There is provided a method of dynamic control for a bottom blowing O.sub.2—CO.sub.2—CaO converter steelmaking process. In the process, O.sub.2 is adopted as a top blowing gas, a mixed gas O.sub.2+CO.sub.2 is adopted as a bottom blowing carrier gas to inject lime powders into the converter from a bottom blowing tuyere. The ingredients of the molten steel in the converter steelmaking process are predicted based on the conservation of matter, in combination with the ingredient data of charged molten iron, the ingredient data of the converter gas in the converter blowing process, and working conditions of the bottom blowing device. The top blowing oxygen amount, the bottom blowing gas ratio and the flow rate of lime powder are dynamically adjusted stage by stage according to requirements for target ingredients at the end point of blowing.

There is provided a method of dynamic control for a bottom blowing O.sub.2—CO.sub.2—CaO converter steelmaking process. In the process, O.sub.2 is adopted as a top blowing gas, a mixed gas O.sub.2+CO.sub.2 is adopted as a bottom blowing carrier gas to inject lime powders into the converter from a bottom blowing tuyere. The ingredients of the molten steel in the converter steelmaking process are predicted based on the conservation of matter, in combination with the ingredient data of charged molten iron, the ingredient data of the converter gas in the converter blowing process, and working conditions of the bottom blowing device. The top blowing oxygen amount, the bottom blowing gas ratio and the flow rate of lime powder are dynamically adjusted stage by stage according to requirements for target ingredients at the end point of blowing.

A method for producing low-carbon ferromanganese capable of achieving a high Mn yield. In producing low-carbon ferromanganese by blowing an oxidizing gas from a top-blowing lance onto a bath face of high-carbon ferromanganese molten metal accommodated in a reaction vessel provided with a top-blowing lance and bottom-blowing tuyere to perform decarburization, the slag composition during the blowing is adjusted so that a value of (CaO+MgO)/(Al.sub.2O.sub.3+SiO.sub.2) on a mass basis in the slag composition is not less than 0.4 but not more than 5.0. Also, agitation is performed under a condition that an agitation power density ε of an agitation gas blown through the bottom-blowing tuyere is not less than 500 W/t.

A method for producing low-carbon ferromanganese capable of achieving a high Mn yield. In producing low-carbon ferromanganese by blowing an oxidizing gas from a top-blowing lance onto a bath face of high-carbon ferromanganese molten metal accommodated in a reaction vessel provided with a top-blowing lance and bottom-blowing tuyere to perform decarburization, the slag composition during the blowing is adjusted so that a value of (CaO+MgO)/(Al.sub.2O.sub.3+SiO.sub.2) on a mass basis in the slag composition is not less than 0.4 but not more than 5.0. Also, agitation is performed under a condition that an agitation power density ε of an agitation gas blown through the bottom-blowing tuyere is not less than 500 W/t.

A method and system for predicting slopping in a converter occurring during decarburization refining in the converter in which molten steel is produced from a molten pig iron by blowing oxidizing gas to the molten pig iron in the converter from a top blowing lance, or optionally further blowing oxidizing gas or inert gas from a bottom blowing tuyere to perform the decarburization refining of the molten pig iron. The method includes measuring an emission spectrum of a throat combustion flame blowing out from a throat of the converter, calculating emission intensity of the measured emission spectrum at a wavelength in a range of 580 to 620 nm, and predicting the occurrence of the slopping based on a time-series change of the calculated emission intensity.

Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.

A gas injection nozzle refractory with one or more gas injection small metal tubes buried therein has improved durability. The gas injection nozzle refractory includes a MgO-C central refractory with a small metal tube buried therein, and a MgO-C peripheral refractory surrounding the central refractory. The central refractory on a plane of the gas injection nozzle refractory has an external shape of a circle with a radius in the range of R+10 to R+150 mm concentric with a virtual circle with a minimum radius surrounding all buried small metal tubes, R mm being a radius of the virtual circle.

The invention relates to a process for producing low-nitrogen crude steel. This process includes melting directly reduced iron and/or scrap in a melting furnace with arc resistance heating to give a metallic melt and a slag. The metallic melt is removed from the melting furnace and used to charge a converter. The metallic melt is refined in the converter to give liquid crude steel. The liquid crude steel is tapped having a nitrogen content [N] of not more than 50 ppm, especially of not more than 30 ppm.

A blowing control method for maintaining a mushroom head of a bottom-blowing nozzle converter is disclosed. Considering the actual state of the mushroom head at the end of the bottom-blowing nozzle tip, the real-time molten steel overheating change during the blowing process, the process requirements of different stages of blowing conversion, and the macroscopic heat balance of the converter, the oxygen-carbon dioxide-lime powder blowing parameters of the inner tube of the bottom-blowing nozzle are dynamically adjusted during the converter smelting process of the bottom-blowing nozzle converter so as to control the cooling intensity, thus achieving precise control of the size of the mushroom head. The present invention maintains the basic stability of the size of the mushroom head at the end of the bottom-blowing nozzle tip, avoiding nozzle blockage caused by an oversized mushroom head and rapid erosion of the nozzle caused by an undersized mushroom head.

A dephosphorization method using a top and bottom blown converter. This method uses a converter charged with molten iron and slag, to blow an oxygen-containing gas from a top-blowing lance, supply the gas from an inlet of a blowing hole, and supply a control gas from an opening toward an axial center. This method has: a slag top-surface position measurement step, with the top surface of the molten iron measured in advance, measuring an arbitrary position in a top surface of the slag; a slag top-surface difference calculation of slag thickness difference between the measured top-surface positions of the molten iron and the slag; and a jetting condition adjustment step of, using the obtained slag thickness, adjusting a jetting condition of the gas jetted from the top-blowing lance into an appropriate range. The top-blown jetting condition is adjusted by comparing the slag thickness and the depth of a surface depression.