Provided is a process capable of converting the cokes on spent catalysts in a fluid catalytic cracking (FCC) process into synthesis gas. The produced synthesis gas contains high concentrations of CO and H.sub.2 and may be utilized in many downstream applications such as syngas fermentation for alcohol production, hydrogen production and synthesis of chemical intermediates. A reducer/regenerator reactor for a fluid catalytic process comprising a chemical looping system to produce synthesis gas is also described.

Methods and systems for producing carbon-negative hydrogen and renewable natural gas from biomass are included herein. In an embodiment, the method may include gasifying biomass in a gasification unit to form a first stream comprising syngas. The syngas may include methane, hydrogen, carbon dioxide, carbon monoxide, ethylene, and water. The method may also include reacting the carbon monoxide with water in the presence of a catalyst to form a second stream. The second stream may include a greater hydrogen concentration than the first stream. The method may further include separating at least a portion of the second stream to form a hydrogen stream and a natural gas stream. The hydrogen stream may have a greater concentration of hydrogen than the second stream. The natural gas stream may have a greater concentration of methane than the second stream.

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

Processes and systems for converting a hydrocarbon-containing feed. The feed and heated particles can be contacted within a pyrolysis zone to effect pyrolysis of at least a portion of the feed to produce a pyrolysis zone effluent and a first gaseous stream rich in olefins and a first particle stream rich in the particles can be obtained therefrom. At least a portion of the first particle stream, an oxidant, and steam can be fed into a gasification zone and contacted therein to effect gasification of at least a portion of coke disposed on the surface of the particles to produce a gasification zone effluent. A second gaseous stream rich in a synthesis gas and a second particle stream rich in heated and regenerated particles can be obtained from the gasification zone effluent. At least a portion of the second particle stream can be fed into the pyrolysis zone.

A looping reaction hydrogen production system includes a reduction reaction device, a primary separation device, a hydrogen production reaction device, a secondary separation device, a primary heat transfer device and a cooling purification device. Based on looping combustion reaction mechanism, the system makes MeO/Me circularly flow between the hydrogen production reaction device and the reduction reaction device to respectively generate a reduction/oxidation chemical reaction, and to convert the conventional carbon-based solid fuel into the high-purity clean hydrogen energy. Compared with the conventional hydrogen production technology from water-gas shift reaction of syngas, the system reduces water consumption, energy consumption and environmental pollution of the hydrogen production process; converts conventional carbon-based fuel into clean hydrogen energy by use of renewable energy sources, such as solar energy; and achieves efficient capture and storage of gaseous CO.sub.2.

Disclosed herein is a method for making hydrogen with carbon sequestration. The method may comprise using a biomass hydroconverter product to fuel a steam reformer that converts a hydrocarbon fuel stream into a gas mixture that contains at least hydrogen and carbon dioxide. The gas stream is separated to form a hydrogen-enriched gas stream and at least one hydrogen-depleted stream. The hydrogen-depleted stream may be stored or further processed to sequester the carbon contained therein. Additionally, or alternatively, the solid residue from the biomass hydroconverter also may be stored for further sequester carbon generated by the method.

A process and apparatus for producing syngas from low grade coal and from a biomass wherein the process includes (i) gasification of a mixture of low grade coal and biomass, (ii) reforming the gasified mixture, and (iii) removing CO.sub.2 from the gasified and reformed syngas mixture.

Hydrogen generation assemblies and methods are disclosed. In one embodiment, the method includes receiving a feed stream in a fuel processing assembly, and heating, via one or more burners, a hydrogen generating region of the fuel processing assembly to at least a minimum hydrogen-producing temperature. The method additionally includes generating an output stream in the heated hydrogen generating region of the fuel processing assembly from the received feed stream, and generating a product hydrogen stream and a byproduct stream in a purification region of the fuel processing assembly from the output stream. The method further includes separating at least a portion of the carbon dioxide gas from the byproduct stream to generate a fuel stream having a carbon dioxide concentration less than the byproduct stream, and feeding the fuel stream to the one or more burners.

A method of online control of a slag-forming process of gasification of a carbonaceous solid fuel, especially coal, in a gasification reactor with supply of a gasifying agent and a moderator is provided. Certain embodiments relate to a gasification process for producing a product gas including carbon monoxide and hydrogen from a solid fuel, to a computer program for online control of the slag-forming gasification process, and to a plant for conducting a gasification process for producing a product gas including carbon monoxide and hydrogen from a solid fuel. Certain aspects of the invention combine an online solid fuel analysis with a process model in order to operate a gasification process for solid fuels by the feed-forward principle at the thermodynamically optimal operating point. The invention permits the establishment of the operating point in real time in order to react to rapid variations in the composition of the solid fuel. Certain embodiments also permit the complete automation of the gasification process.

An ASG system for polygeneration with CC includes a devolatilizer that pyrolyzes solid fuel to produce char and gases. A burner adds exothermic heat by high-pressure sub-stoichiometric combustion, a mixing pot causes turbulent flow of the gases to heat received solid fuel, and a riser micronizes resulting friable char. A devolatilizer cyclone separates the micronized char by weight providing micronized char, steam and gases to a gasifier feed and oversized char to the mixing pot. An indirect fluid bed gasifier combustion loop includes a gasifier coupled to the gasifier feed, a steam input to provide oxygen for gasification and to facilitate sand-char separation, and an output for providing syngas. A burner provides POC to a mixing pot which provides hot sand with POC to a POC cyclone via a riser, where the POC cyclone separates sand and POC by weight and provides POC and sand for steam-carbon reaction.