The object of the present invention is to provide a moisture-curable hot melt adhesive having high initial adhesive strength, long open time, excellent coating property and reduced stringing property. The present invention relates to a moisture-curable hot melt adhesive comprising (A) a urethane prepolymer having a terminal isocyanate group, (B) a metallocene-based polyolefin having a viscosity of 10,000 mPa.Math.s or less at a temperature of 170° C. and (C) a polyester-polyether copolymer.

The object of the present invention is to provide a moisture-curable hot melt adhesive having high initial adhesive strength, long open time, excellent coating property and reduced stringing property. The present invention relates to a moisture-curable hot melt adhesive comprising (A) a urethane prepolymer having a terminal isocyanate group, (B) a metallocene-based polyolefin having a viscosity of 10,000 mPa.Math.s or less at a temperature of 170° C. and (C) a polyester-polyether copolymer.

The object of the present invention is to provide a moisture-curable hot melt adhesive having high initial adhesive strength, long open time, excellent coating property and reduced stringing property. The present invention relates to a moisture-curable hot melt adhesive comprising (A) a urethane prepolymer having a terminal isocyanate group, (B) a metallocene-based polyolefin having a viscosity of 10,000 mPa.Math.s or less at a temperature of 170° C. and (C) a polyester-polyether copolymer.

A hot-melt composition includes, with respect to 100 parts by mass of (A) a hydrogenated styrene thermoplastic elastomer having styrene-based polymer blocks at both ends and a hydrogenated diene polymer block at a middle portion and having a mass-average molecular weight of 250,000-600,000, 20-150 parts by mass of (B) a first styrene-based tackifying resin having a softening point of 135-160° C., 100-400 parts by mass of (C) a second styrene-based tackifying resin having a softening point of 105-135° C., 100-500 parts by mass of (D) a third tackifying resin for the hydrogenated diene polymer block having a softening point of 100-160° C. and 500-1,500 parts by mass of (E) a liquid softener. The hot-melt composition has excellent adhesion and easy peel ability, and is a material suitable as a sealing material for a lighting device of an automobile or the like.

A hot-melt composition includes, with respect to 100 parts by mass of (A) a hydrogenated styrene thermoplastic elastomer having styrene-based polymer blocks at both ends and a hydrogenated diene polymer block at a middle portion and having a mass-average molecular weight of 250,000-600,000, 20-150 parts by mass of (B) a first styrene-based tackifying resin having a softening point of 135-160° C., 100-400 parts by mass of (C) a second styrene-based tackifying resin having a softening point of 105-135° C., 100-500 parts by mass of (D) a third tackifying resin for the hydrogenated diene polymer block having a softening point of 100-160° C. and 500-1,500 parts by mass of (E) a liquid softener. The hot-melt composition has excellent adhesion and easy peel ability, and is a material suitable as a sealing material for a lighting device of an automobile or the like.

A hot-melt composition includes, with respect to 100 parts by mass of (A) a hydrogenated styrene thermoplastic elastomer having styrene-based polymer blocks at both ends and a hydrogenated diene polymer block at a middle portion and having a mass-average molecular weight of 250,000-600,000, 20-150 parts by mass of (B) a first styrene-based tackifying resin having a softening point of 135-160° C., 100-400 parts by mass of (C) a second styrene-based tackifying resin having a softening point of 105-135° C., 100-500 parts by mass of (D) a third tackifying resin for the hydrogenated diene polymer block having a softening point of 100-160° C. and 500-1,500 parts by mass of (E) a liquid softener. The hot-melt composition has excellent adhesion and easy peel ability, and is a material suitable as a sealing material for a lighting device of an automobile or the like.

A tackifier (B) according to the present invention comprises a copolymer (C) that comprises a structural unit derived from α-methylstyrene or isopropenyltoluene and a structural unit derived from styrene, and the copolymer (C) satisfies the following (i) to (iii): (i) a content of the structural unit derived from α-methylstyrene or isopropenyltoluene is in the range of 30 to 70 mol %, (ii) a softening temperature (Tm) measured by the ring-and-ball method according to JIS K 2207 is in the range of 110° C. to 170° C., and (iii) a content of a fraction having molecular weight of not more than 350, as determine by gel permeation chromatography (GPC) and calculated from polystyrene standard, is less than 1.5 mass %.

A tackifier (B) according to the present invention comprises a copolymer (C) that comprises a structural unit derived from α-methylstyrene or isopropenyltoluene and a structural unit derived from styrene, and the copolymer (C) satisfies the following (i) to (iii): (i) a content of the structural unit derived from α-methylstyrene or isopropenyltoluene is in the range of 30 to 70 mol %, (ii) a softening temperature (Tm) measured by the ring-and-ball method according to JIS K 2207 is in the range of 110° C. to 170° C., and (iii) a content of a fraction having molecular weight of not more than 350, as determine by gel permeation chromatography (GPC) and calculated from polystyrene standard, is less than 1.5 mass %.

Sealing lacquer for application in a printing process, in particular for sealing packaging parts which can be peeled off from one another. The sealing lacquer has in particular a) 40 to 65 wt % solvent, b) 0 to 10 wt % styrene butadiene block copolymer, c) 8 to 12 wt % styrene alpha methylstyrene, d) 6 to 12 wt % linear and/or radial Tri-block (SBS) block, e) 0 to 10 wt % linear Di-Block (SB) block, f) 15 to 30 wt % polyester, and g) up to 3 wt % antioxidant. The sealing lacquer provides a seal that, whether the seal is opened by peeling, or the packaging is push-through packaging, provides a holding force exhibiting a strength until cohesion failure that is determined by the pressures and temperatures used during sealing.

The present invention is generally related to various types of compositions that comprise a polyindane resin. In particular, the polyindane resins may be utilized in various polymer-based and elastomer-based formulations in order to enhance several properties and characteristics of those formulations. More specifically, adhesive formulations are provided that comprise at least one polyindane resin, which may be used to replace or enhance the functionality of existing hydrocarbon resins typically used in adhesive formulations. Compositions comprising at least one thermoplastic elastomer and at least one polyindane resin are also provided.