C10L1/1963

Polymers as additives for fuels

A method minimizes power loss in a direct injection diesel engine by adding a copolymer to a diesel fuel composition. The copolymer contains, in a copolymerized form, (A) maleic anhydride, (B) an α-olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B), and (D) optionally an additional copolymerizable monomer other than monomers (A), (B) and (C). Monomer (D) can be a vinyl ester, a vinyl ether, a (meth)acrylic ester of an alcohol having at least 5 carbon atoms, an allyl alcohol or an ester thereof, a N-vinyl compound, an ethylenically unsaturated aromatic, an α,β-ethylenically unsaturated nitrile, a (meth)acrylamide, or an allylamine. Anhydride functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present are hydrolyzed.

ASSOCIATIVE POLYMERS FOR MIST-CONTROL

Polymeric mist control materials, methods of forming polymeric mist control materials, and methods of using such materials for mist control are provided. The polymeric mist control additives are formed of molecules comprised predominantly of monomers that confer high solubility in fuel and include associative groups that attract each other in donor-acceptor manner, and are incorporated such that multiple associative groups are in close proximity (“clusters”), such that the clusters are separated by very long non-associative sequences.

HYDROCARBON FLUID HAVING IMPROVED COLD TEMPERATURE PROPERTIES

A composition includes (a) a hydrocarbon fluid comprising less than 1000 ppm by weight of aromatics, a weight ratio normal paraffins/isoparaffins ranging from 0.2 to 1.0 and having an initial boiling point and a final boiling point in the range from 265° C. to 380° C., and (b) a copolymer derived from alpha-olefin monomers and vinyl acetate type monomers and optionally acrylate type monomers.

PARAFFIN INHIBITOR/PPD PRODUCTS WITH VINYL ACETATE-ALKYL ACRYLATE/METHACRYLATE COPOLYMERS COMBINED WITH ETHYLENE-BASED COPOLYMERS

A stabilized paraffin inhibitor/pour point depressant (PI/PPD) product formulation is described which includes a copolymer having a monomer selected from the group consisting of alkyl acrylate polymers, alkyl methacrylate polymers, and combinations thereof, where the copolymer comprises vinyl acetate and the product includes an ethylene-based copolymer. The presence of the vinyl acetate stabilizes the product to prevent or inhibit the ethylene-based copolymer from separating out of the product. The product is useful to reduce paraffin deposition and/or improve flow characteristics of petroleum fluids, such as crude oil.

Polymer compositions and use thereof as pour Point depressants in Paraffin-containing hydrocarbon oils

The invention relates to polymer compositions with improved manageability, The invention also relates to a polymer composition obtainable by radical polymerisation of A) 95-40 wt. % of a monomer mixture comprising Ai) 65-98 wt. % of at least alkyl (meth)acrylate having a linear C.sub.16-C.sub.40 alkyl radical and Aii) 2-35 wt. % of at least one comonomer selected from (meth)acrylates and (meth)acrylamides, which supports an optionally substituted aromatic radical bonded via an alkylene, alkenylene, oxyalkylene or polyoxyalkylene group to the ester group of the (meth)acrylate or to the amide group of the (meth)acrylamide, in the presence of B) 5-60% by weight % of at least one ethylene copolymer. The invention further relates to a method for the preparation and use thereof as flow improvers for paraffin-containing hydrocarbon oils.

ADDITIVES FOR WINTERIZATION OF PARAFFIN INHIBITORS

A winterized paraffin inhibitor, which is capable of being used for preventing the deposition of paraffins in hydrocarbon streams and capable of withstanding freezing or crystallization at freezing or sub-freezing temperatures, may be formed by adding an oxyalkylated branched aliphatic compound having 12 or more carbons to a high molecular weight aliphatic polymer paraffin inhibitor, the oxyalkylated branched aliphatic compound having 12 or more carbons being produced by the oxyalkylation of the branched aliphatic compound having 12 or more carbon atoms in which the branched aliphatic compound having 12 or more carbon atoms is grafted with a polyether via a ring-opening reaction, wherein the polyether is a polymer of ethylene oxide, propylene oxide, butylene oxide, and combinations thereof.

Wax Inhibitors With Improved Flowability

This invention provides a wax inhibitor composition comprising A) the reaction product obtainable by reaction of i) a carboxylic acid containing an optionally substituted cycloaliphatic hydrocarbyl residue with ii) an alkylene polyamine, B) a polymeric wax inhibitor, and C) an organic solvent.

FUELS

An additive composition for a diesel fuel, the additive composition comprising: (i) a first additive comprising one or more of: (a) the reaction product of a polycarboxylic acid having at least one tertiary amino group and a primary or secondary amine; (b) the reaction product of an α, β dicarboxylic acid or a derivative thereof and a primary amine; and (c) the reaction product of a polyamine and a fatty acid; and (ii) a second additive which is a terpolymer obtained by reacting monomers of: (x) an α-olefin; (y) an ester of an unsaturated alcohol; and (z) a third monomer different to (x) and (y) comprising an alkene functional group.

Polyacrylamide antifoam components for use in diesel fuels

There is disclosed an antifoam component which includes at least one acrylamide polymer for use in a diesel fuel. Acrylamide polymers prepared by polymerizing a (meth)acrylamide monomer to yield a homopolymer or, alternatively, the acrylamide polymer may be prepared by polymerizing a (meth)acrylamide monomer and a (meth)acrylate monomer to yield a heteropolymer.

COPOLYMER AND USE THEREOF FOR REDUCING CRYSTALLIZATION OF PARAFFIN CRYSTALS IN FUELS

The present invention relates to a novel copolymer, to processes for preparation thereof and to the use thereof.