The present invention relates to an integrated process for the manufacture of methylchlorohydridomonosilanes in particular, from products of the Müller-Rochow Direct Process.

A method of producing a halosiloxane, the method comprising: combining water, a halosilane, and a first solvent, where the first solvent has a water solubility of >1.5 grams in 100 ml of solvent, to form a reaction mixture having a temperature above the melting point temperature of the solvent, partially hydrolyzing and condensing the halosilane to form a reaction product mixture comprising the halosiloxane, the solvent, a hydrogen halide and unreacted halosilane, and, optionally, adding a second solvent with a boiling point≥the boiling point of the halosiloxane to the reaction mixture or the reaction product mixture.

The invention relates to halogenated tetrasilylboranates of the general formula

M.sup.z+[B(SiR.sub.mX.sub.n).sub.4.sup.−].sub.z  (I),

where the radicals and indices have the meanings indicated in claim 1, with the proviso that m+n=3,
processes for the production thereof and also the use.

Described are compounds of the structure R4—.sub.a—Si—(Sp-Y).sub.a—Z.sub.b, wherein “a” is integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”“R” or formula (II), wherein each “R” is halogen, C.sub.1-6 linear or branched alkyl, alkenyl, or alkynyl or C.sub.1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C.sub.1-15 linear or branched alkylenyl or CMS linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Preparation of sulfur fine chemicals from sulfur sources is described.

A method for preparing a reaction product including an aryl-functional silane includes sequential steps (1) and (2). Step (1) is contacting, under silicon deposition conditions, (A) an ingredient including (I) a halosilane such as silicon tetrahalide and optionally (II) hydrogen (H.sub.2); and (B) a metal combination comprising copper (Cu) and at least one other metal, where the at least one other metal is selected from the group consisting of gold (Au), cobalt (Co), chromium (Cr), iron (Fe), magnesium (Mg), manganese (Mn), nickel (Ni), palladium (Pd), and silver (Ag); thereby forming a silicon alloy catalyst comprising Si, Cu and the at least one other metal. Step (2) is contacting the silicon alloy catalyst and (C) a reactant including an aryl halide under silicon etching conditions.

Disclosed herein are chlorodisazanes; silicon-heteroatom compounds synthesized therefrom; devices containing the silicon-heteroatom compounds; methods of making the chlorodisilazanes, the silicon-heteroatom compounds, and the devices; and uses of the chlorodisilazanes, silicon-heteroatom compounds, and devices.

Described are compounds of the structure R.sub.4-a—Si-((Sp-Y)—Z.sub.b).sub.a, wherein “a” is an integer from 1 to 3; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”=0, is halogen, C.sub.1-6 linear or branched alkyl, alkenyl, or alkynyl, C.sub.1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl, or

##STR00001##

wherein each “R” is halogen, C.sub.1-6 linear or branched alkyl, alkenyl, or alkynyl or C.sub.1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C.sub.1-15 linear or branched alkylenyl or C.sub.1-15 linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Described are compounds of the structure R.sub.4-a—Si-(Sp-Y).sub.a—Z.sub.b, wherein “a” is an integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”=0, is “R” or ##STR00001##
wherein each “R” is halogen, C.sub.1-6 linear or branched alkyl, alkenyl, or alkynyl or C.sub.1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C.sub.1-15 linear or branched alkylenyl or C.sub.1-15 linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

The invention relates to a process for the manufacture of organomonosilanes, in particular, bearing both hydrogen and chlorine substituents at the silicon atom by subjecting a silane substrate comprising one or more organomonosilanes, with the proviso that at least one of these silanes has at least one chlorine substituent at the silicon atom, to the reaction with one or more metal hydrides selected from the group of an alkali metal hydride and an alkaline earth metal hydride in the presence of one or more compounds (C) acting as a redistribution catalyst.