A grain-oriented electrical steel sheet having excellent iron loss property is produced from a steel slab containing, by mass %, C: 0.002-0.15%, Si: 2.5-6.0%, Mn: 0.01-0.80%, Al: 0.010-0.050% and N: 0.003-0.020%, when: a heating rate between 500-700° C. in decarburization annealing is not less than 80° C./s, a surface roughness Ra of a work roll in final cold rolling is 0.01-3.0 μm, a total content of alkaline earth metals to MgO in annealing separator is 0-5 mass %, an average length L in rolling direction of passed crystal grains is not more than 25 mm, a ratio of crystal grains having a length in rolling direction of not more than 5 mm is 40-90%, and an existence ratio of alkaline earth metal sulfides having a size corresponding to circle of not less than 0.5 μm in a cross section of forsterite film is not more than 0.2/μm per unit length in sheet width direction.

A grain-oriented electrical steel sheet that includes a base coating with a high TiN ratio advantageous for the application of tension to the steel sheet and has excellent magnetic property is provided. The grain-oriented electrical steel sheet includes: a base coating having a peak value PTiN of TiN in the form of osbornite, observed in a range of 42°<2θ<43° and a peak value PMg.sub.2SiO.sub.4 of Mg.sub.2SiO.sub.4 in the form of forsterite, observed in a range of 35°<2θ<36° of both more than 0 and satisfying a relationship PTiN≧PMg.sub.2SiO.sub.4, in thin-film X-ray diffraction analysis; and an iron loss W.sub.17/50 of 1.0 W/kg or less.

Provided is an oriented electrical steel sheet including a groove existing on the surface of the electrical steel sheet and a forsterite layer formed on a part or all of the surface of the electrical steel sheet, in which forsterite which is extended from the forsterite layer and penetrates to a base steel sheet in an anchor form is present on the surface of the side of the groove.

Provided is a grain-oriented electrical steel sheet having better transformer iron loss property than conventional grain-oriented electrical steel sheets. A grain-oriented electrical steel sheet comprises: a steel substrate; a forsterite film on a surface of the steel substrate; and a Cr-depleted layer at a boundary between the steel substrate and the forsterite film, the Cr-depleted layer having a Cr concentration that is 0.70 times to 0.90 times a Cr concentration of the steel substrate.

An annealing separator for an oriented electrical steel sheet includes: a first component including a Mg oxide or a Mg hydroxide; and a second component including one kind among oxides and hydroxides of a metal selected from Al, Ti, Cu, Cr, Ni, Ca, Zn, Na, K, Mo, In, Sb, Ba, Bi, and Mn, or two or more kinds thereof.

Provided is an oriented electrical steel sheet including: a forsterite film formed on one side or both sides of an oriented electrical steel sheet substrate; and a ceramic layer formed on an entire or partial region of the forsterite film. Provided is a manufacturing method for an oriented electrical steel sheet including: preparing an oriented electrical steel sheet having a forsterite film formed on one surface or both surfaces thereof; and forming a ceramic layer by spraying ceramic powder on the forsterite film.

An annealing separator for an oriented electrical steel sheet including: a first component includes a Mg oxide or a Mg hydroxide; and a second component including one kind among oxides and hydroxides of a metal selected from Al, Ti, Cu, Cr, Ni, Ca, Zn, Na, K, Mo, In, Sb, Ba, Bi, and Mn, or two or more kinds thereof.

Provided is a method for manufacturing a grain-oriented electrical steel sheet. The method comprises: hot rolling a slab to obtain a hot rolled sheet; subjecting the hot rolled sheet to hot band annealing as necessary; subjecting the hot rolled sheet to cold rolling; subjecting the cold rolled sheet to decarburization annealing; applying an annealing separator having MgO as a main component onto a surface of the decarburization annealed sheet and subjecting the decarburization annealed sheet to final annealing to form the forsterite film; and applying an insulating coating treatment liquid onto the final annealed sheet and subjecting the final annealed sheet to flattening annealing to form a tension-applying insulating coating. A difference in total tensions between one and opposite surfaces of the sheet is less than 0.5 MPa. A difference in tensions between the forsterite films in one and opposite surfaces of the sheet is 0.5 MPa or more.

The present disclosure provides a manufacturing method and a grain-oriented electrical steel sheet manufactured thereby, the manufacturing method comprising the steps of: heating a slab; hot rolling the heated slab so as to manufacture a hot-rolled sheet; cold rolling the hot-rolled sheet so as to manufacture a cold-rolled sheet; decarburizing and annealing the cold-rolled steel sheet; forming a ceramic coating layer on a portion or the whole of one surface or two sides of the decarburized and annealed cold-rolled sheet by using a chemical vapor deposition (CVD) process; and finally annealing the cold-rolled sheet on which the ceramic coating layer is formed.

Disclosed is a manufacturing method for a high silicon grain oriented electrical steel sheet, the silicon content of the high silicon grain oriented electrical steel is greater than 4 wt %, comprising the steps of: (1) performing decarburization annealing of a cold-rolled steel plate; (2) allowing high silicon alloy particles in a completely solid state to collide at a high speed with the surface of the decarburization annealed steel plate to be sprayed, thus forming a high silicon alloy coating on the surface of the steel plate to be sprayed; (3) coating a release agent and drying; and (4) annealing. The manufacturing method for the high silicon grain oriented electrical steel sheet of the present invention is inexpensive, and, the high silicon grain oriented electrical steel sheet produced is of stable quality and is provided with great magnetic performance.