The present invention relates to novel (per)fluoropolyether polymers characterized by high molecular weight and high functionality, to a process for their manufacture and to their use as intermediate compounds in the preparation of further polymers.

The present invention relates to novel (per)fluoropolyether polymers characterized by high molecular weight and high functionality, to a process for their manufacture and to their use as intermediate compounds in the preparation of further polymers.

This fluorine-containing ether compound is represented by formula (1) shown below.

R.sup.1—CH.sub.2—R.sup.2—CH.sub.2—R.sup.3  (1)

In formula (1), R.sup.2 is a perfluoropolyether chain represented by a formula (2) shown below. R.sup.1 is a terminal group that is bonded to R.sup.2 via a CH.sub.2 group, and is represented by a formula (3) shown below. R.sup.3 is bonded to R.sup.2 via a CH.sub.2 group, is a terminal group having at least one hydroxyl group, and may be the same as, or different from, R.sup.1.

—(CF.sub.2).sub.p-1—O—((CF.sub.2).sub.pO).sub.q—(CF.sub.2).sub.p-1—  (2)

In formula (2), p represents an integer of 2 to 3, and q indicates the average polymerization degree and is a number within a range from 1 to 20.

—O(CH.sub.2—CH(OH)—CH.sub.2—O).sub.2—CH.sub.2—(CH.sub.2).sub.n,—OH  (3)

In formula (3), n represents an integer of 1 to 8.

The invention relates to epoxide-amine adducts obtainable by reaction of one or more primary amines (A) of general formula (I)
Q-NH.sub.2  (I)
with one or more monoepoxides (B) of general formula (II) ##STR00001##
wherein Q is a radical R.sup.t-[OEt].sub.n[OPr].sub.m[OBu].sub.s-, in which R.sup.t is a radical selected from alkyl radicals having 1 to 6 carbon atoms, OEt is an ethylene oxide radical, OPr is a propylene oxide radical and OBu is a butylene oxide radical, n is a number from 0 to 100, m is a number from 3 to 50 and s is a number from 0 to 20 and n+m+s=3 to 170, R is an organic radical selected from aliphatic radicals having 4 to 24 carbon atoms, aromatic radicals having 6 to 18 carbon atoms and araliphatic radicals having 7 to 34 carbon atoms, and p is 0 or 1, wherein (i) the primary amine(s) (A) and the monoepoxide(s) (B) are reacted in an equivalents ratio (A):(B) of from 1:2 to 1:1.35; and (ii) at least 40 mol % of the radicals R are selected from aromatic radicals having 6 to 18 carbon atoms and araliphatic radicals having 7 to 24 carbon atoms; and optionally subsequent salification and/or quaternization and/or modification of the reaction product. The invention furthermore relates to wetting agents and dispersants comprising or consisting of the epoxide-amine adducts and also to the production of the wetting agents and dispersants and to the use of the epoxide-amine adducts and the wetting agents and dispersants for the production of dispersions. The invention also relates to dispersions and particle formulations comprising the epoxide-amine adducts and wetting agents and dispersants.

The invention relates to epoxide-amine adducts obtainable by reaction of one or more primary amines (A) of general formula (I)
Q-NH.sub.2  (I)
with one or more monoepoxides (B) of general formula (II) ##STR00001##
wherein Q is a radical R.sup.t-[OEt].sub.n[OPr].sub.m[OBu].sub.s-, in which R.sup.t is a radical selected from alkyl radicals having 1 to 6 carbon atoms, OEt is an ethylene oxide radical, OPr is a propylene oxide radical and OBu is a butylene oxide radical, n is a number from 0 to 100, m is a number from 3 to 50 and s is a number from 0 to 20 and n+m+s=3 to 170, R is an organic radical selected from aliphatic radicals having 4 to 24 carbon atoms, aromatic radicals having 6 to 18 carbon atoms and araliphatic radicals having 7 to 34 carbon atoms, and p is 0 or 1, wherein (i) the primary amine(s) (A) and the monoepoxide(s) (B) are reacted in an equivalents ratio (A):(B) of from 1:2 to 1:1.35; and (ii) at least 40 mol % of the radicals R are selected from aromatic radicals having 6 to 18 carbon atoms and araliphatic radicals having 7 to 24 carbon atoms; and optionally subsequent salification and/or quaternization and/or modification of the reaction product. The invention furthermore relates to wetting agents and dispersants comprising or consisting of the epoxide-amine adducts and also to the production of the wetting agents and dispersants and to the use of the epoxide-amine adducts and the wetting agents and dispersants for the production of dispersions. The invention also relates to dispersions and particle formulations comprising the epoxide-amine adducts and wetting agents and dispersants.

The present invention relates to novel (per)fluoropolyether (PFPE) polymer derivatives, a method for their manufacture and their use for providing an anti-soiling coating.

The present invention relates to novel (per)fluoropolyether (PFPE) polymer derivatives, a method for their manufacture and their use for providing an anti-soiling coating.

A storage stable aqueous coating composition comprising a novel combination of an anionic acrylic polymer with a small amount of a specific acetoacetamide functional compound and providing coating films made therefrom with formaldehyde abatement property, yellowing resistance, and scrub resistance.

A hydrophilic polymer derivative having a cyclic benzylidene acetal linker represented by the following formula (1): ##STR00001##
wherein R.sup.1 and R.sup.6 are each independently a hydrogen atom or a hydrocarbon group; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently an electron-withdrawing or electron-donating substituent or a hydrogen atom; X.sup.1 is a chemically reactive functional group; P is a hydrophilic polymer; s is 1 or 2, t is 0 or 1, and s+t is 1 or 2; w is an integer of 1 to 8; and Z.sup.1 and Z.sup.2 are each independently a selected divalent spacer.

Provided are a magnetic disk and, in particular, a compound which makes it possible to realize a lubricant having excellent heat resistance and solubility in a fluorine-based solvent. A perfluoropolyether compound in accordance with an aspect of the present invention has, in hydrocarbon groups at both terminals thereof, five or six hydroxyl groups in total.