The present invention belongs to the technical field of metallurgical solid waste resource utilization, and particularly relates to acidification and carbonization coupling modified steel slag as well as a preparation process and an application thereof. The process specifically includes the following steps of adopting acetic acid, tributyl phosphate, ethanolamine and a NaOH and Ca(OH).sub.2 emulsion as reaction reinforcing agents, and modifying the steel slag together with CO.sub.2-rich lime kiln flue gas. The process for modifying the steel slag through acidification and carbonization coupling provided in the present invention has the advantages of simple reaction conditions and no need of high-pressure CO.sub.2, additionally, the carbonation reaction rate can be greatly increased, and f-CaO and f-MgO in the steel slag can be effectively eliminated.

The present invention belongs to the technical field of metallurgical solid waste resource utilization, and particularly relates to acidification and carbonization coupling modified steel slag as well as a preparation process and an application thereof. The process specifically includes the following steps of adopting acetic acid, tributyl phosphate, ethanolamine and a NaOH and Ca(OH).sub.2 emulsion as reaction reinforcing agents, and modifying the steel slag together with CO.sub.2-rich lime kiln flue gas. The process for modifying the steel slag through acidification and carbonization coupling provided in the present invention has the advantages of simple reaction conditions and no need of high-pressure CO.sub.2, additionally, the carbonation reaction rate can be greatly increased, and f-CaO and f-MgO in the steel slag can be effectively eliminated.

A method of making building materials from an aqueous solution includes receiving the aqueous solution with dissolved ions and increasing a pH of the aqueous solution so the dissolved ions precipitate from the aqueous solution as salt. The method also includes collecting the salt precipitated from the aqueous solution and forming the building materials from the salt.

A process for producing fly ash in a fluidized bed boiler includes combusting a fuel in a fluidized bed combustor in the presence of limestone particles, recovering fly ash, and recovering bottom ash. The fuel contains hydrocarbons and sulfur. A majority of the sulfur from the fuel is recovered from the bottom ash. The fly ash may contain less than 5% by weight of sulfur oxides. This may be achieved by using limestone particles having certain properties and/or narrowing an inlet from the boiler into a cyclone.

A method of making building materials includes precipitating calcium salts from an aqueous solution by increasing a pH of the aqueous solution, and mixing the calcium salts with a first material including silicon to form a mixture. The mixture is then heated to form cement clinker.

The cement clinker production system includes: a first supplying section configured to supply a sulfur source and a fluorine source of mineralizer; a second supplying device configured to supply clinker raw material; a crusher configured to crush the mixed raw material obtained by mixing the clinker raw material with the fluorine source of the mineralizer; a kiln configured to burn the crushed mixed raw material; an introducing section configured to introduce the sulfur source of the mineralizer to the kiln; a third supplying section configured to supply fuel to the kiln; and a test sample-analyzing system configured to collect each of the mixed raw material before the burning and the clinker after the burning and to measure amounts of the fluorine, main components and free lime depending on the type collected.

The cement clinker production system includes: a first supplying section configured to supply a sulfur source and a fluorine source of mineralizer; a second supplying device configured to supply clinker raw material; a crusher configured to crush the mixed raw material obtained by mixing the clinker raw material with the fluorine source of the mineralizer; a kiln configured to burn the crushed mixed raw material; an introducing section configured to introduce the sulfur source of the mineralizer to the kiln; a third supplying section configured to supply fuel to the kiln; and a test sample-analyzing system configured to collect each of the mixed raw material before the burning and the clinker after the burning and to measure amounts of the fluorine, main components and free lime depending on the type collected.

A method of making building materials from an aqueous solution includes receiving the aqueous solution with dissolved ions and increasing a pH of the aqueous solution so the dissolved ions precipitate from the aqueous solution as salt. The method also includes collecting the salt precipitated from the aqueous solution and forming the building materials from the salt.

A cement clinker composition incorporates calcium fluoride and iron oxide to reduce firing temperatures and increase strength. High fly ash, aluminum dross, aluminum scrap, high aluminum clays and combinations thereof may also be substituted for bauxite in the cement clinker composition

The invention comprises a method of making lime, dolomitic lime, hydraulic cement such as portland cement clinker and co-products such as pozzolan, acids, alumina, silica and the like while producing reduced amounts of carbon dioxide. The method comprises combining hyaloclastite with a first acid to form a first salt, combining the first salt with a second acid to form a second salt and heating the second salt to form an oxide.