The present disclosure provides coating compositions and cured products formed from the coating compositions. The cured products can be formed at high cure speeds from the coating compositions and feature low Young's modulus, high tear strength, and/or high tensile toughness. The cured products can be used as primary coatings for optical fibers. The primary coatings provide good microbending performance and are resistant to defect formation during fiber coating processing and handling operations. The coating compositions include an oligomer, an alkoxylated monofunctional acrylate monomer, and preferably, an N-vinyl amide compound.

The present disclosure provides coating compositions and cured products formed from the coating compositions. The cured products can be formed at high cure speeds from the coating compositions and feature low Young's modulus, high tear strength, and/or high tensile toughness. The cured products can be used as primary coatings for optical fibers. The primary coatings provide good microbending performance and are resistant to defect formation during fiber coating processing and handling operations. The coating compositions include an oligomer, an alkoxylated monofunctional acrylate monomer, and preferably, an N-vinyl amide compound.

The present invention provides a polymerizable composition containing a specific polymerizable compound and a fluorosurfactant having a specific polyoxyalkylene skeleton and having specific molecular weight. The invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable composition of the present invention. The present invention is useful because, when an optically anisotropic body is produced by photo-polymerization of the polymerizable composition, three features including the leveling properties of the surface of the optically anisotropic body, offset onto the substrate, and liquid crystal alignment can be improved simultaneously.

The present invention provides a polymerizable composition containing a specific polymerizable compound and a fluorosurfactant having a specific polyoxyalkylene skeleton and having specific molecular weight. The invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable composition of the present invention. The present invention is useful because, when an optically anisotropic body is produced by photo-polymerization of the polymerizable composition, three features including the leveling properties of the surface of the optically anisotropic body, offset onto the substrate, and liquid crystal alignment can be improved simultaneously.

Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.

An ink contains water, a pigment, and a polymer having a structure unit represented by the following Chemical structure 1, ##STR00001## where R.sub.1 represents an organic group having at least carbon and oxygen.

Fluorinated coupling agents and polymerizable compositions including such fluorinated coupling agents and at least one free-radically polymerizable monomer, oligomer, or mixture thereof. Multilayer films including a substrate and at least a first layer overlaying a surface of the substrate also are described, in which the at least first layer includes a (co)polymer obtained by polymerizing the foregoing polymerizable compositions. Processes for making a multilayer film using the polymerizable composition also are taught. Articles including the multilayer film also are disclosed, in which the article preferably is selected from a photovoltaic device, a display device, a solid-state lighting device, a sensor, a medical or biological diagnostic device, an electrochromic device, light control device, or a combination thereof.

The present invention provides a copolymer used as oily gelling agent with which a stable oily gelled composition can be prepared.

The copolymer of the present invention is characterized by comprising a hydrophobic monomer represented by the following general formula (1) and a hydrophilic monomer represented by the following general formula (2) and/or the following general formula (3).

##STR00001##

(In formula (1), R.sup.1 is a straight-chain or branched-chain alkyl group having 16 to 22 carbon atoms. R.sup.2 is a hydrogen atom or a methyl group.)

##STR00002##

(In formula (2), R.sup.3 is a hydrogen atom, a glyceryl group, a straight-chain or branched-chain hydroxyalkyl group having 1 to 4 carbon atoms, or a polypropylene glycol group represented by —(C.sub.3H.sub.6O).sub.nH (here, n is an integer of 2 to 10). R.sup.4 is a hydrogen atom or a methyl group.)

##STR00003##

(In formula (3), R.sup.5 is a hydrogen atom or a methyl group, R.sup.6 is a straight-chain or branched-chain alkyl group or hydroxyalkyl group having 1 to 4 carbon atoms, or a substituent represented by the following structural formula (4).)

##STR00004##

The present invention provides a copolymer used as oily gelling agent with which a stable oily gelled composition can be prepared.

The copolymer of the present invention is characterized by comprising a hydrophobic monomer represented by the following general formula (1) and a hydrophilic monomer represented by the following general formula (2) and/or the following general formula (3).

##STR00001##

(In formula (1), R.sup.1 is a straight-chain or branched-chain alkyl group having 16 to 22 carbon atoms. R.sup.2 is a hydrogen atom or a methyl group.)

##STR00002##

(In formula (2), R.sup.3 is a hydrogen atom, a glyceryl group, a straight-chain or branched-chain hydroxyalkyl group having 1 to 4 carbon atoms, or a polypropylene glycol group represented by —(C.sub.3H.sub.6O).sub.nH (here, n is an integer of 2 to 10). R.sup.4 is a hydrogen atom or a methyl group.)

##STR00003##

(In formula (3), R.sup.5 is a hydrogen atom or a methyl group, R.sup.6 is a straight-chain or branched-chain alkyl group or hydroxyalkyl group having 1 to 4 carbon atoms, or a substituent represented by the following structural formula (4).)

##STR00004##

A process to form a composition comprising an asymmetrical polyene, the asymmetrical polyene comprising an “α,β unsaturated-carbonyl end” and a “C—C double bond end,” the process comprising: reacting an alkene- or polyene-containing alcohol with an alkyl ester of an α,β unsaturated carboxylic acid in the presence of at least the following components A) through C) to form a solution comprising an asymmetrical polyene: A) a lithium salt; B) a component selected from the group consisting of hydroquinone, an alkyl-substituted phenol, a substituted alkyl-substituted phenol, an alkyl-substituted hydroquinone, a substituted alkyl-substituted hydroquinone, and combinations thereof; and C) an N-oxyl-containing compound; wherein the “α,β unsaturated-carbonyl end” of the asymmetrical polyene is selected from the group consisting of structures a) through c), as described herein, and wherein the “C—C double bond end” of the asymmetrical polyene is selected from the group consisting of structures 1) through 17), as described herein.