Patent classifications
C08F299/024
Photocurable resin composition
Provided are a photocurable resin composition that can be suitably used for an optical three-dimensional shaping method, and a cured product obtained by photocuring the composition and a three-dimensional shaped object including the cured product. The photocurable resin composition contains a compound represented by the formula (1) and a compound containing two or more epoxy groups. ##STR00001##
Resin composition and article made therefrom
A resin composition includes: a vinyl-containing polyphenylene ether resin; a compound of Formula (1); and a compound of Formula (2), a compound of Formula (3), a compound of Formula (4) or a combination thereof. The resin composition may be used to make various articles, such as a prepreg, a resin film, a laminate or a printed circuit board, and at least one of the following improvements can be achieved, including prepreg viscosity variation ratio, prepreg stickiness resistance, amount of void after lamination, multi-layer board thermal resistance, glass transition temperature, ratio of thermal expansion, copper foil peeling strength, dissipation factor and laminate appearance.
WOUND DRESSINGS COMPRISING POLYSILOXANE-POLYGLYCEROL BLOCK COPOLYMERS AND METHODS OF MAKING AND USE THEREOF
Described herein are wound dressing comprising a silicone hydrogel composition and optionally an antimicrobial agent, and methods of making and use thereof. The silicone hydrogel compositions comprise an actinically-crosslinkable polysiloxane-polyglycerol block copolymer crosslinked with a crosslinker. The actinically-crosslinkable polysiloxane-polyglycerol block copolymer being derived from: a polysiloxane prepolymer comprising a polyglycerol side chain, the polyglycerol side chain comprising an ethylenically unsaturated group covalently linked thereto, wherein the ethylenically unsaturated group is actinically curable.
Preparation method for polycarboxylate water reducer having regular sequence structure
Disclosed is a preparation method of a polycarboxylate water reducer having a regular sequence structure. The preparation method of the present invention comprises: performing Michael addition on polyethylene glycol ether acrylate macromonomer A and amino-containing carboxylic acid B for 5-12 hours, then cooling to 0° C., dropwise adding acryloyl chloride slowly and evenly, and further reacting for 12 hours at room temperature to obtain carboxyl-containing polyether macromonomer C; mixing the carboxyl-containing polyether macromonomer C, a small molecular RAFT reagent, an initiator, and water adequately; and holding the polymerization mass concentration at 30%-60% and heating to 60-80° C. in the atmosphere of N2 to react for 2-5 hours to obtain the polycarboxylate water reducer having a regular sequence structure.
PREPREG AND MOLDED ARTICLE
Provided is a prepreg containing a urethane (meth)acrylate (A), an ethylenically unsaturated monomer (B), a polymerization initiator (C), and reinforcement fibers (D), characterized in that the urethane (meth)acrylate (A) is a reaction product of a polyisocyanate (a1) and a polyol (a2) having an ethylenically unsaturated group and an aromatic skeleton, and/or a reaction product of a polyisocyanate (a1), a polyol (a3) not having an ethylenically unsaturated group but having an aromatic skeleton, and a hydroxyalkyl (meth)acrylate (a4), and that the ethylenically unsaturated monomer (B) has a molecular weight of 320 or more and a weight reduction rate (%) of less than 2 when heated under atmospheric pressure at 150° C. for 3 minutes. The prepreg has excellent moldability and enables to produce a molded article having excellent physical properties such as flexural strength and interlaminar shear strength, and therefore the prepreg can be suitably used in automobile components and the like.
ELECTROCHEMICAL DEVICE, ELECTRODE FOR ELECTROCHEMICAL DEVICES, COATING LIQUID FOR ELECTROCHEMICAL DEVICES, AND USE OF SAME
An electrochemical device, which is a non-aqueous electrochemical device, comprising a polymer (P) enclosed in an inside of the electrochemical device, wherein the polymer (P) is a polymer having a molecular structure containing a unit (P) represented by the following formula (P), the polymer (P) having a weight-average molecular weight of greater than 50,000, as well as an electrode for an electrochemical device, a coating liquid for an electrochemical device, an insulating layer for an electrochemical device, an undercoat layer for an electrochemical device, and an electrolytic solution for an electrochemical device including the polymer (P) and other ingredients:
##STR00001## in the formula (P), R.sup.P is a group of 1 to 20 carbon atoms.
