Provided is grease capable of suppressing a decrease in a function as a lubricant even when used in a device installed in a refrigerant circuit in which a refrigerant containing a chlorine atom and an olefin bond in a molecule flows, and a refrigeration cycle apparatus using the grease as a lubricant. Grease that is used in a device installed in a refrigerant circuit in which a refrigerant containing a chlorine atom and an olefin bond in a molecule flows contains fluorine as a component. In a chiller apparatus, the grease is used as a lubricant for at least one of a first radial touchdown bearing and a second radial touchdown bearing of a compressor, a drive portion of an inlet guide vane of the compressor, and a drive portion of an expansion valve.

The present invention provides a refrigerating machine oil comprising a hydrocarbon-based base oil having a viscosity index of 120 or less, and the refrigerating machine oil being used with a 1-chloro-2,3,3,3-tetrafluoropropene refrigerant.

The present invention relates to compounds according to formula (Ia) or formula (Ib); ##STR00001##
wherein each W is independently selected from the group consisting of H, F, Cl, Br, I and (CY.sub.2).sub.mCY.sub.3; each Y is independently selected from the group consisting of F, Cl, Br and I; each Z is independently selected from the group consisting of H, OH, (CW.sub.2).sub.pCW.sub.3, CY.sub.3, OCW.sub.3, O(CW.sub.2).sub.pCW.sub.3, OCW((CY.sub.2).sub.mCY.sub.3)CWCW.sub.2, (CW.sub.2).sub.pOH, polyalkylene glycol and polyolester; n is an integer from 2 to 49; m is an integer from 0 to 3; p is an integer from 0 to 9; the molecular weight average (M.sub.W) is ≤5500; and the polydispersity index is ≤1.45; compositions comprising these compounds and methods for their production.

Provided are azeotrope or azeotrope-like compositions comprised of 1-chloro-1,2 difluoroethylene (R-1122a) and 2,3,3,3-tetrafluoropropene (HFO-1234yf) and uses thereof.

The invention relates to a lubricating oil composition and a refrigerant composition containing a polyalkylene glycol having a terpenoid end group, such as a farnesol end group.

A composition comprising a heat transfer portion and a lubricating portion, wherein the lubricating portion comprises one or more compounds according to formula (I) of the present disclosure, wherein W is H; Y is independently selected from the group consisting of F, Cl, Br and I; Z is independently selected from the group consisting of H, OH, (CW.sub.2).sub.PCW.sub.3, CY.sub.3, OCW.sub.3, O(CW.sub.2).sub.pCW.sub.3, OCW((CY.sub.2).sub.mCY.sub.3)CWCW.sub.2, polyalkylene glycol and polyolester; n is an integer from 2 to 250; m is an integer from 0 to 3; and p is an integer from 0 to 9.

Compositions, methods, systems, and applications herein are directed to lubricant blends that balance solubility and viscosity of a refrigerant, where in some cases the lubricant blends herein help reduce solubility of a refrigerant. A lubricant blend includes a mixture of two or more different types of lubricants to reduce refrigerant solubility.

A composition comprising a heat transfer portion and a lubricating portion, wherein the lubricating portion comprises one or more compounds according to formula (I): wherein W is independently selected from the group consisting of H, F, Cl, Br and I; Y is independently selected from the group consisting of F, Cl, Br and I; Z is independently selected from the group consisting of H, OH, (CW.sub.2).sub.PCW.sub.3, CY.sub.3, OCW.sub.3, O(CW.sub.2).sub.pCW.sub.3, OCW((CY.sub.2).sub.mCY.sub.3)CWCW.sub.2, polyalkylene glycol and polyolester; n is an integer from 2 to 250; m is an integer from 0 to 3; and p is an integer from 0 to 9.

A compound of formula (I): wherein W is independently selected from the group consisting of H, F, CI, Br, and I; X is independently selected from the group consisting of H, F, CI, Br, and I; Y is independently selected from the group consisting of F, CI, Br, and I; Z is independently selected from the group consisting of H, F, CI, Br, and I; n is an integer from 1 to 8; and n′ is an integer from 1 to 12.

##STR00001##

The present invention relates to compounds according to formula (Ia) or formula (Ib);

##STR00001##

wherein each W is independently selected from the group consisting of H, F, Cl, Br, I and (CY.sub.2).sub.mCY.sub.3; each Y is independently selected from the group consisting of F, Cl, Br and I; each Z is independently selected from the group consisting of H, OH, (CW.sub.2).sub.pCW.sub.3, CY.sub.3, OCW.sub.3, O(CW.sub.2).sub.pCW.sub.3, OCW((CY.sub.2).sub.mCY.sub.3)CWCW.sub.2, (CW.sub.2).sub.pOH, polyalkylene glycol and polyolester; n is an integer from 2 to 49; m is an integer from 0 to 3; p is an integer from 0 to 9; the molecular weight average (M.sub.W) is ≤5500; and the polydispersity index is ≤1.45; compositions comprising these compounds and methods for their production.