Disclosed are multifunctional compounds represented by structural formula (I): ##STR00001##
methods of producing compounds represented by structural formula (I) and their use in inhibiting corrosion in corrodible material.

The present invention relates to a fuel composition, in particular for an internal combustion engine, comprising: (1) at least one liquid hydrocarbon cut from one or more sources selected from the group consisting of mineral, animal, plant and synthetic sources, and (2) from 1 to 10,000 ppm by weight of an additive which comprises at least 6% by weight of free sterols and/or sterol esters and from 70% to 94% by weight of free fatty acids, these contents being expressed in relation to the total weight of the additive. The present invention also relates to the use of such an additive for improving the lubricity properties of an engine fuel.

A method of producing liquid fuel and/or chemicals from a carbonaceous material entails combusting a conditioned syngas in pulse combustion heat exchangers of a steam reformer to help convert carbonaceous material into first reactor product gas which includes carbon monoxide, hydrogen, carbon dioxide and other gases. A portion of the first reactor product gas is transferred to a hydrogen reformer into which additional conditioned syngas is added and a reaction carried out to produce an improved syngas. The improved syngas is then subject to one or more gas clean-up steps to form a new conditioned syngas. A portion of the new conditioned syngas is recycled to be used as the conditioned syngas in the pulse combustion heat exchangers and in the hydrocarbon reformer. A system for carrying out the method include, a steam reformer, a hydrocarbon reformer, first and second gas-cleanup systems, a synthesis system and an upgrading system.

An unleaded gasoline composition comprises, based on the total volume of the unleaded gasoline composition, 50 to 96 vol. % of an unleaded gasoline; 2 to 20 vol. % of a mixed butanol; and 2 to 30 vol. % of a distillate oil fraction comprising a paraffin, an olefin, a naphthene, and an aromatic at an initial boiling point cut of 180° C., wherein the unleaded gasoline, the mixed butanol, and the distillate oil fraction are selected to provide the unleaded gasoline composition with a Research Octane Number of 90 to 101, determined in accordance with ASTM D 2699; and a Motor Octane Number of 81.4 to 90, determined in accordance with ASTM D 2700.

The disclosure relates to fuel additive compositions including heavy paraffinic distillates and lighter petroleum distillates, in particular with the heavy paraffinic distillates including a mixture of hydrotreated and/or saturated components and solvent-dewaxed and/or branched components. The disclosure further relates to fuel compositions including the fuel additive composition and a liquid or solid combustible fuel. Related methods include methods of making the fuel compositions and methods of burning the fuel compositions. The resulting fuel compositions have several improved combustion properties such as improved combustion efficiency, improved combustion energy/calorie content, reduced sulfur generation, and reduced ash generation.

A fuel composition for a spark-ignition internal combustion engine comprises naphtha in an amount of at least 5% by volume, and an octane-boosting additive having the formula: (I) The well-to-wheel greenhouse gas emissions associated with the fuel composition are significantly lower than those associated with a conventional gasoline fuel of comparable performance.

The present invention relates to a method of marking a petroleum hydrocarbon by adding to and uniformly mixing with said petroleum hydrocarbon a chemical marker of general formula (I)

##STR00001##

wherein two of the residues R.sup.1-R.sup.10 are independently of each other selected from C.sub.1-C.sub.4-alkoxy, and eight of the residues R.sup.1-R.sup.10 are independently of each other selected from the group consisting of hydrogen and C.sub.1-C.sub.4-alkyl, as well as to a composition of a petroleum hydrocarbon comprising a petroleum hydrocarbon and at is least one chemical marker of general formula (I). The presence and concentration of the chemical marker of general formula (I) in the composition of the petroleum hydrocarbon can be advantageously determined by laser ionization coupled with mass spectrometry or by laser ionization coupled with ion mobility spectrometry.

An emulsifying dispersant includes, as the main component, vesicles formed from an amphiphilic substance capable of self-assembly or an emulsifying dispersant comprising single particles of a biopolymer as the main component. The particles made from amphiphilic substances capable of self-assembly are used. The amphiphilic substances are selected from among polyoxyethylene-hydrogenated castor oil derivatives wherein the average number of added ethylene oxide molecule is 5 to 15, dialkyldimethyl-ammonium halides wherein the chain length of the alkyl or alkenyl is 8 to 22, and phospholipids or phospholipid derivatives. According to the invention a three-phase structure composed of an aqueous phase, an emulsifying dispersant phase and an oil phase is formed on the surface of an emulsion to give an emulsion (such as emulsion fuel) excellent in thermal stability and long-term stability.

A fuel stabilizer formulation includes a hybrid component that acts as an antioxidant, a chelating agent, and lubricant when added to the fuel, one or more vapor suppressants, and a water scavenger. Furthermore, the formulation may include components that bond with gasoline compounds to prevent evaporation of low-end components, form a layer along with the engine metal that prevents condensed water from corroding the metal, prevent corroded metal ions from destabilizing gasoline compounds into resin, and scavenge water to prevent water deposits at the bottom of the tank which limits biological activity, resulting in an overall improvement in oxidation stability over conventional fuel stabilizers.

A gasoline fuel composition for a spark ignition internal combustion engine comprising (a) gasoline blending components, (b) renewable naphtha at a level of 10 to 30% v/v and (c) oxygenated hydrocarbon at a level of 20% v/v or less, wherein the gasoline blending components comprise (a) 0-30% v/v alkylate, (b) from 0 to 15% v/v isomerate; (c) 0 to 20% v/v catalytic cracked tops naphtha; and (d) 20% to 40% v/v of heavy reformate, wherein the total amount of alkylate, isomerate, catalytic cracked tops naphtha and heavy reformate is at least 50% v/v based on the total fuel composition, and wherein the gasoline fuel composition meets the EN228 specification. While the low octane number of renewable naphtha would normally severely restrict its blendability in gasoline to low levels, it has now been found that renewable naphtha can be included in, for example, ethanol-containing gasoline fuel compositions, in surprisingly and significantly high blend ratios of renewable naphtha to ethanol.