Electrophotographic photosensitive member, process cartridge, and electrophotographic image forming apparatus
An electrophotographic photosensitive member, which is suppressed in occurrence of fogging and is excellent in abrasion resistance. In the electrophotographic photosensitive member, an outermost surface layer of the electrophotographic photosensitive member comprises a polymerized product of a composition comprising at least a polyrotaxane and a monomer having a polymerizable reactive group, and a chain molecule of the polyrotaxane has two blocking groups at both terminals thereof, and a (meth)acryloyloxy group of a cyclic molecule of the polyrotaxane forms a bond.
NOVEL BLOCK COPOLYMER AND MICELLE COMPOSITIONS AND METHODS OF USE THEREOF
Provided herein are block copolymers comprising a hydrophilic polymer segment and a hydrophobic polymer segment, wherein the hydrophilic polymer segment comprises a polymer selected from the group consisting of: poly(ethylene oxide) (PEO), poly(methacrylate phosphatidyl choline) (MPC), and polyvinylpyrrolidone (PVP), wherein the hydrophobic polymer segment comprises
##STR00001##
wherein R′ is —H or —CH.sub.3, wherein R is —NR.sup.1R.sup.2, wherein R.sup.1 and R.sup.2 are alkyl groups, wherein R.sup.1 and R.sup.2 are the same or different, wherein R.sup.1 and R.sup.2 together have from 5 to 16 carbons, wherein R.sup.1 and R.sup.2 may optionally join to form a ring, wherein n is 1 to about 10, and wherein x is about 20 to about 200 in total. Also provided are pH-sensitive micelle compositions for therapeutic and diagnostic applications.
THERMOFORMING LAMINATE AND METHOD FOR MOLDING LAMINATE
Provided is a thermoforming laminate, etc., having good thermoforming properties as well as excellent chemical resistance and abrasion resistance. Examples of solutions to the problem include a thermoformable laminate, including: (a) a substrate layer containing a thermoplastic resin; (b) a post-cure type hard coat layer containing an active-energy-ray-curable resin having a (meth)acryloyl group, the hard coat layer also containing a polymerization inhibitor; and (c) a protective film, wherein: (a) the substrate layer, (b) the hard coat layer, and (c) the protective film are layered in this order; and the polymerization inhibitor includes at least one among a quinone-based compound, a sulfur-containing compound, and a nitrogen-containing compound.
A CRYSTALLINE RADICAL POLYMERIZABLE COMPOSITION FOR FIXING A MAGNET OF A ROTATING ELECTRIC MACHINE ROTOR CORE, A ROTATING ELECTRIC MACHINE ROTOR CORE USING THE COMPOSITION, AND A METHOD OF MANUFACTURING THE ROTATING ELECTRIC MACHINE ROTOR CORE
An object of the present invention is to provide a crystalline radically polymerizable composition for fixing a magnet of a rotating electric machine rotor core, which is excellent in handleability around room temperature, excellent in fluidity from the injection step to the curing step, and excellent in strength of the cured product.
A crystalline radical polymerizable composition for fixing a magnet of a rotating electric machine rotor core of the present invention is characterized by fixing the magnet inserted in a magnet accommodating portion provided in a rotor core of a rotating electric machine formed of a laminated steel sheet and the laminated steel sheet, wherein the crystalline radical polymerizable composition contains at least a crystalline radical polymerizable compound A, an inorganic filler B, a silane coupling agent C, and a radical polymerization initiator D, wherein the crystalline radical polymerizable compound A is solid at 23° C. and has the property capable of imparting fluidity by heating, wherein the inorganic filler B is contained in an amount of 50 to 90% by mass based on the total amount of the crystalline radical polymerizable composition, and the melt viscosity of the crystalline radical polymerization measured by an enhanced flow tester is 500 Pa.Math.s or more at 90° C. and a shear velocity of 1/s.