An optical coating for a glass substrate includes an inner metal or metal alloy layer, a first pair of transparent conductive oxide or dielectric layers, and a pair of outer metal or metal alloy layers. The optical coating includes an eye-weighted transmittance of less than about 20% and an eye-weighted reflectance of less than about 30%, as measured with a D65 illuminant according to the CIE 10° Standard Observer.

A composite pane includes an outer pane, an inner pane, and a thermoplastic intermediate layer. The composite pane has, between the outer and inner panes, a solar protection coating that substantially reflects or absorbs rays outside the visible spectrum of solar radiation. The solar protection coating includes starting from the outer pane, a layer sequence of first dielectric module (M1), first silver layer (Ag1), second dielectric module (M2), second silver layer (Ag2), third dielectric module (M3), third dielectric module (M3), third silver layer (Ag3), fourth dielectric module (M4), wherein the silver layers (Ag1, Ag2, Ag3) have a layer thickness relative to one another of Ag1/Ag2>1 and Ag1/Ag3>1, and the dielectric modules (M1, M2, M3, M4) have a relative layer thickness of M2/M1>1, M2/M3>1, and M2/M4>1.

Multilayer metallo-dielectric energy control coatings are disclosed in which one or more layers are formed from a hydrogenated metal nitride dielectric, which may be hydrogenated during or after dielectric deposition. Properties of the multilayer coating may be configured by appropriately tuning the hydrogen concentration (and/or the spatial profile thereof) in one or more hydrogenated metal nitride dielectric layers. One or more metal layers of the multilayer coating may be formed on a hydrogenated nitride dielectric layer, thereby facilitating adhesion of the metal with a low percolation threshold and enabling the formation of thin metal layers that exhibit substantial transparency in the visible spectrum. Optical properties of the coating may be tuned through modulation of metal-dielectric interface roughness and dispersion of metal nanoparticles in the dielectric layer. Electrical busbars and micro-nano electrical grids may be integrated with one or more metal layers to provide functionality such as de-icing and defogging.

Multilayer metallo-dielectric energy control coatings are disclosed in which one or more layers are formed from a hydrogenated metal nitride dielectric, which may be hydrogenated during or after dielectric deposition. Properties of the multilayer coating may be configured by appropriately tuning the hydrogen concentration (and/or the spatial profile thereof) in one or more hydrogenated metal nitride dielectric layers. One or more metal layers of the multilayer coating may be formed on a hydrogenated nitride dielectric layer, thereby facilitating adhesion of the metal with a low percolation threshold and enabling the formation of thin metal layers that exhibit substantial transparency in the visible spectrum. Optical properties of the coating may be tuned through modulation of metal-dielectric interface roughness and dispersion of metal nanoparticles in the dielectric layer. Electrical busbars and micro-nano electrical grids may be integrated with one or more metal layers to provide functionality such as de-icing and defogging.

A material includes a transparent substrate coated with a stack of thin layers acting on infrared radiation including at least one functional layer. The stack includes a protective coating deposited above at least a part of the functional layer. The protective coating includes at least one lower protective layer based on titanium and zirconium, these two metals being in the metal, oxidized or nitrided form, and at least one upper protective layer of carbon, within which layer the carbon atoms are essentially in an sp.sup.2 hybridization state, located above the layer based on titanium and zirconium.

A transparent substrate includes a stack of thin layers successively including, starting from the substrate, an alternation of three metallic functional layers, in particular of functional layers based on silver or on silver-comprising metal alloy, and of four antireflective coatings, each antireflective coating including at least one dielectric layer, so that each metallic functional layer is positioned between two antireflective coatings, wherein: the thicknesses of the metallic functional layers, starting from the substrate, increase as a function of the distance from the substrate, the second metallic functional layer is directly in contact with a blocking layer, referred to as second blocking layer, chosen from a blocking underlayer and a blocking overlayer, respectively referred to as second blocking underlayer and second blocking overlayer, the second blocking underlayer and/or the second blocking overlayer exhibits a thickness of greater than 1 nm.

Provided is a radiative cooling device that provides coloration of the radiative surface while maximally avoiding reduction in its radiative cooling performance due to absorption of solar light. An infrared radiative layer for radiating infrared light from a radiative surface and a light reflective layer disposed on the side opposite to the presence side of the radiative surface of the infrared radiative layer are provided in a mutually stacked state. The light reflective layer is arranged such that a first metal layer made of silver or silver alloy and having a thickness equal to or greater than 10 nm and equal to or less than 100 nm, a transparent dielectric layer and a second metal layer reflecting light transmitted through the first metal layer and the transparent dielectric layer are stacked in this order on the side closer to the infrared radiative layer. The transparent dielectric layer has a thickness that causes a resonance wavelength of the light reflective layer to be a wavelength included in wavelengths equal to or greater than 400 nm and equal to or less than 800 nm.

There is provided a multilayer coating comprising a plurality of layers comprising a) one or more layers of an elemental transition metal; b) one or more layers of an elemental metalloid; and c) two or more layers of an oxide; characterized in that the transition metal and metalloid layers are between the oxide layers and the plurality of layers does not need to contain an additional transparent conductive film (TCF). The multilayer coatings show high transparency in the visible light range combined with heat shielding without the need of transparent conductive oxide which have been previously used to achieve these properties. The multilayers can be produced with conventional physical vapor deposition methods on glass and polymer substrates. The coatings may therefore be used for applications on windows, plastic sheets and window shields. The invention relates also to the process for making the multilayer coatings, articles comprising them and their use in building and other applications.

The invention relates to a technique of manufacturing a coated substrate (102) such as glass (104) carrying a conductive layer (112) such as a metal layer to be tempered after deposition. A system (100) for manufacturing the coated substrate (102) may comprise a sputtering configuration (120) adapted for depositing the conductive layer (112) on the substrate (104). A pulse laser (132) is adapted for irradiating the conductive layer (112) with laser pulses (136). The pulse laser (132) is adapted for laser pulses (136) with a pulse duration below one microsecond.

Certain example embodiments relate to a coated article including at least one infrared (IR) reflecting layer of a material such as silver or the like in a low-E coating, and methods of making the same. In certain cases, at least one layer of the coating is of or includes nickel and/or titanium (e.g., Ni.sub.xTi.sub.yO.sub.z). The provision of a layer including nickel titanium and/or an oxide thereof may permit a layer to be used that has good adhesion to the IR reflecting layer, and reduced absorption of visible light (resulting in a coated article with a higher visible transmission). When a layer including nickel titanium oxide is provided directly over and/or under the IR reflecting layer (e.g., as a barrier layer), this may result in improved chemical and mechanical durability. Thus, visible transmission may be improved if desired, without compromising durability; or, durability may simply be increased.