configured to electrolyze a liquid; and housing having the electrolysis unit disposed in an inside of the housing. In addition, housing includes inflow port into which the liquid supplied to the electrolysis unit flows and outlet port from which an electrolyte solution produced in the electrolysis unit flows out. Conductive film has protrusion that protrudes toward the inner surface of housing and is provided to position conductive film with respect to housing. This can provide the electrolyte solution production device in which conductive film can be downsized and easily positioned with respect to housing.

Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H.sub.2O.sub.2 and .Math.OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe.sup.3+ and 5 to 15% wt. Cu.sup.2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .Math.OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H.sub.2O.sub.2 to .Math.OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.

A system for treating a source of water contaminated with PFAS is disclosed. The system includes a PFAS separation stage having an inlet fluidly connectable to the source of water contaminated with PFAS, a diluate outlet, and a concentrate outlet and a PFAS elimination stage positioned downstream of the PFAS separation stage and having an inlet fluidly connected to an outlet of the PFAS separation stage, the elimination of the PFAS occurring onsite with respect to the source of water contaminated with PFAS, with the system maintaining an elimination rate of PFAS greater than about 99%. A method of treating water contaminated with PFAS is also disclosed. The method includes introducing contaminated water from a source of water contaminated with a first concentration of PFAS to an inlet of a

PFAS separation stage, treating the contaminated water in the PFAS separation stage to produce a product water substantially free of PFAS and a PFAS concentrate having a second PFAS concentration greater than the first PFAS concentration, introducing the PFAS concentrate to an inlet of a PFAS elimination stage; and activating the PFAS elimination stage to eliminate the PFAS in the PFAS concentrate. A method of retrofitting a water treatment system as described herein is also disclosed. The method includes providing a PFAS elimination module as described herein and fluidly connecting the PFAS elimination module downstream of a PFAS separation stage.

An oil-contaminated soil and groundwater treatment system, in which the polluted groundwater pumped into the electrocatalytic device uses a high-voltage electric field to change the structure of water molecules. After high voltage discharge, electrocatalysis and electrolysis, alkaline reduced water, acidic oxidized water and neutral water can be quickly produced. By the oxidation effect of electrocatalytic device anode, chloride ions and dissolved oxygen in water generate hypochlorous acid and superoxide ions, and the interaction between the two generates hydroxyl radicals and microbubbles with high oxidizing ability and long-lasting oxidation, thereby effectively remediating soil and groundwater polluted by total petroleum hydrocarbons.

Electrolytic liquid generation device includes stacked body in which conductive membrane is interposed between cathode and anode constituting electrodes, electrolytic part that electrolyzes a liquid, and housing in which electrolytic part is disposed. Housing includes flow path in which a liquid flowing direction intersects a stacking direction of stacked body. Electrolytic part includes slot open to flow path in which a part of interface between conductive membrane and the electrode is exposed. In housing, positioning member is disposed, and positioning member positions the electrode. This configuration provides electrolytic liquid generation device in which an electrode can be downsized and the electrode can be positioned in housing.

An easily adaptable or do-it-yourself (DIY) installation water cleaning device on any existing spa or pool is provided herein. The cleaning device includes an electrolysis module equipped with a particular boron-doped diamond electrode on silicum substrate. The foregoing also relates to a method to clean water on spa or pools using a water cleaning device that includes particular boron-doped diamond electrode present on the elecrolysis module. The foregoing also relates to electrolyzed bathing water for use in the treatment of inflammatory diseases of the skin and for use for use in the treatment of wound healing of the skin.

Disclosed is a method of treating a clinical analyser wastewater stream containing a first concentration of azide ions in solution, comprising at least the step of passing the clinical analyser wastewater stream through an anodic oxidation chamber having one or more anodic oxidation cells to provide a post-chamber treated water stream, said treated water stream having a second concentration of azide ions in solution that is less than the first concentration of azide ions in solution. A clinical analyser treatment apparatus comprising an anodic oxidation chamber having one or more anodic oxidation cells able to reduce a concentration of azide ions is also disclosed.

Disclosed herein is a wastewater treatment reactor that makes use of activated carbon as the adsorbent. The wastewater treatment reaction is suitable for use in an electrochemical advanced oxidation process and includes a cathode and anode, where the cathode is arranged to incorporate activate carbon and carbon brushes. Also disclosed herein are methods making use of the reactor for adsorption of contaminants and its regeneration.

Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H.sub.2O.sub.2 and .OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe.sup.3+ and 5 to 15% wt. Cu.sup.2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H.sub.2O.sub.2 to .OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.