Disclosed are a method and device for preventing carbon deposition in a fluidized bed reactor for the organosilicon monomer synthesis. The device includes a tank, at least one U-shaped heat exchange tube, and at least one upper flow-guide block. The U-shaped heat exchange tube includes an elbow portion, and is arranged vertically with the elbow portion at a lower end. The upper flow-guide block is arranged on an upper surface of the elbow portion. A width of the upper flow-guide block decreases from an end connected to the elbow portion to an end away from the elbow portion.

Disclosed are a method and device for preventing carbon deposition in a fluidized bed reactor for the organosilicon monomer synthesis. The device includes a tank, at least one U-shaped heat exchange tube, and at least one upper flow-guide block. The U-shaped heat exchange tube includes an elbow portion, and is arranged vertically with the elbow portion at a lower end. The upper flow-guide block is arranged on an upper surface of the elbow portion. A width of the upper flow-guide block decreases from an end connected to the elbow portion to an end away from the elbow portion.

Disclosed is a combined process for preparing zirconium oxide, methyl chlorosilane and/or polycrystalline silicon and a combined system comprising: preparing zirconium oxide by using zircon sand, carbon, chlorine gas, silicon, and hydrogen chloride as raw materials, the products separated during preparing zirconium oxide include gas phase products and liquid phase products, methyl chlorosilane is prepared from the gas phase separated during preparing zirconium oxide, and polycrystalline silicon is prepared by using the liquid phase products as raw materials. In this invention, not only carbon monoxide, hydrogen chloride and other waste gases generated are used as raw materials for producing methyl chlorosilane, but also a by-product silicon tetrachloride generated is used as a raw material for producing polycrystalline silicon, thereby effectively recycling waste gases and silicon tetrachloride, reducing the treatment cost of waste gases and silicon tetrachloride and the production cost of methyl chlorosilane and polycrystalline silicon, and avoiding environmental pollution.

Disclosed is a combined process for preparing zirconium oxide, methyl chlorosilane and/or polycrystalline silicon and a combined system comprising: preparing zirconium oxide by using zircon sand, carbon, chlorine gas, silicon, and hydrogen chloride as raw materials, the products separated during preparing zirconium oxide include gas phase products and liquid phase products, methyl chlorosilane is prepared from the gas phase separated during preparing zirconium oxide, and polycrystalline silicon is prepared by using the liquid phase products as raw materials. In this invention, not only carbon monoxide, hydrogen chloride and other waste gases generated are used as raw materials for producing methyl chlorosilane, but also a by-product silicon tetrachloride generated is used as a raw material for producing polycrystalline silicon, thereby effectively recycling waste gases and silicon tetrachloride, reducing the treatment cost of waste gases and silicon tetrachloride and the production cost of methyl chlorosilane and polycrystalline silicon, and avoiding environmental pollution.

The invention relates to halogenated tetrasilylboranates of the general formula

M.sup.z+[B(SiR.sub.mX.sub.n).sub.4.sup.−].sub.z  (I),

where the radicals and indices have the meanings indicated in claim 1, with the proviso that m+n=3,
processes for the production thereof and also the use.

The invention relates to halogenated tetrasilylboranates of the general formula

M.sup.z+[B(SiR.sub.mX.sub.n).sub.4.sup.−].sub.z  (I),

where the radicals and indices have the meanings indicated in claim 1, with the proviso that m+n=3,
processes for the production thereof and also the use.

Methylchlorosilanes are synthesized by an at least two stage reaction in which contact composition from a first fluidized bed reactor is fed to a second fluidized bed reactor.

Methylchlorosilanes are synthesized by an at least two stage reaction in which contact composition from a first fluidized bed reactor is fed to a second fluidized bed reactor.

A process for preparing a product including a monohydrogentrihalosilane is disclosed. The process includes the steps of: 1) initially charging a reactor with a contact mass including both fresh silicon and recycled contact mass, where the recycled contact mass is obtained from during or after a production phase of an inorganic Direct Process reaction for production of a monohydrogentrihalosilane; and thereafter 2) feeding to the reactor a hydrogen halide and additional fresh silicon, thereby forming the product.

A process for preparing a reaction product including a halosilane includes: contacting an unsaturated hydrocarbyl halide and a ternary intermetallic compound at a temperature of 300° C. to 700° C. to form the reaction product. The ternary intermetallic compound includes copper, silicon and a transition metal. The halosilane in the reaction product has formula R1.sub.mR.sup.2.sub.n—H.sub.oSiX.sub.(4-m-n-o)> where each R.sup.1 is independently a saturated monovalent hydrocarbyl group, each R.sup.2 is independently an unsaturated monovalent hydrocarbyl group; each X is independently a halogen atom; subscript m is 1, 2, or 3; subscript n is 0, 1, or 2; subscript o is 0, 1, or 2; and a quantity (m+n+o) is 1, 2, or 3. At least a portion of the unsaturated hydrocarbyl groups in the unsaturated by drocarbyl halide are converted to saturated hydrocarbyl groups (R.sup.1) in the halosilane.