Embodiments of methods for forming strengthened glass articles comprise providing an exchangeable glass substrate having a coefficient of thermal expansion (CTE) between about 60×10−7°/C. to about 110×10−7°/C., depositing at least one decorative porous inorganic layer onto at least a portion of the surface of the glass substrate, wherein the decorative porous inorganic layer comprises a glass transition temperature (Tg)≥450° C., a glass softening temperature (Ts)≥650° C., wherein the difference in CTE values between the glass substrate and the decorative porous inorganic layer is within 10×10−7°/C.; and curing the glass substrate and the deposited decorative porous inorganic layer at a temperature greater than the Ts of the decorative porous inorganic layer; and chemically strengthening the cured glass substrate and the decorative porous inorganic layer thereon via ion exchange at a temperature below the Tg of the decorative porous inorganic layer.

Embodiments of methods for forming strengthened glass articles comprise providing an exchangeable glass substrate having a coefficient of thermal expansion (CTE) between about 60×10−7°/C. to about 110×10−7°/C., depositing at least one decorative porous inorganic layer onto at least a portion of the surface of the glass substrate, wherein the decorative porous inorganic layer comprises a glass transition temperature (Tg)≥450° C., a glass softening temperature (Ts)≥650° C., wherein the difference in CTE values between the glass substrate and the decorative porous inorganic layer is within 10×10−7°/C.; and curing the glass substrate and the deposited decorative porous inorganic layer at a temperature greater than the Ts of the decorative porous inorganic layer; and chemically strengthening the cured glass substrate and the decorative porous inorganic layer thereon via ion exchange at a temperature below the Tg of the decorative porous inorganic layer.

Provided is a near infrared absorbing glass excellent in each of weather resistance, resistance to denitrification, and optical properties even if not containing fluorine. A near infrared absorbing glass containing, in % by mass, 25 to 60% P.sub.2O.sub.5, 2 to 19% Al.sub.2O.sub.3, 10 to 45% RO (where R is at least one selected from Mg, Ca, Sr, and Ba), 0 to 13% ZnO, 12% to 20% (exclusive of 12% and 20%) K.sub.2O, 0 to 12% Na.sub.2O, and 0.3 to 20% CuO.

Provided is a near infrared absorbing glass excellent in each of weather resistance, resistance to denitrification, and optical properties even if not containing fluorine. A near infrared absorbing glass containing, in % by mass, 25 to 60% P.sub.2O.sub.5, 2 to 19% Al.sub.2O.sub.3, 10 to 45% RO (where R is at least one selected from Mg, Ca, Sr, and Ba), 0 to 13% ZnO, 12% to 20% (exclusive of 12% and 20%) K.sub.2O, 0 to 12% Na.sub.2O, and 0.3 to 20% CuO.

A glass includes from 42 mol % to 47 mol % P.sub.2O.sub.5, from 42 mol % to 48 mol % CuO, and from greater than 0 mol % to 15 mol % Fe.sub.2O.sub.3. The glass is an amorphous, single-phase glass. Methods of making a glass article include heating batch materials to a melting temperature from 900° C. to 1350° C. In aspects, methods include pouring the molten glass in an inert gaseous environment, and cooling the molten glass in the inter gaseous environment. In aspects, methods include cooling the molten glass to form the glass article and annealing the glass article without growing crystals in or on the glass article during the cooling or the annealing.

The near-infrared absorbing glass contains at least, as constituent ions, P ions; Cu ions; O ions; one or more ions selected from the group consisting of Li ions, Na ions and K ions; and one or more ions selected from the group consisting of Mg ions, Ca ions, Sr ions and Ba ions, wherein, in a glass composition expressed in cation %, the content of Cu ions is 15.0 cation % or lower; the content of P ions is 55.0 cation % or lower; and a cation ratio of the total content of Al ions and P ions relative to the total content of Mg ions, Ca ions, Sr ions, Ba ions, Zn ions and Cu ions ((Al ions+P ions)/(Mg ions+Ca ions+Sr ions+Ba ions+Zn ions+Cu ions)) is 5.300 or lower.

The near-infrared absorbing glass contains at least, as constituent ions, P ions; Cu ions; O ions; one or more ions selected from the group consisting of Li ions, Na ions and K ions; and one or more ions selected from the group consisting of Mg ions, Ca ions, Sr ions and Ba ions, wherein, in a glass composition expressed in cation %, the content of Cu ions is 15.0 cation % or lower; the content of P ions is 55.0 cation % or lower; and a cation ratio of the total content of Al ions and P ions relative to the total content of Mg ions, Ca ions, Sr ions, Ba ions, Zn ions and Cu ions ((Al ions+P ions)/(Mg ions+Ca ions+Sr ions+Ba ions+Zn ions+Cu ions)) is 5.300 or lower.

A metallic laminate shaped flow path member has both a surface roughness of a flow path inner surface and corrosion resistance at such a level as to be utilizable as a flow path member for use in a supply line for a corrosive fluid in a semiconductor device manufacturing apparatus. A metallic substrate constituting the metallic laminate shaped flow path member has surface irregularities, the inner surface of the flow path of the metallic laminate shaped flow path member is formed with a glass coating layer in such a manner as to fill at least recessed regions of the surface irregularities of the metallic substrate, and the glass coating layer includes at least one of a layer of a P.sub.2O.sub.5—ZnO—Al.sub.2O.sub.3 based glass, a layer of a Bi.sub.2O.sub.3—ZnO—B.sub.2O.sub.3 based glass, and a layer of an SiO.sub.2—B.sub.2O.sub.3—Na.sub.2O based glass.

A glass powder composite includes a first glass powder, and a second glass powder having a different solubility from that of the first glass powder depending on pH, wherein both the first glass powder and the second glass powder have ion sustained-release properties.

A borophosphate glass composition including B.sub.2O.sub.3, P.sub.2O.sub.5, and CaO, and optionally a source additive selected from: Li.sub.2O, Na.sub.2O, K.sub.2O, Al.sub.2O.sub.3, ZnO, MgO, Fe.sub.2O.sub.3/FeO, CuO/Cu.sub.2O, and mixtures thereof, as defined herein. Also disclosed are bioactive compositions or substrates including the disclosed borophosphate glass composition, and at least one live cell. Also disclosed are methods of inhibiting or increasing the relative amount of species containing boron, phosphorous, or both, being released into an aqueous solution from aborophosphate glass composition defined herein. Also disclosed is a method of proliferating cells on a bioactive substrate as defined herein. Also disclosed are related glass compositions that exclude one of B.sub.2O.sub.3, P.sub.2O.sub.5, and CaO.